Do you like math?
Do you like math?
Here follows some elegant description of QM...
이 병 호
Kets and Bras Kets and Bras
β α
bracket
α β
• Hilbert space
P. A. M. Dirac
Ket Space Ket Space
γ β
α + =
c
c α = α
Operator and Eigenkets Operator and Eigenkets
( ) α A α
A
⋅ =• Eigenvalues and eigenkets
,...
, ,
a a a
′ ′′ ′′′A a ′ = a a ′ ′ , A a ′′ = a a ′′ ′′
Bra Space Bra Space
• Dual Correspondence (DC)
α α
↔DC,...
, ,...
,
a a a
a
′ ′′ ↔DC ′ ′′β α
β
α + ↔
DC+
β α
β
α + ↔
∗+
∗Inner Product Inner Product
( ) ( ) β α
α
β
= ⋅Bra (c) ket
• Postulates
≥ 0 α α
= α β
∗α
β
Orthogonality & Normalization Orthogonality & Normalization
• Orthogonality
= 0 β α
• Normalization
α α α α
⎟⎟
⎟
⎠
⎞
⎜⎜
⎜
⎝
= ⎛ 1
~
~
~
α
α
Operators Operators
( ) α X α
X ⋅ =
X Y
Y
X + = +
(
Y Z) (
X Y)
Z X + + = + +( ) α ⋅
X= α
XHermitian Adjoint & Hermitian Operator Hermitian Adjoint & Hermitian Operator
• X† is called Hermitian adjoint of X if
• An operator X is said to be Hermitian if
X
†X α ↔
DCα
X
†X =
Operator Multiplication I Operator Multiplication I
YX XY ≠
( ) ( ) YZ XY Z XYZ
X = =
(
Y) ( )
XY XY(
X)
Y( )
XY XYX α = α = α , β = β = β
Operator Multiplication II Operator Multiplication II
( Y ) ( Y
†) X
†Y
†X
†X
XY α = α ↔ α = α
( ) XY
†= Y
†X
†• Outer product
( ) ( ) β ⋅ α = β α
Associative Axiom Associative Axiom
• Important Examples
(
β α)
⋅ γ = β ⋅(
α γ)
: If
X= β α , then
X †= α β 예
( ) (
β ⋅ X α) (
= β X) ( )
⋅ α = α X† β ∗bra ket bra ket
( ) = { ( ) ⋅ }
∗=
∗⋅
= β α α β α β
α
β X X X
†X
†• For a Hermitian X, we have
= α β
∗α
β X X
Eigenvalues of Hermitian Operator
Eigenvalues of Hermitian Operator
Theorem.
The eigenvalues of a Hermitian operator A are real; the eigenkets of A corresponding to different eigenvalues are orthogonal.a a a
A ′ = ′ ′ a a
A
a
′′ = ′′∗ ′′( )
Proof.
Eigenkets as base Kets Eigenkets as base Kets
a c
a
a
′
= ∑
′ ′
α
α
a c
a′= ′
α
α a a
a
′
=
∑
′′
Completeness Relation Completeness Relation
I a
a
a
′ =
∑ ′
′
∑
2∑
′ ′= ′
⎟ ⎠
⎜ ⎞
⎝
⎛ ′ ′ ⋅
⋅
=
a a
a a
a α α
α α
α
2
1
2
= ∑ ′ =
∑
′ ′ ′ a aa
a
c α
Projection Operator Projection Operator
a a
A
a′≡ ′ ′
I
a
a
=
∑ Λ
′
′
( a ′ a ′ ) ⋅ α = a ′ a ′ α = c
a′a ′
Measurement I Measurement I
• For an observable, there corresponds a Hermitian operator.
If we measure the observable, only eigenvalues of the Hermitian operator can be measured. A measurement
always causes the system to jump into an eigenstate of the
Hermitian operator.
Measurement II Measurement II
∑
∑
′ ′′ =
′′ ′
=
a a
a a a a
c
α
α
a′
A measurementa′
α
A measurementa′
for 2
y
Probabilit a′ = a′
α
Expectation value Expectation value
α α A A =
obtaining for
y
probabilit a' a
a a
α a a
a a A a a
A = ∑∑ ′′ ′′ ′ ′ = ∑ ′ ′
′
′ ′′
α α
measured value a'
Compatibility & Incompatibility Compatibility & Incompatibility
• Observables A and B are compatible when the corresponding operators commute, i.e.,
[ ]
A,
B= 0
• Observables A and B are incompatible when
[ ]
A,
B≠ 0
Uncertainty Principle Uncertainty Principle
( ) ( )
2 2[ ] ,
24
1 A B B
A Δ ≥
Δ
where
A A
A = − Δ
( ) Δ A
2= ( A
2− 2 A A + A
2) = A
2− A
2• The uncertainly relation can be obtained from the Schwarz inequality in a
Example of Uncertainty Relation Example of Uncertainty Relation
( ) ( )
2
4
1
22 2
≥ Δ Δ
≥ Δ
Δ p x
i p
x
, i
Χ Ρ = − ∇
[ ] Χ, Ρ = i
Schrödinger’s Cat
Schrödinger’s Cat
Harmonic Oscillator Harmonic Oscillator
2 2
2 2
2
m x
m
H = p + ω
⎟ ⎠
⎜ ⎞
⎝ ⎛ −
⎟ =
⎠
⎜ ⎞
⎝ ⎛ +
= ω
ω ω
ω
m x ip a m
m x ip a m
2 2 ,
†
a : Annihilation operator a
† : Creation operator[ ] = ⎛ 1 ⎞ ( − [ ] [ ] + ) =
(
†) (
†)
2
2 , m a a
i p a
m a
x = + = ω − +
ω
Number Operator I Number Operator I
•
Number Operatora a N =
†( +
12)
= N
H ω
n n n
N
=( ) n n
n
H
= + 12ω
Number Operator II Number Operator II
[ N a , ] = ⎡ ⎣ a a a
†, ⎤ ⎦ = a a a
†[ ] , + ⎡ ⎣ a a a
†, ⎤ ⎦ = − a
† †
N a , a
⎡ ⎤ =
⎣ ⎦
[ ]
( , ) ( 1 )
Na n = N a + aN n = n − a n
( ) ( )
† † † †
, 1
Na n = ⎡ ⎣ N a ⎤ ⎦ + a N n = n + a n
Annihilation and Creation Operators Annihilation and Creation Operators
− 1
= n c n
a
†
a n c
2a
n =
c
2n =
− 1
= n n n
a
1
†