• 검색 결과가 없습니다.

Studies on the Characteristics of Single-Layered Organic EL Device Using a Copolymer Having Hole and Electron Transporting Moieties

N/A
N/A
Protected

Academic year: 2022

Share "Studies on the Characteristics of Single-Layered Organic EL Device Using a Copolymer Having Hole and Electron Transporting Moieties "

Copied!
8
0
0

로드 중.... (전체 텍스트 보기)

전체 글

(1)

Demo

  N



ºÊ# ¶«&*.# šžï# s/# *Ê# ¶«/# ¯c¯/#

­Ú# v›/# ú# ë'^# ‹ò# hÚ# ?ªÞ# šZ z# ".# ®>¦¢ö# ÎÊ# ²^Nò# p0n# «&*

# Cö# ¶«# ~¾vÚ# ºFö# s+Ê# š^#

*FN# –¯# &*~1# # ¶«&*.# &*ò# Ë

–# FC².# Öbj# ò# û# z*ö# ‚N^# ‚

ϯ# ¶«&*Ú# š*ö# ‚N^# ›Ï¯# ¶«&*

ö#2¦#²#"~1407#û#z*#Cö#‚ϯ#¶

«&*.# â¯Ë# ŠN2z# šv«º# ›‡ò# Bz#

cÞ# žú# ²# "Ö2# ‚# Öbö# ˶# ‚ÏÖ ö# ‚NÒ# "N# *FNG+fduulhu,ò# ž†# "z¯Ö ö# ö# ¶ö¶# ¶«BÂ# Ò¶ªÖö# Z›²N# î

~18/9# ‚ϯ# ¶«&*ò# Ò¶ªÞ# ¶ºòÊ# ž# š

*# ºÊÖÞ# Cö# ›Ï¯# ¶«&*j# šö# Š

*ý¬MInØ°Ã\<IØ í§.

Iý.Ëãê¬n&ƒ´Ñ.ØJ

Žì"%:²"Š§%

)3113Ä!5C!33w!¨-!3113Ä!6C!39w!B)*!

!

Studies on the Characteristics of Single-Layered Organic EL Device Using a Copolymer Having Hole and Electron Transporting Moieties

Chang Ho Lee, Seung Wook Kim, and Se Young Oh

% Department of Chemical Engineering, Sogang University, Seoul 121-742, Korea

e-mail : syoh@sogang.ac.kr

(Received April#22, 2002;accepted May 28, 2002)

RG k[FFj#¯#©#ž*#ž†Nö#wulskhq|odplqh#prlhw|Ú#wuld}lqh#prlhw|#°.#böN#

«N#Ëòš~1#LWR2«NÚ#¶«Öb#+GFP/#frxpdulq#9/#GSyEl,2DoÖö#˲.#‚ϯ#

ºÊ#HO#&*.#¯#ž†#‚žNÚ#ž*#ž†#‚žN#ÞÂ#9=7Ú#¶«Öbò#ºc#63#zw(#

æ#özò##+*#BÂÞ#2ZNb~1#S"#žj¶#¶+ö#ºÊ#HO#&*.#››#¶«Öbj#[ëò .#¯#+953#qp,/#¢÷#+853#qp,–#¦+c#+783#qp,ò#õÞ#¶«òš~1#öz#²^.#GF#45#Yj

¶#LWR2«N#+9=7,Ú#GFP#+63#zw(,2DoÖö#˲.#&*#sòšÞ#æ#833#fg2p#b~1##

#

"#453"$5+Zh#kdyh#v|qwkhvl}hg#d#qryho#fduulhu#wudqvsruwlqj#frsro|phu#kdylqj#wulskhq|odplqh#

prlhw|#dv#d#kroh#wudqvsruwlqj#xqlw#dqg#wuld}lqh#prlhw|#dv#dq#hohfwurq#wudqvsruwlqj#xqlw#lq#wkh#

sro|phu# vlgh# fkdlq1# Vlqjoh0od|huhg# rujdqlf# hohfwuroxplqhvfhqw# +HO,# ghylfhv# frqvlvwhg# ri#

LWR2frsro|phu# dqg# hplwwlqj# pdwhuldov# +GFP/# frxpdulq# 9/# GSyEl,2Do# h{klelwhg# pd{lpxp#

h{whuqdo#txdqwxp#hiilflhqf|#zkhq#wkh#udwlr#ri#kroh#wudqvsruwlqj#xqlw#dqg#hohfwurq#wudqvsruwlqj#

xqlw#lv#9=7#dqg#wkh#frqwhqw#ri#hplwwlqj#pdwhuldo#lv#63#zw(1#Hvshfldoo|/#wkh#ghylfhv#hplwwhg#wkh#

oljkw# ri# uhg# +953# qp,/# juhhq# +853# qp,# dqg# eoxh# +783# qp,# fruuhvsrqglqj# wr# wkh# hplwwlqj#

pdwhuldov/#uhvshfwlyho|1#D#pd{lpxp#oxplqdqfh#ri#LWR2frsro|phu#+9=7,#dqg#GFP#+63#zw(,2Do#

HO#ghylfh#zdv#derxw#833#fg2p##dw#d#GF#gulyh#yrowdjh#ri#45#Y1#

#

Keywords+electroluminescence, carrier transporting copolymer, single layer, emitting material, luminance.

(2)

š# ^#²N# hÚ# Š# J–š# ¶ö²z# ".# Ú#

³Ú# ›Ï¯# ¶«&*.# FC².# ºÊ# ÖbÞ# ®4 N# *FNò# ž†'^# B–›Öö# ¶Nò†# &*ò#

¶«BÂÞ# ?[vF# ²# "~1:/;# ’†2# ›Ï¯# ¶«

&*ò# ››ò# ÏÚ# ²›Öö# 7Ãj# ò# ¶+²

# 7Ã# v# š*# ºÊÖj# šö# Ž# â¯Ë–# &*

ò# s# v# ¶w².# Žj# òö# š*# Öbò# ëk Öö# &*ò# Žîš# ¶w²z/# ²².# 7Ã# ¯Ö ö# # ¶+¯# ªö# ;ò†# ®>¦¢# v?j

¶#W[¿##N¾R#²#"~1<##

ö–j.# ‚Ï# Nj# ž*# ž†# Ê?–# ¯# ž†#

Ê?Þ# svj# †ö# ‚ϯ# ¶«&*ò# ¶+# v

^²z#"~143#Ú#³Ú#Ã/Þ#Cò#‚#C~#

Nj# *FN# ž†Öb–# ¶«ÖbÞ# †# >Ú# *>

ŸfÖö# &*¶+# Cò†# ¶+¯Þ# ö&îv F# ²# "Þ# jf# Þb# *FNò# ž†'^# ¶N

Öö# &*ò# ¶«BÂÞ# ?[vF# ²# ".# ›Ï¯#

¶«&*ò# ?ªÚ# Öú# z*ò# ?ª^# svj# ~

žú#²#"~z#Ff¶~1##

ʶ# ’# Šj¶.# J²ö# ¯# ž†Ê?Þ# š

^# wulskhq|odplqh–# ž*# ž†Ê?Þ# š^# 5/7/90 wulskhq|o04/6/80wuld}lqhÞ#[FFö#šZ.#sro|0 phwk|ophwkdfu|odwh# º^N# Ëòz# z*ò#

# ©# ÖF›# SËÞ# :ò†# *FN# ž†Öb öò# öC# š?ËÞ# Fòš~1# †Êj# zBÂò# ~ +ö# š*# ¶«ÖbÞ# ^Öö# GÌ̛c ò# *N# ¶ž# š?–# svj# J²ö# šË–#

â¯Ë# ©# ,Ú# BÂÞ# °.# ‚ϯ# ¶«&*ò# ¶+#

š?˖# &*ò# «ÌžÊ›# SËj# š# :òšÖ

# ¶«Öbò# '^Ú# [FFò# ÞÂj# Ê# &*ò#

Þ#ïWòš~1##

#

Ò  Æ



Êk# ‚cNò# Ë# v# «j¶# 40iorxrur070 qlwurehq}hqh/# glskhq|odplqh/# FvI/# Sg# rq# dfwly0 dwhg#fduerq/#70ioxrurehq}doghk|gh/#dqlolqh/#phwkd0 fu|olf#dflg.#Dogulfk#Fkhp1#Fr1ò#S£vÞ#¯¶

–¯# `# FCòšz/# phwkdfu|or|o# fkorulgh/# wul0 hwk|odplqh/#eh}dplglqh#k|gurfkorulgh.#WFL#Fr1ò#

S£vÞ# ò†# ¯¶–¯# `# FCòš~1#  Ë#C~ö#FCö#GPVR/#GPI.#vª².#4£#vÞ#

7òò†# FCòšÖ/# WKIÚ# öö†Ú# M1# W1#

Ednhuò# S£vÞ# FCòšz/# «# ¶v¶ö# F Cö# DLE QÚ# Mxqvhl# Fkhp1# Fr1ò# S£vÞ# FC òš~1# ¶«Öbö# FCö# GFP/# Frxpdulq# 9/# GSyEl .#Dogulfk#Fkhp1#Fr1ò#S£vÞ#FCòš~1##

W ¯# ž†# Öb# ‚cNò# ËÚ# Vfkhph# 4j#

2ZR# 6‚^ò# Ã/Öö# #òšz/# *Òö# NCÚ# ~ æ–#³~1#֚#4‚^j¶.#40iorxrur070qlwur#ehq0 }hqh# <1;;# jG+:3# ppro,–# glskhq|odplqh# 441;8# jG +:3# ppro,# º¶# GPVR# Cûj# £~# FvI#

43196# jG+:3# ppro,Þ# ½N# 453# ~# b&# žÊ# ò j¶# 73vž# sâ# ²ëv>z# ²ëÖÞ# Öj# žv B# ^# ·6¶# zN# dfhwlf# dflgö# FJ¯ò†# 4‚

^# C›ÖÞ# Ub~G+²Â# =# <515(,1# 5‚^j¶.# 4

‚^# C›Ö# ;146# j# +5;# ppro,–# £~# 8(ò# Sg#

6193# jG+5;# ppro,Þ# GPI# Cûj# ½z# [Â# ²&#

žÊ# òj¶# ²ëvB# ^# £~ö# FCö# SgÞ# †

–v>z# Öj# žv¶# ·6¶# zN# Öö# ²# Ò 3ò†# 91:5# jò# 5‚^# C›ÖÞ# Ub~G+²Â +#

8413(,1#ö›Öö#5‚^#C›Ö#51:3#jG+581;#ppro,

–# wulhwk|odplqh# 5194# jG+581;# ppro,Þ# >ºj# B

šò†# 43# ~j¶# 73vž# sâ# ê²v¶# GSPD# ‚c N#Ëòš~1#Ë#ÖÖÞ#4#P#KFo#²Cû/#Ö/#

N H

F NO2

N NO2

N NH2

CH3 C CH2

C Cl

O

N NH C C

O CH3 CH2

CsF

Pd/C H2

+

DMSO

+

DMF N

H

F NO2

N NO2

N NH2

CH3 C CH2

C

jj““

O

N

uuoo

C C

O CH3 CH2

CsF

Pd/C H2

+

DMSO

+

DMF

6FKHPH  V|qwkhwlf# urxwhv# ri# Q0+s0glskhq|o0 dplqh,skhq|o#phwkdfu|o#dplgh1

G

(3)

QdRK# ²Cû# ¶Öö# Ò3ö# ^# βJ# 2RÖ ö# 57vž# sâ# vÊ~1# ’# ^# >º–# Jò# Ö

C~ö#FJ¯ò†#7166#jò#¶²ö#‚cN#UÞ#

²#"b~G+²Â#=#84(,1##

#

Fdofg1# F#=#;3179(# K#=#9147(# Q#=#;186(#

Irxqg# F#=#;3157(# K#=#914;(# Q#=#;18:(#

#

FWž*#ž†#Öb#‚cNò#ËÚ#Vfkhph#5 j#2Z6#6‚^ò#Ã/Öö##òšz#*Òö#Ã/Ú#

~æ–# ³~1# ֚# 4‚^j¶.# öö†j# #

70ioxrurehq}doghk|gh# 4517# jG+433# ppro,j# Þj J#<16#jG+433#ppro,Þ#Bšö#^#7;vž#sâ#93#~

j¶# ²ëv>z# öö†Þ# ¶ò†# 4‚^# C›

Ö#4818#jÞ#UÞ#²#"b~G+²Â#=#:;(,1#5‚^j¶

.# 4‚^# C›Ö# <1<8# jG+83# ppro,–# eh}dplglqh#

k|gurfkorulgh# 481:# jG+433# ppro,Þ# GPIj# ½z#

;3# ~# b&# žÊ# òj¶# 7;vž# sâ# ²ëvB# ^#

8# ~ö# c›v¶# ·6¶# zN# î^Æö# Ò3ò†#

[# J¯ò# 5‚^# C›Ö# 4515# jÞ# UÞ# ²# "b~G +²Â# =# :8(,1# ö# 6‚^j.# 5‚^# C›Ö# 918# j#

+53#ppro,–#phwkdfu|olf#dflg#41:6#j#+53#ppro,#

º¶#GPI#Cûj#£~#FvI#6136#jG+53#ppro, Þ#½N#453#~# b&#žÊ#òj¶#73vž#sâ#² ëv>z# ²ëÖÞ# Öj# žv¶# UN^# ‚cN#

öö†j# FJ¯ò†# ¶²ö# ‚cN# 71:4# jÞ# U Þ#²#"b~G+²Â#=#93(,1##

#

Fdofg1# F#=#:916(# K#=#71<(# Q#=#431:(#

Irxqg# F#=#:914(# K#=#71;(# Q#=#431<(#

#

Ú#³#Ëö#5šZ#‚cNò#¯c̯Ë#·

Ú#KSOF/#IW0LU/#"K0QPUö##òš~1##

ãÿW¢W «Nò# ËÚ# GSPD# ‚cN Ú# GWSP# ‚cN# ~+ö# ÞÂö# Öò†# DLE Q#

¶v¶j# òö# Cû# «Öö# #òš~1# *Òö# «

Nò#˶¶.#~æ–#³~1#¶v¶ö#DLEQ#3135;#

jG+314:# ppro,Þ# WKI# 63# pOj# ½Ú# ~æ# GSPD#

‚cNG 319:# jG+5# ppro,–# GWSP# ‚cN# 3186# j#

+416# ppro,Þ# Bšò†# 93# ~ò# b&# žÊ# òj

¶# 7;vž# sâ# «vÊ~1# «CûÞ# –cò# î^

Æj# ½N# žv>z# Ò3# ©# †–# ^# ^# v

¶# c# jò# «N# SGSPD0fr0GWSP# 31<:#

jÞ#Ub~G+²Â#=#;4(/#²cz*c#=#;333,1##

ãÿW¢H «Nò#"K0QPU#»¯Ú#Yduldq#

Jhplql#IW0QPU#ÊÊ#FCòšz/#C~.#4#(0 WPVš#~N#".#FGFo$#FCòš~1#*c#»¯

Ú# Zdwhuv# KW9H# †––# MDVFR# Y7# XY# 6ʚ#

¾ò¶# JSF# FCòšz/# sro|vw|uhqh# Ž¯{ºÞ#

FCò†# ^Jòš~1# z*ò# Ž›# ËbÚ# GVF#

+Shunlq# Hophu# GVF# :,Ú# WJDG+WD# lqvwuxphqwv#

5<83# WJD,# FCò†# b&# žÊ# òj¶# Fò

š~1#«Nò#JîÌòj#žž.#f|folf#yrowdp0 phwu|G+HJ)J#prgho#695,ö#«N##ö ö†#CûÞ#*>Ÿö#Ë¢ž“G+4Ý4# fp#,Þ# FC òšz/# šž“–# ʚž“Ú# Ë¢G+5Ý5# fp#,–# Dj2#

DjFo# FCòšÖ# žb# CûÚ# QdFoÞ# Cv B# GL# zdwhu# FCòš~1# «N# ¯cò# öÚ#

DIPG+Dxwr#Sureh#FS/#Sdun#Vflhqwlilf#Lqwuxphqwv, Þ#FCò†#šÊòš~1##

Ω2fp#ò#

šÞ# šZ.# LWR# ʪG+5Ý518# fp#,j# –J# ² Cû–# pdjqhvlxp# phwdo# srzghu# FCò†# j

ö#^#lvrsurs|o#dofrkro–#NRK#63#zw(ò#ÖCû j# ›v¶# 53# sâ# ¢æ¦# Ò3Êö# Ò3òš~1#

’# ^# GL# zdwhuj# ›v¶# Ò3ö# ^# ×Ú# JC ûÞ# FCò†# ö2F# #òz# # b&# š>ö#

vÊ~1# Ò3ö# LWR# ʪ# žj# Ëö# «N

# SGSPD0fr0GWSPÚ# ¶«Öb# GFP/# Frx0 6FKHPH  V|qwkhwlf# urxwhv# ri# Q0+5/70glskhq|o0

4/6/80wuld}lqh,skhq|o#phwkdfu|odwh1

G

CHO

F NH2

F

+ N

CHCl3

DMF

N N N F NH

NH2

+

N N

N O C C O CH2

CH3

+

CH3 C C CH2

O O

H

NMP

CsF

+ ,

,

+

(4)

pdulq# 9/# GSyEl# «# ò2# prqrfkorurehq}hqhj#

Cv¶#4#zw(ò#®¦v#¶ö#^#5333#uspò#

'^ö# >Ú# *>Ÿv¶# 833# Ø# êHò# ¯cÞ# ¶ òš~1#Iljxuh#4j#’#~rj#Š#Öbò#îó

# 2ZNb~1# ¯Ë¶# ®¦vÏ# žj# ^7Ã# Ã/

Þ# FCò†# 悒# ž“Þ# 4333# Ø# êHö# 7à òš~1# ^7ÃÚ# XOYDF# YSF0593I# prghoÞ#

FCò†# 4Ý43&# Wruu# òò# ^[vj¶# #òš

z/# c# êHò# ¶N.# FUWP# 8333# jdxjhG+XOYDF#

Fr1,# FCòš~1# Ú# ³Ú# Ã/Öö# ¶+¶# ºÊ#

¶«&*ò#žò0žï0²^GG+L0Y0O,#SËÚ#Nhlwkoh|#

56:#hohfwurphwhuÚ#Qhzsruw#4;630f#skrwrglrgh ö#Fòš~1##

#

žêýÎ



ãÿW¢F Z^ ’# Šj¶# ¶ö# «N#

SGSPD0fr0GWSPÚ#WKI#‹j#C²N#>Ú#*

ž†# Ê?Ê# wulskhq|odplqh–# ž*ž†# Ê?Ê#

wuld}lqh# prlhw|# šZz# "N# ¯–# ž*ž†#

š?ò~1#Iljxuh#5j#‚cN#GSPD/#GWSP–#

«Nò# IW0LU# >3R–Þ# 2ZNb~1# GSPDÚ#

GWSPò# >3R–j¶.# ÞjÊò# F@FK## z/^

s# Öš# 4953# fp"j¶# 2Z2z/# «Nò# >

3R–j¶.# ›# ‚cNò# ÞjÊj# “².# «J

ò# Öš# FZ.# Öö# ŽÞ# «# ^#¶# 

Þ# æ# ²# "b~1# ªö# ‚cNò# ÞÂj# Ê# «

Nò# ÞÂÞ# ›# ‚cNj# “².#"K0QPU# >3R

–j¶# SËÖò# ›Þ# Oò†# ^Jòš~1#

Iljxuh# 6j# 2ZR# 2–# GSPDj# “².# 6"#

ÖÚ# GWSPj# “².# 7"# Öò# ›Þ# Þ êö# J–# «v# ‚cN# GSPDÚ# GWSPò# ÞÂ#

:=6##æ#«Nj¶#››ò#›Þš#:#=#51:<ö#

2Z6# Öö# ŽÞ# ‚cNò# ÞÂj# Ê# «# ^

#².#Þ#æ#²#"b~1##

ãÿW¢Fâï§ š*# ÖbfÖö# ˲ .# ›Ï¯# ºÊ# HO# &*.# s# v# ¶w².# Ž–# J

&j# šö# NË# BNÒ# &*ò# ²# ÞZ.#

‚ªÞ# šZz# "~1"""%# ªö# &*ò# s# v# #

483# ×# [ò# Ž# ºÊÖbj# šZZö# .# š

*# Öbò# Žî# ž[Þ# £^v>z# šÊ# «ò# J&

Ú# ²Ú# š*# Öbò# J¯î# ž[Þ# º^ò†# ö

ò# ¯v# &# *[v¶# ^# ¯Fž[Þ# ¶wv )LJXUH #Fkhplfdo#vwuxfwxuhv#ri#+d,#fduulhu#wudqv0

sruwlqj#frsro|phu#dqg#hplwwlqj#pdwhuldov#=#+e,#GFP/#

+f,#Frxpdulq#9/#+g,#GSyEl1

G

N

N N O C C O CH3 CH2 C CH3

C CH2

NH O

N

[ ]x [ ]y

v v jjooZZ jjoo

jjjjuu u ujj

j

joo uu

j jooZZ j jooZZ

u u zz u

u vv

j jooYYjjooZZ j jooZZjjooYY

+d,#

+e,#

+f,# +g,#

46# 45# 44# 43# <# ;# :# 9# 8# 7# 6# 5# 4# 3# IIF# Wavenumber (cm-1)

500 1000 1500 2000 2500 3000 3500 4000

Transmittance (%)

DTPM

DPMA

PDPMA-co-DTPM C=CH2

C=CH2

)LJXUH # IW0LU# vshfwud# ri# GWSP/# GSPD# dqg#

SGSPD0fr0GWSP1

G

)LJXUH#"K0QPU#vshfwuxp#ri#SGSPD0fr0GWSP1

G

(5)

>z# J–›Öö# ^«£Þ# ßîv¶# Þ¶«# ›Þ#

7šv>&# ¶~144/4804:# ʶ# ’# Šj¶.# Ë ö# SGSPD0fr0GWSP# «N# ž†Öbò# Ž›#

â¯ËÞ# :òÊ# ž# š*# ¯# ž†Öb–# ž

*# ž†Öb# wulskhq|odplqh# ©# 5/7/90wulskhq|o0 4/6/80wuld}lqh–# H# GVFÚ# WJD# Fòš~1#

*FN# ž†# SËÞ# °.# 5/7/90wulskhq|o04/6/80 wuld}lqh–# wulskhq|odplqhò# .ªÚ# ››# 563# ~ Ú#45;#~~1# j#²G #Iljxuh#7ò#GVF#J–j#

2Z6# –# ³# SGSPD0fr0GWSP# «N# ž

†Öbò# WJ# ºFž# Â^š# 4;;# ~ö# 2Z2# &

*ò# Ž›# SË# š*# FCö# &*j# Þ# ?[

º# # w›¶~1# ªö# Iljxuh# 8ò# WJD# J–j

¶^# 5<;# ~ò# ,Ú# Â^# 2ZNN# ŠN6# Ž

›#SËÖö#ö#&*ò#â¯Ë#ʚ¶~1##

&*ò# Ž2Fj# Ê# â¯ËÞ# FòÊ# žò†#

SGSPD0fr0GWSP# «N# ž†Öbö# ¶ö# ¯

cÞ# Ž2F# ž–# 483# ~j¶# ;vž# sâ# Ž2Fö# ^ò# öÞ# DIPÖö# Fòš~1# Iljxuh# 9j¶# æ#

²# "‰# Ž2F# žò# ö–# Ž2F# ^ò# ö#

Bê# z&# 2Z2# Ž2Fj# Ê# â¯Ë# ŠN2

~.# Þ# ïú# ²# "b~1# †ö# J–.# &*ò#

sv# SGSPD0fr0GWSP# «N# ž†Öbö# ¶ ö# ¯c–# LWR# ž“Ú# ¢'# ž“žò# ^SËÞ#

â¯ò&# ºZv¶# sv# ¶w².# Žj# òö# &*

ò#â¯ËÞ#&#?[vF#²#"Þ#Öö#w›¶~1##

ãÿW¢Fòï§ ‚ϯÖö# ˲.# º v# HO# &*ò# ¶«BÂÚ# ›# *FN# ž†N# ª.# ¶

«Öb# šZz# ".# KRPR/# OXPR# šžÚ# ¢'#

ž“/# LWR# ž“ò# 2’# šžò# Âj# Ê# &#

›?Þ# µ.~1# ’# Šj¶# ¶ö# LWR2®¦vÏG +SGSPD0fr0GWSP# «N# ž†Öb/# GFP# ¶

«Öb,2Doö# ˲.# ºÊ# HO# &*j¶# «Nò#

j¢Z# ~N’BÞ# Fò.# # ¶«SËò# ·

j# «.ö# .# ²F# w›¶~1# ʶ# SGSPD0 fr0GWSP# «N# ž†Öbò# JîÌòj# žž#

»¯ò†# wulskhq|odplqh# prlhw|ò# KRPR# šžÚ#

wuld}lqh# prlhw|ò# OXPR# šž# ^Jòšz/# ²›

Öö# FC².# ¯# ž†Öb# sro|ylq|ofdued}rohG +SYN,/# ž*# ž†Öb# 5070elskhq|o|o08070w0 exw|oskhq|o04/6/70r{dgld}rohò# KRPR/# OXPR#

šžÚ# Þêò†# SGSPD0fr0GWSP# «N# ž )LJXUHGVF#wkhuprjudp#ri#SGSPD0fr0GWSP1

G

Temperature (oC)

120 140 160 180 200 220

Exothermic

9j;4;;# Ž#

##H{rwkhuplf#

Whpshudwxuh#+~,#

)LJXUHWJD#fxuyh#ri#SGSPD0fr0GWSP1

G

100 200 300 400 500

0 20 40 60 80 100

9g;5<;# ~#

Whpshudwxuh#+Ž,#

Zhljkw#+(,#

)LJXUHDIP#lpdjh#ri#SGSPD0fr0GWSP#vxuidfh#

diwhu#khdw#wuhdwphqw#iru#;#kuv1

G

53313 48313 43313 8313

! !& " "& #µF 49313 45313

;313 7313 313

! !& " "& #µF

5 µp4 418

318 3 3 3184µp 418

5

µp4 318 3 3

318 4185

5 4µp

418

5<3 4783 6934;3

3

lq#vlwx# # diwhu#;#k#

A A

A 313

A

(6)

†Öbò#*FN#–#SËÞ#ÞêÌ·òš~1#Iljxuh#

:j# SGSPD0fr0GWSP# «N# ž†Öbò# f|0 folf# yrowdpprjudpÞ# 2ZNbz# öÊ# ^J¶#

SGSPD0fr0GWSPò# KRPR/# OXPR# žžöÊ#

SYNÚ# SEG/# ’Fz# ’# ~rj¶# FCö# Öb~ò#

j¢Z#~N’BÞ#Iljxuh#;j#››#^vòš~1##

Iljxuh# ;j¶# æ# ²# "‰# SGSPD0fr0GWSP#

«N# ž†ÖbNj¶# ¯# –‡úÞ# ò.# wul0 skhq|odplqh# prlhw|ò# KRPR# šžG+08183# hY,Ú#

SYNò# KRPR# šžG+08193# hY,ò# š# 314# hY

z# ž*# –‡úÞ# ò.Gwuld}lqh# prlhw|ò# OXPR#

šžG+051<3# hY,Ú# SE Gò# OXPR# šžG+05193# hY, ò# š# 316# hY# Öö# ŽÞ# LWRöÊò# ¯

ò# ––# DoöÊò# ž*ò# –# SYNÚ# SE GŽ~#

ŠN:# Öö# Ff²/# J–›Öö# ºÊ# HO# &*

ò#BÂ#?[º#Öö#Ff¶~1##

ãÿW¢FÖ·¢ ¾Bÿ§ LWR2®

¦vÏ+SGSPD0fr0GWSP#«N#ž†Öb/#GFP#

¶«Öb,2Doö#˲.#ºÊ#HO#&*j¶#«Nò#

‚cN# ÞÂj# Ê# # ¶«BÂ# Zî# Iljxuh# <j#

2ZNb~1# Iljxuh# <j¶# æ# ²# "‰# «N# ž

†Öbj¶# ¯Þ# ž†v>.# GSPD# ‚cNÚ# ž*

# ž†v>.# GWSP# ‚cNò# ÞÂ# 9=7# WJ#

š?#,Ú#¶«BÂÞ#2ZNb~1#†ö#J–.#GSPD#

‚cNò# ¯# s^Ž~# GWSP# ‚cNò# ž*#  s^š# úÊ# æÒj# J–›Öö# «Nj¶# ›#

‚cNò# ÞÂ# 9=7# æ# *# Nj¶# *FNò# z

¯# ›¢ò&# ‚NZ.# j# Êò.# Öö# w

ݦ~14;##

LWR2®¦vÏG+SGSPD0fr0GWSP# «N# ž

†Öb/# GFP# ¶«Öb,2DoÖö# ˲.# ºÊ# ¶«

&*j¶# GFP# ºcj# Ê# ¶«SËÞ# Iljxuh#

43j# 2ZNb~1# ¶«Öb# GFPò# '^š# 7šj#

Ê# öš# ¶«¦?# 953# qpj¶# 973# qpö# s

)LJXUH # F|folf# yrowdpprjudp# ri# SGSPD0fr0 GWSP1

G

Voltage (V vs. Ag/Ag+ )

-2 -1 0 1 2 3

Current (A)

51596# # Y#

41955# # Y#

031<;5# # Y# 31<83# # Y#

)LJXUH Vfkhpdwlf#hqhuj|#gldjudp#iru#rujdqlf#HO#

ghylfh# frqvlvwhg# ri# LWR2SGSPD0fr0GWSP# dqg#

hplwwlqj#pdwhuldov#=#GFP/#Frxpdulq#9/#GSyEl2Do1

G

)LJXUH H{whuqdo#txdqwxp#hiilflhqf|#ri#LWR2#SGSPD0 fr0GWSP#dqg#GFP2Do#ghylfhv1

G

Voltage (V)

0 5 10 15 20

Q.E.(%)

0.00000 0.00005 0.00010 0.00015 0.00020 0.00025

5:5 6:4 7:3

 

  

  

Wavelength (nm)

400 500 600 700 800

Intensity (A.U.)

0.0 0.2 0.4 0.6 0.8

1.0 10 wt%

20 wt%

30 wt%

50 wt%

)LJXUH  HO# vshfwud# ri# LWR2SGSPD0fr0GWSP#

dqg#GFP2Do#ghylfhv#zlwk#ydulrxv#frqwhqwv#ri#g|h1

G

(7)

ò# :53# qpj¶# vkrxoghu# Öš# w˲b~1# S"#

63# zw(#[ò#'^j¶.#öš#¶«¦?#vkrxoghu#

Ö#:53#qpö# sòš~1#Ú#³Ú#J–.#GFP ò# '^š# 7šj# Ê# SGSPD0fr0GWSP# «

N# ž†Öb# Nj¶# GFP# *ò# ëkj# òö#

h{lphuš# ¯Ë²N# >^# «Cj# òö# «0«

# †Ê*š# HÚ# j¢Z# šžö# ž²N# HÞ^# j

¢Z# Çf# öš# ¶«¦?# s¶# Öö# Ff¶~1##

Iljxuh# 44Ú# ¶«Öbò# '^j# Ê# LWR2®¦v#

ÏG+SGSPD0fr0GWSP# «N# ž†Öb/# GFP#

¶«Öb,2Do# &*ò# # ¶«BÂÞ# 2ZR# J–

~1# ¶«Öbò# '^š# 7šj# Ê# ¶«BÂ# 7

šò~š# 63# zw(# [ò# '^j¶.# ¾"¾# 66"#

ª&ò†# Iljxuh# 43j# 2ZR# ¶«SËò# J–Ú# ³ Ú# W?Þ# 2ZNb~1# Ú# ³# «N# ž†Öb

–# ¶«Öbò# ®¦vÖj¶# GFPò# ºc# Z2

ò&##WJ#¾"¾#¶«SË#2úZ.#º.#GFP#

*ò# ëkj# Ê# *ž# Fš# šæfÒ# >^# « Cj# òö# «0V«# †Ê*# ‹ò# Þ¶«# &#

Wöš# hÞZÊ# æÒz# Ff¶~1# Iljxuh# 45j#

LWR2®¦v# ÏG+SGSPD0fr0GWSP# «N# ž†

Öb/#¶«ÖbG+GFP#53#zw(/#Frxpdulq#9#53#zw(/#

GSyEl# 53# zw(,,2DoÖö# ˲.# ºÊ# HO# &*j

¶# ¶«Öbò# òj# Ê# ¶«SËÞ# 2ZNb~1#

«N# ž†Öb–# ¶«Öbò# ®¦vÖö# ¶ö#

ºÊ# HO# &*.# ¶«Öbò# òj# Ê# ››# ~+

ö# cÞ# 2ZNN# GFPò# WJ# 953# qp/# Frxpdulq#

9#853#qpÚ#GSyElj¶.#753#qpò#öš#¶«¦?

Þ# Žš~1# Ú# ³Ú# J–öÊ# >Ú# *>Ÿj# ò ö# ž‚ö# ¯Öö# ‚ÏÖö# ˲.# ºÊ# HO#

&*ò# ¶+# š?ËÞ# ïú# ²# "bÖ# S"# ¶«

Öbò# ›¢ö# ºwÖö# ††# ¶«&*ò# ¶+# ª ö#š?ò~.#Þ#æ#²#"b~1##

#

ž  N

#

’# Šj¶# wulskhq|odplqh–# 5/7/90wulskhq|o0 4/6/80wuld}lqhÞ#[FFö#°.#sro|phwk|ophwkdfu0

|odwh# ^ò# «N# Ëö# ~æ# «NÚ# ¶«

Öbò#®¦vö#˲.#‚ϯ#ºÊ#HO#&*#¶+

ò†# «žÊ›# SËÞ# Fö# J–# ~æ–# ³Ú# Jú Þ#Ub~1##

+4,# ¶v¶ö# DLE QÞ# FCò†# ›# ‚cNò# ÞÂ

^ö# Cû«j# ò# cz# ;3(# [ò# ,Ú# ²Âö#

«N# SGSPD0fr0GWSPÞ# UÞ# ²# "bÖ /##«N.#Böö>º/#öö†/#WKI#

‹–#³Ú#ºÊ#C~j#2#ò~1##

+5,# SGSPD0fr0GWSP# «N# ž†Öbò# º F# žÂ^.#4;5#×ö#2ZFz/#Â^š#5<;# × ö#Ž›#SË#~J#ŠN6#Þ#æ#²#"b~1##

+6,# SGSPD0fr0GWSP# «N# ž†Öbò# ¯

# ž†# Ê?Ê# wulskhq|odplqh# prlhw|ò# KRPR#

šžÚ# ž*# ž†# Ê?Ê# wuld}lqh# prlhw|ò# OXPR#

šž# »¯ö# J–# ››# 0818# hYÚ# 051<# hYö# 2 Z2# ¯# –# ©# ž*# –# Cò~.# Þ# æ#

²#"b~1##

+7,#LWR2®¦vÏG+SGSPD0fr0GWSP#«N#

Voltage (V)

0 2 4 6 8 10 12 14 16 18 20

Q.E. (%)

0.0000 0.0001 0.0002 0.0003

0.0004 10 wt%

20 wt%

30 wt%

50 wt%

)LJXUH  H{whuqdo# txdqwxp# hiilflhqf|# ri# LWR2#

SGSPD0fr0GWSP#dqg#GFP2Do#ghylfhv#zlwk#ydulrxv#

frqwhqwv#ri#g|h1

G

Wavelength (nm)

100 200 300 400 500 600 700 800

Intensity (A.U.)

0.0 0.2 0.4 0.6 0.8 1.0

Red (DCM) Green (Coumarin 6) Blue (DPvBi)

)LJXUH  HO# vshfwud# ri# LWR2SGSPD0fr0GWSP#

dqg#hplwwlqj#pdwhuldov#+GFP/#Frxpdulq#9/#GSyEl,2Do#

ghylfhv1

G

(8)

ž†Öb/# GFP# ¶«Öb,2Doò# ¶«&*# Ëv# 

«N# ž†Öbj¶# GSPD# ‚cNÚ# GWSP# ‚c Nò# ÞÂ# 9=7# WJ# ¶«Öbò# '^š# 63# zw(

#æ#š?#,Ú#¶«BÂÞ#2ZNb~1##

+8,#LWR2®¦vÏG+SGSPD0fr0GWSP#«N#

ž†Öb/#¶«ÖbG+GFP/#Frxpdulq#9/#GSyEl,,2Do#

¶«&*ò# ¶«SËÖöÊ# ¶«Öbò# ›¢ö# º wÞ# Oò†# GÌ̛cÞ# *&# žú# ²# "æ Þ#æ#²#"b~1##

#

þšFî’# Š.# «&Ê_G# «&Ê_# "&

F# s¶¶F_G+–¶"Ò# =# K340344,–# J_ʺ

Š&ò#Zjj#òö#Öö#j#ªFvWb~1##

#

&Î&º

# #

# 41# G1# E udxq# dqg# D1# M1# Khhjhu/# Appl. Phys. Lett1/# /#

4<;5#+4<<4,1##

# 51# V1#\1#Rk/#F1#K1#Ohh/#M1#Z1#Fkrl/#H1#V1#Mxqj/#dqg#S1#

M1#Mxqj/#Mol. Cryst. Liq. Cryst1/#/#78<#+5334,1##

# 61# V1# \1# Rk/# F1# K1# Ohh/# V1# Mxqj/# dqg# H1# Nlp/# Mol.

Cryst. Liq. Cryst1/#/#598#+5334,1##

# 71# V1#\1#Rk/#V1#Z1#Nlp/#dqg#F1#K1#Ohh/#Mol. Cryst. and Liq. Cryst1/#/#86#+5334,1##

# 81# M1Nlgr# dqg# W1Pdwvxprwr/# Appl. Phys. Lett1/# /#

5;99#+4<<;,1##

# 91# O1#F1#Sdololv/#G1#J1#Olg}h|/#P1#Uhghnhu/#G1#G1#F1#

Eudgoh|/#P1#Lqedvhndudq/#H1#S1#Zrr/#dqg#Z1#Z1##

Zx/#Synthetic Metals/#/#444#+5333,1##

# :1# H1# Dplqdnd/# W1# Wvxwvxl/# dqg# V1# Vdlwr/# Synthetic Metals/#/#533<#+4<<8,1##

# ;1# F1# Dgdfkl/# W1# Wvxwvxl/# dqg# V1# Vdlwr/# Appl. Phys.

Lett1/#/#:<<#+4<;<,1##

# <1# M1#Nlgr/#N1#Qdjdl/#dqg#\1#Rkdvkl/#Chemistry Letters, Jpn1/#+4<<3,1##

431# V1#\1#Rk/#F1#K1#Ohh/#K1#P1#Nlp/#dqg#V1#E1#Ohh/#

Mol. Cryst. Liq. Cryst1//#7:<#+5333,1##

441# M1# F1# Vfrww/# M1# K1# Ndxipdq/# S1# M1# E orfn/# U1#

Gslhuwur/#M1#Vdohlq/#dqg#M1#D1#Jrlwld/#J. Appl. Phys1/#

/#5:78#+4<<9,1##

451# I1#Fdofldool/#U1#K1#iulhqg/#V1#F1#Prudwwl/#dqg#D1#E1#

Krophv/#Synthetic Metals/#/#48:#+4<<7,1##

461# W1# Dudnl# dqg# K1# Plvdzd/# Rev. of Sci. Instru1/# /#

879<#+4<<8,1##

471# M1# U1# Vkhdwv/# K1# Dqwrqldglv/# P1# Kxhvfkhq/# Z1#

Ohrqdug/#M1#Ploohu/#U1#Prrq/#G1#Urlwpdq/#dqg#D1#

Vwrfnlqj/#Science/#/#;;7#+4<<9,1##

481# Z1#Wdfkhohw/#V1#Mdfrev/#K1#Qgd|lnhqjxuxnl|h/#K1#

M1#Jhlvh/#dqg#M1#Juxqhu/#Appl. Phys. Lett1/#/#5697#

+4<<7,1##

491# E1#Kx/#]1#\dqj/#dqg#I1#H1#Ndudv}/#Appl. Phys1/#/#

574<#+4<<7,1##

4:1# V1# \1# Rk/# F1# K1# Ohh/# K1# P1# Nlp/# M10Z1# Fkrl/#

dqg# K1# Z1# Ukhh/# Synthetic# Metals/# /# 4<8#

+5334,1# #

4;1# U1#Ilqn/#F1#Iuhq}/#P1#Wkhodnndw/#dqg#K1#Vfkplgw/#

Macromolecules/#/#;4::#+4<<:,1#

G

참조

관련 문서

The enhanced photocatalytic performance could be attributed to synergistic effects of band gap lowering, photoinduced electron-hole pair at the interface

We make performance simulations of three different organic light-emitting diodes (OLEDs), one of which is based on a conventional layered structure and the others on

• 대부분의 치료법은 환자의 이명 청력 및 소리의 편안함에 대한 보 고를 토대로

플록 구조의 측면에서 볼 때 폴리머를 일차 응집제로 사용하면 플록 강도와 크기가 향상되었지만, 다른 처리 옵션과 비교해 볼 때 플록 침전 속도에는 개선이 없었으며 유기 물질

Current density-Voltage characteristics and performance parameters of a representative DSSC fabricated by using the counter electrode having catalytic layer of platinum

Recent studies showed that a phosphonate group instead of a carboxylate group was also strongly adsorbed on the surface of nanocrystalline TiO 2 film and an

In this paper, we summarized the characteristics of ETRI's own mHEMT device with a 0.1-μm gate length and the design and results of the MMIC using it.. Based on

Methods We retrospectively reviewed the records of seven MCC patients between 2000 and 2018 from a single institution, and analyzed patient characteristics, tumor