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SUPPORTING INFORMATIONLiquid-Liquid Equilibrium and Physical Properties of Aqueous Mixtures of Poly (Ethylene Glycol) 3000 with Tri-Potassium Citrate at Different pH: Experiment, Correlation and Thermodynamic Modeling

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Journal of the Korean Chemical Society 2019, Vol. 63, No. 1

Printed in the Republic of Korea https://doi.org/10.5012/jkcs.2019.63.1.1

-1-

SUPPORTING INFORMATION

Liquid-Liquid Equilibrium and Physical Properties of Aqueous Mixtures of Poly (Ethylene Glycol) 3000 with Tri-Potassium Citrate at Different pH: Experiment,

Correlation and Thermodynamic Modeling

Mahnam Ketabi, Mohsen Pirdashti†,*, and Poorya Mobalegholeslam

Chemical Engineering Department,Faculty of Engineering, Shomal University, PO Box 731, Amol, Mazandaran, Iran.

*E-mail: [email protected]

Young Researchers and Elite Club, Babol branch, Islamic Azad University, Babol, Iran.

(Received August 26, 2018; Accepted November 26, 2018)

Table S1. Density, ρ, and Refractive Index, nD, for the binary and ternary of PEG 3000 (p) + tri-potassium citrate (s) + water system at 298.15 Ka and 0.1 MPab at various mass fractions of polymer, wp and salt, ws

wpc wsc nD (±0.0001)

0.00 0.00 0.9970 1.3327

0.05 0.00 1.0057 1.3394

0.10 0.00 1.0120 1.3458

0.20 0.00 1.0297 1.3599

0.30 0.00 1.0475 1.3743

0.00 0.02 1.0097 1.3357

0.00 0.06 1.0349 1.3413

0.00 0.10 1.0603 1.3470

0.00 0.20 1.1278 1.3615

0.00 0.30 1.1999 1.3760

0.05 0.02 1.0177 1.3416

0.07 0.02 1.0209 1.3444

0.1 0.02 1.0259 1.3487

0.15 0.02 1.0343 1.3559

0.05 0.05 1.0364 1.3468

0.10 0.05 1.0445 1.3539

0.15 0.05 1.0686 1.3609

0.05 0.10 1.0683 1.3540

0.10 0.10 1.0780 1.3612

0.15 0.10 1.0680 1.3683

0.05 0.15 1.1012 1.3615

0.08 0.15 1.1081 1.3658

a298.15 ± 0.05 K, b100 ± 0.05 kPa, c%mass ± 0.001

ρ 0.0001(± ) kg m⋅ 3 ---

수치

Table S1. Density, ρ, and Refractive Index, n D , for the binary and ternary of PEG 3000 (p) + tri-potassium citrate (s) + water system at   298.15 K a  and 0.1 MPa b  at various mass fractions of polymer, w p  and salt, w s

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