직접 플루오르화에 의한 폴리프로필렌 필름의 표면개질

0 20 40 60 80 100 50

60 70 80 90 100 110

Fluorination pressure (kPa) Cont act angl e (

)

water

methylene iodide

0 10 20 30 40 50 60 70 50

60 70 80 90 100 110

Fluorination time (min) Cont act angl e (

)

water

methylene iodide

0 20 40 60 80

0 5 10 15 20 25 30 35

Sur face f re e ene rg y ( m N /m )

Fluorination pressure (kPa) polar ( γ

) dispersive ( γ

) total ( γ

)

0 10 20 30 40 50 60

0 5 10 15 20 25 30 35

polar ( γ

) dispersive ( γ

) total ( γ

)

Su rf ace f re e e ner gy ( m N /m )

Fluorination time (min)

4000 3500 3000 2500 2000 1500 1000 (d)

(c) (b)

(a) untreated (b) 5kPa, 5min (c) 5kPa, 60min (d) 80kPa, 5min

(a)

-CF

-CH

Wavenumber (cm

)

1000 800 600 400 200 0

(c) 60 min

(b) 5 min (a) untreated

FKVV

O1s F1s

C1s

Binding energy (eV)

298 296 294 292 290 288 286 284 282 (d) 60 min

(b) 5 min

(a) untreated 5 5

4 4

3 3

2 2

1 1 1

Binding energy (eV)

676 674 672 670 668 attached F

2

(c) 60 min

(b) 5 min

(a) untreated

Binding energy (eV)

540 538 536 534 532 530 528

2 2

2 1

1

1 (c) 60 m in

(b) 5 m in

(a) untreated

Binding energy (eV)