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Efficacy of Tetraethylammonium Hydroxide in Dispersing Calcium Carbonate in Ethylene Glycol

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Efficacy of Tetraethylammonium Hydroxide in Dispersing Calcium Carbonate in Ethylene Glycol

Kwang-hyung Lee, Seung-joo Kim and Tai-Soo Chung

Department of Chemical Engineering, Sungkyunkwan University, Suwon 440-746, Korea (Received 4 August 2000; accepted 5 July 2001)

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Abstract−Tetraethylammonium hydroxide was very effective in dispersion of calcium carbonate in ethylene glycol. The effective amount of tetraethylammonium hydroxide was 0.3 wt% at 45 wt% calcium carbonate suspension at which the values of average particle diameter, viscosity and zeta potential energy were good enough to maintain the dispersion stability. The variation of particle diameters was also good in the adjusted pH between 6 and 12 after treatment of tetraethylammonium hydroxide on calcium carbonate surface. It was due to adsorption on the calcium carbonate of the cationic tetraethylammo- nium hydroxide electrolyte thus strengthening mutual repulsion.

Key words: Surface Treatment, Ethylene Glycol, Calcium Carbonate, Dispersion, Tetraethylammonium Hydroxide

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To whom correspondence should be addressed.

E-mail: tschung@yurim.skku.ac.kr

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Fig. 9. Relationship between particle diameter and pH(45 wt% CaCO3).

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