Demo
N#
J²ö# SËÞ# Z.# böN# z*# ¶bò.#
Ã/Öö.# böN# cN# Ëò2# böN# ?
Ê# ^ò.# ò# îó# Ã/# ê# Z# [ò#
z*# Öv¶# Þ.ö# ò.# Ëbò# z*# U .# ÖF# Ã/# "~1# z*# ®¦v.# ^*j#
'ò.# Öö# Þê# N# Ã/Öö# ¬&# z*
ä/:;+SYF,2ä/:;0¢3%#
Ã\<In#§8#:¦´#Ñ.#ØJ#
##W%"Æn"%."ê.#
.)Ü*wæ!*öÞ!
)3113Ä!4C!31w!¨&-!3113Ä!:C!21w!B)*!
!
A Study on Solution Blend of Poly(vinyl chloride) with Poly(VC-co-AN)
Soo Lee
%, Gang Seok Oh, Seung Ryung Kim
., and Young Se Oh
.Department of Chemical Engineering, Changwon National University, Changwon 641-773, Korea
.R & D Center, Hanil Synthetic Fiber Co., Masan 630-791, Korea
†e-mail : slee@sarim.changwon.ac.kr (Received March 20, 2002;accepted September 10, 2002)
R k+Sro|+ylq|o# fkorulgh,+SYF,Ú# ylq|o# fkorulgh+YF,2dfu|orqlwuloh+DQ,# cÞj# Ê# sro|#
+YF0fr0DQ,Úò# ®¦v# ÞÞ# ¶ò# pruskrorj|/# ª^/# s# ª^Ë# ©# Ê^# ÖËÞ# zÊ ò~1# ®¦vò# pruskrorj|.# ²Öö# pdwul{0grpdlq# ¯vò# Þ[C^ö# «Nj¶# YF#
c# 7ú²÷# pruskrorj|.# ~&# zò~1# S# YF# c# ::154(# PR034 # ®¦vò#
WJ# SYF# hÚ# j¶# [CËÚ# J²ò~1# ®¦v# Cûò# ª^.# ²Öö# Þ[CËÖö# ò# qhjdwlyh# ghyldwlrqÞ# 2/# PR034# ®¦vj¶# SYF# c# <3(# æ# £Cö# ª^ò# 7
# Ö/# ?^ËÂ# ©# Wj# sj¶# PR034 # ®¦vò# WJ# [CË# ®¦vò# Wj# ZîÚ# W?#
ºFòÖ2#PR035#©#PR036ò##WJ#Þ[CË#®¦vò#W?Þ#2ZNb~1#SYFÚ#sro|+YF0 fr0DQ,ò# ®¦vj¶# YFò# c# ?# ,Ú# PR034Ú# <3=4 3# j¶ò# [CË# ?# N FÖ/#®¦v#Þò#Ê^#ÖËò#?[Ú#¶Fú#²#`b~1#
#
"#453"$5+Sro|+ylq|o# fkorulgh,# zdv# eohqghg# zlwk# ylq|o# fkorulgh0dfu|orqlwuloh# frsro|phuv#
+PR034+Pz@4<<37</# DQ@551:<(/# PR035+Pz@56;856/# DQ@7:136(/# PR036+Pz@#
5;<7<9/# DQ@8517<(/# PR037+Pz@674;6:/# DQ@8;19;(,# e|# pl{lqj# glphwk|oirupdplgh#
+GPI,#vroxwlrq#ri#hdfk#sro|phu#dqg#wkhlu#pruskrorj|/#ylvfrvlw|/#ylvfrhodvwlf#dqg#phfkdqlfdo#
surshuwlhv#zhuh#vwxglhg1#Eohqgv#ri#SYF#dqg#PR034#vkrzhg#d#krprjhqhrxv#pruskrorj|1#Rq#
wkh#frqwudu|/#wkh#rwkhu#frsro|phu#eohqgv#vkrzhg#d#odujh#skdvh#vhsdudwlrq#zlwk#vskhulfdo#grpdlqv1#
Plvflelolw|#ri#eohqgv#ri#SYF#dqg#PR034#zdv#vkrzq#wr#eh#ehwwhu#wkdq#wkdw#ri#eohqgv#ri#rwkhu#
frsro|phuv#iurp#pruskrorjlfdo#dqg#ylvfrhodvwlf#vwxglhv1#Hyhq#wkrxjk#eohqgv#ri#SYF#dqg#PR0 34#zhuh#revhuyhg#wr#eh#wkh#frqvlghudeoh#frpsdwlelolw|#dw#d#frpsrvlwlrq#ri#SYF2PR034@<3243/#
wkh#phfkdqlfdo#surshuwlhv#ri#eohqg#ilopv#zhuh#qrw#lpsuryhg#wrr#pxfk#lq#prvw#eohqg#fdvhv1#
#
Keywords+blend, PVC, copolymer, morphology, viscoelastic property, compatibility.
ò# ËbÞ# ZîvF# ²# "~.# ªj¶# _Öö2#
úÖö# hÚ# Þ# æz# ".# z*ò# ö# #
~1# ªö/# BÖò# Ë/# *c/# [CË# #
³Ú# # Z# .j# Ê# ÖË# Zîö~14# Ê
¶# z*# ®¦vò# [CËj# ö# # ©# ö# w ËÖò# Ê^# ÖË# ÖF# SËÞ# ¶Nú# ²# ".#
vóÞ#ØÖ¾.#¿#ö¶##òZz#"~1##
FîÞj +SYF,Ú#α# k|gurjhq# &j# òö#
²&J5# ª.# F0Fo# jurxsò# glsrodu# lqwhudfwlrq6#
?òÊ# æÒj# [CËÞ# .# z*# Öbò#
# h~1# SYFò# ª# NCCË/# NË/# NöË
# ËÞ# Þòz# ?ª# J²ö# NwË# N
zË/# 6Ë/# æÂ# Ë# Þ# vF# ²# ".#
[# z*# Öbò# ¶¶Þ# # hÚ# # z#
²b~1709# öR/# SYFÚ# dfu|orqlwuloh# ^# z*Úò#
®¦v# .:/;# qlwulohÊò# ¯ö# ËÖö# ò#
[«# ê# z*ò# ®¦v# Oö# [CË# J²ö# ®
¦v#¶òÊ.#NÏ~1##
ʶ# # j¶.# dfu|orqlwuloh# ^# z*ö¶#
SYFÚò# [CËÞ# Êú# ²# ".# ylq|o# fkorulghÚ#
dfu|orqlwuloh# «N# FCò# dfu|orqlwulohò# c j#Ê#®¦vò#[CË#Ê^#ÖËÞ#ò~1#
#
Ò Æ
º# SYF# ²Z.# ²cz«^# 4 333# öî
îó+,ò#¶"Þ#¯¶#`#FCòz/#sro|+YF0 fr0DQ,Ú#öîîó+,#ʺ&j¶#Ëö#
Öö#¯¶#`#FCòÖ/#«Nò#«ccz
*c# ©# cNò# ËÞ# Wdeoh# 4j# 2ZNb~1#
«Nò# ËÞ.# j&·Þ# O# UÚ# Q+(,# ¬Ö ö# ^Jòz/# «ccz*cÚ# JSF# ·j¶# U b~1#C¶ö#FC¶#GPI.#Wrn|r# Ndvhl#4£#vÞ#
¯¶#`#FCò~1#
úÊ2H^# ê²C# ¦># j# GPI#
¯c# òz# 93# ~# æZ# ¶¶# ö# ^# '^
# 4 :# zw(ö# ¯c¶# SYF# j# sro|+YF0fr0 DQ,# jÞ# ¶¶# Æò# ê²ò¶# j# F
Zz# Æb# ææZ# Þ# C# CvÊ~1#
CvB#ò# CûÞ#Î&Þ#43=3/#<=4 /#:=6/# 8=8/#
6=:/#4=</#3=43Öö#Öòz#krprjhql}hu#Cò
# <833# uspj¶# 8# Öò~1# Ö¶# ò#
®¦v# CûÞ# ºFªj# fdvwlqjò# 93# ~# gu|# ryhq j¶# 57v# vB# ^# ºFªj¶# ÞÞ# Fv
>z#~v#93#~#ydfxxp#ryhqj¶#7;v#ªï#
úÊaOFþ²^Ç ®¦v# Cûò# ª^
sÚ# EurrnilhogFò# frqh2sodwh# w|sh# GY0Þ.#
Ylvfrphwhu#Cò#»¯ò~1#VslqgohÚ#FS0 74/#vfò#+Ú#5#pOö#ò/#vkhdu#udwh#Zîv
j¶#¢ò~1##
2HFÖ>Z^# ®¦v# Þò# ò# pru0 skrorj|.#MhroFò#F*W +VHP/#MVP#9733, Þ#Cò# Êò~1# # æ# vRÚ# ûNb&# 'j
¶#¢ò#¶ò~1##
Çïþ²^Ç ®¦v# Þò# Â^j# Ê#
ª^Ë# sÚ# RULHQWHFFò# Ukhryleurq# +GGY0 34IS,Þ#FCò#»¯ò~1#¦²#443#K}/#S '^# 6# ~2plqÖö# ¯ò&# ºZö# ^# Â^[Sj#
Ê#vwrudjh#prgxoxv#©#wdqδ #»¯ò~1##
f* # ?ÖËÚ# RULHQWHFFò# Whq0 vlorq +DU09333,Þ#FCò#~Âj¶#DVWP#G#745#
w|sh# F# vf# vCÖö# ?'^.# 433# pp2plq# ©#
fkduw#vshhg.#433#pp2plqÖö#ò#»¯ò~1##
#
êýÎ
.PSQIPMPHZ#®¦v#Öbj¶#[CËÞ#ª^ò.#à 7DEOH # :HLJKW $YHUDJH 0ROHFXODU :HLJKW DQG
&RPSRVLWLRQRI3RO\9&.4 $1
frsro|phu#frpsrvlwlrq+zw(,a# / # produ#pdvvb# vdpsoh#
ylq|o#fkorulgh# dfu|orqlwuloh# / # 2q# 2z# 2z 2q# PR034# ::154# 551:<# 44;:33# 4<<333# 419;#
PR035# 851<:# 7:136# 469933# 56;833# 41:8#
PR036# 74165# 8;19;# 4;<633# 674;33# 41;4#
a/Frpsrvlwlrq#ri#frsro|phuv#zhuh#hvwlp dwhg#e|#hohphqwdo#
dqdo|vlv1# #
b Pq/# Pz/# dqg# Pz 2Pq# zhuh# phdvxuhg# e|# jho# shuphdwlrq#
fkurpdwrjudsk|1# #
/Öö.# ®¦vÖÞ# [«# ¦v¶# pruskrorj|#
Êò.# Ã//43# ·44# ©# s# ª^Ë# ·Þ45# O# ºF# Â^# sÖö# ª^ò.# Ã//# Fz#
lqiuduhg# vshfwuxpj¶# SË# Öò# sÖö# [CË Þ#ª^ò.###Z#"Þ#²#"~146/47#Iljxuh#4 j¶# Iljxuh# 6Ú# YFc# ~# sro|+YF0fr0DQ, Ú# SYFÚò# ®¦v# Þ# ¦ò# pruskrorj|#
2ZR# ~1# Iljxuh# 4Ú# YFò# c# ::154 (#
«N# PR034# SYFÚò# ÖÞj# Ê# ®¦v#
Þò# VHP# F^Öö# SYFò# c# hÚ# j¶#
[F# # ²/# PR034# c# hÚ# j¶
.# zö# pruskrorj|# 2ZNz# "~1# PR0342#
SYF+432<3,#®¦vò#WJ#SYF#~RG>#Nj#PR0 34# grpdlq# ¯vò# J[Öö# Fò~# PR0 34# c# 7ú²÷# ~RG># 'ò# grpdlqÚ# ª ª# J²N# PR034 # c# 83(# [ò# ®¦vj¶
.# z[Þ# z# "~1# Iljxuh# 5.# PR0# 352SYF#
®¦vò# pruskrorj|# 2ZR# ~1# PR0342SYF#
®¦vÚ# F# # Ëj¶# ò# [F# z#
"~1# PR0352SYF+83283,# ®¦vò# WJ# SYF# ~ pdlq# 'j# ~v# ²#µp# Êò# PR035# grpdlqÞ#
Êú# ²# "~1# .# ê# Öb# ö# lqwhudfwlrq# Fú# WJ# 2Z2.# [Öö# î# # ²# ".# [
~1#Iljxuh#6Ú#PR0362SYF#®¦v#Þò#VHP#
F^~1##Ëj#"N¶#PR0352SYF#®¦v#
~# ö# [F# z# "~1# PR036# J[#
WJ#Z¯¶#[Öö#grpdlqÞ#¯Ëò.#²#SYF
# J[# WJ.# ¯ò# grpdlqÞ# ¯Ëòz# "~1#
Fz# PR036ò# c# 63(# ®¦v.# SYF#
'[# ²# PR036ò# c# 83(# ®¦v.#
PR036# '[Þ# z# "N# # Ëò# .j
¶# [# NBÞ# z# "~1# ²Öö# Þ [C^# Cû# ®¦vj¶# grpdlq# ÊÚ# ¯[Ú# ê#
Öbò# ª^Âj# &# òò.# J[ò# ª^
# '[ò# ª^~# HÞ# WJ# Þ# ¯Ë¯j¶#
¶wò.# # ë¿j# ò# J[Ú# ¯j¶# Z¯
²N# Zj¯# grpdlqÞ# 2ZNz/# Ú# ²ö# J [ò# ª^# '[ò# ª^~# ,Þ# WJ# J[Ú#
¯ò#grpdlqÞ#2ZR~1#
[j¶# VHPÞ# O¶# YF# c^# DQ# «N Ú# SYF# ®¦v~ò# pruskrorj|# Êö# J# ¢ [öö# DQ# c# 7ú²÷# [F.# òÖ /#YF#c#::#zw(ö#?#hÚ#PR034#®¦v
)LJXUHVfdqqlqj#hohfwurq#plfurjudskv#ri#iudfwxuhg#furvv#vhfwlrq#ri#PR 0342SYF#eohqg#ilopv1#
# +d,#PR0342SYF#@#432<3# #+e,#PR0342SYF#@#632:3##
# +f,#PR0342SYF#@#83283# +g,#PR0342SYF#@#:3263# +h,#PR0342SYF#@#<3243#
j¶# «N# J[# æ# ²Ë# qp# Êò# gr0 pdlqÞ# z# PR034 # c# 83# zw(# [#
# æ# z[Þ# # [CË# ?# NBÞ# æ# ²#
"~1# ö# J.# >ò# s# ª^Ë# JÚ^# )LJXUHVfdqqlqj#hohfwurq#plfurjudskv#ri#iudfwxuhg#furvv#vhfwlrq#ri#PR0352SYF#eohqg#ilopv1#
# +d,#PR0352SYF#@#432<3# +e,#PR0352SYF#@#632:3#
# +f,#PR0352SYF#@#83283# +g,#PR0352SYF#@#:3263# +h,#PR0352SYF#@#<3243#
)LJXUHVfdqqlqj#hohfwurq#plfurjudskv#ri#iudfwxuhg#furvv#vhfwlrq#ri#PR0362SYF#eohqg#ilopv1#
# +d,#PR0362SYF#@#432<3# +e,#PR0362SYF#@#632:3#
# +f,#PR0362SYF#@#83283# +g,#PR0362SYF#@#:3263# +h,#PR0362SYF#@#<3243#
òòz#"~1##
þ²F^Ç ²Öö# Þ[C^# ®¦v# Cûò#
WJ# ª^.# J[# grpdlqò# ¯vÚ# Ê/# grpdlq
# grpdlqò# [Ò+C¿/# Fz# grpdlq# ' [ò# [Ò+C¿j# &# òö~1"&# #/# J[ò#
grpdlq# Ê# +Þ²÷/# grpdlq0grpdlq/# grpdlq0 pdwul{# ò# [Ò+C¿# ¯ú²÷# ®¦v# Cûò#
ª^.# [Sò&# ¶~1# Iljxuh# 7.# sro|+YF0fr0DQ,
# SYFò# # ®¦v# Cûò# ª^# Ëò# ²ö#
2ZR# ~1# PR034# ®¦v# Cûò# ª^.# #
Ëj¶# srvlwlyh# ghyldwlrqÞ# z# "Ö/# S# SYF#
c# Ú# j¶~# hÚ# j¶# # ,Ú# R
?#Þ#z#"~1# PR035#®¦v#Cûò#W J# # SYFj# ö# «Nò# c# 7ú²÷#
Cûò#ª^.#srvlwlyh#ghyldwlrqÞ#~#«
Nò# c#63# zw(#[j¶# ¯ö#qhjdwlyh#ghyld0 wlrqÞ# z# "~1# .# ø¶# ¾ö# ®Ú# ³# J[ò# *# Êj# Êö# Öö# w¶~1# SYF#
~RG># ²z# PR035# grpdlqÖö# Jº# W J# grpdlqò# Ê# +Þ# ª^# [Sòz/# Ú#
²ö# PR035# ~RG># z# SYF# grpdlq Öö# Jº# WJ# grpdlqò# Ê# Þê# z# ¯ v# ªö# ¯Ê# æÒj# ª^# HÚ# Öö# w¶
~1#PR036#®¦v#Cûò#ª^.##Ëj¶#qh0 jdwlyh# ghyldwlrqÞ# 2ZNz# "./# ö# W?Ú#
J[ò# *# Êj# Êö# Öö# VHP# JÚ#
òòz#"~1##
c[ò# DQ# c# ~# «NÚ# SYFÚò# ®
¦vò# ª^sÞ# zÊö# J# «N# «ò# DQ#
c# HÚ# «N# PR034Þ# 4 3(# ¯^# ö#
SYF#®¦vò# [CË# ?# J²"Ö/# .# Þ
ò#VHP#Ê#JÚ#òòz#"~1#
Çïþ²^Ç# Iljxuh# 8Ú# Iljxuh# 9Ú# sro|#
+YF0fr0DQ,ò# ylq|o# fkorulghÚ# dfu|orqlwulohò#
[# c# Zîj# Ê# ?^ËÂ +H′ ,# wdqδ ò# Zî# # Â^ò# ²ö# 2ZR# ~1# PR0#
34ò# WJ# ºFj# òö# H′ò# £Cö# ª&Ú#
Copolymer content (wt%)
0 20 40 60 80 100
Viscosity (poise X10-1)
0 100 200 300 400 500
MO-01/PVC MO-02/PVC MO-03/PVC
)LJXUH #Ylvfrvlw|#ri#frsro|phu2SYF#vroxwlrq#eohqgv#
lq#GPI#+4:#zw(,#dw#93#~1#
Temperature (oC)
50 100 150 200
Storage modulus (dyn/cm2)
107 108 109 1010 1011
MO-01 MO-02 MO-03
)LJXUH #Vwrudjh#prgxoxv#fxuyh#iru#wkh#frsro|phu#
ilopv1#
Temperature (oC)
50 100 150 200
Tan δ
0.0 0.2 0.4 0.6 0.8 1.0
MO-01 MO-02 MO-03
)LJXUH # Orvv# wdqjhqw# fxuyh# iru# wkh# frsro|phu#
ilopv1#
6WRUDJHPRGXOXVG\QFP
wdqδò#ö#Ö#:3#~#j¶#2Z2z/#PR0 35Ú# PR036Öö# DQò# c# 7ú²÷#
ö# s# ,Ú# Â^j¶# NBÞ# æ# ²# "~1# Fz# ºFÂ^# [j¶# ¯ö# H′# ¬# ºZ² .# zÎ[# c^Þ# 2ZN.# Ú# DQ# cNj#
òö# J¯# ÖF# ê# úÞ# òÊ# æÒ~1#
zÎ[# c^j¶# H′# ¬ò# Ê# DQ# c# 7
j# Ê# ~jÞ# æ# ²# "./# # ªö# DQ# c Nj#òö#J¯#7òÊ#æÒ~1#Fz#wdqδ {º+Iljxuh#9,j¶#DQc#7ú²÷#ö#Ö
ªÚ# ,Ú# Â^# 9Öö# sòz# Ö# Ú# ª&ò .#W?Þ#z#"~1#Wdqδ#Ö##~.#
Ú# ÞJ¯# ò# gdpslqj# ~.# Þ# òò#
#ªö#DQ#cNò#c#7ú²÷#J¯#
7ö¶#Êö~1#Iljxuh# :#;Ú# PR034 2SYF#
®¦v# Þò# Ëj# Ê# H′ # wdqδ # # Â^
²ö#2ZR#~1#PR034Ú#:3#~#j¶#H′
# £C# ª&ö# ~æ# ¯ò&# ºZ².# zÎ[# c
^# C# ¶ö# ²/# SYF.# <3# ~# j¶#
ºFö#ö#H′ #ª&#^#zÎ[#c^#~&#
îî²N# 2Z2z# "N# ÞJ¯Ë# Öb.# Þ#
~#z#"~1#SYF#c#7ú²÷#H′ò#
gdpslqj# Â^.# ,Ú# Â^# 9Öö# sòz/# wdqδ# {ºÚ#Ëj#Ê#ò2ò#Ö#2ZNb~1# F~/#
sro|+YF0fr0DQ,# SYF# ê# Öbò# wdqδ# Ö# ª
# ¶ö# «ö# Â^j# "N# [CË# ¯^j# Ê#
ºFÂ^ò# F# ÊòÊ.# ~J# ~z/# ¾ F# wdq# {ºj¶# ò2ò# Ö# ~.# Öö# [ CË# "~z# ¯òÊ.# v2/# # ~rj¶.#
pruskrorj|# ©# ª^# sj¶# ï¶# JÚ# k#
#zÊú#æ#[CË#"~z#.¯ú#²#"~1#Iljxuh#
<Ú# 4 3Ú# PR0352SYF# ®¦v# Þò# Ëj# Ê#
H′ #wdqδ ##Â^²ö#2ZR#~1#²
Öö# ºFÂ^# òj¶.# ®¦v# Ëj# Ê#
H′ò# Zî# ò# `z# ºFÂ^# [ò# zÎ[#
c^j¶.# PR035# &c# æ# ,Ú# H′ Þ#
z# "~1# .# PR035# SYF# ~RG># 'j#
grpdlqÖö# J²N# ~# grpdlq# ~RG># Jò.# ÖF# ê# z# "Ê# æÒÖö# w¶
~1# ʶ# grpdlqò# Ê# +Ú# PR0352SYF@#
432<3# ®¦vò# H′# î# ,&# 2Z2z# "~1# PR0 35# ®¦vò# wdqδ# {ºÞ# NN +Iljxuh# 43,# SYF#
c#hÚ#®¦vò#WJ#wdqδ#Ö.#SYFÚ#ºF òz/# PR035# c# hÚ# ®¦vò# WJ# wdqδ# Ö
Â^.# PR035ò# Â^# j¶# 2Z2z# "~1# .#PR034#®¦vÚ.#F#PR035#®¦vò#[C Ë#~ò~.#Þ#òö~1#Iljxuh#44#45.#
PR0362SYF# ®¦v# Þò# Ëj# Ê# H′# wdqδ
# # Â^²ö# 2ZR# ~1# ºF# [ò#
Â^j¶# PR036# c# 7ú²÷# H′ Ú# 7
ò2# PR035# ®¦v2# J[ò# grpdlqj# òö# H′#
6WRUDJHPRGXOXVG\QFP
Temperature (oC)
50 100 150 200
107 108 109 1010 1011
MO-01/PVC = 0/100 MO-01/PVC = 10/90 MO-01/PVC = 30/70 MO-01/PVC = 50/50 MO-01/PVC = 70/30 MO-01/PVC = 90/10 MO-01/PVC = 100/0
)LJXUH # Vwrudjh# prgxoxv# fxuyh# iru# wkh# PR0 342SYF#eohqg#ilopv1#
Temperature(oC)
50 100 150 200
tanδ
0.0 0.2 0.4 0.6 0.8 1.0
MO-01/PVC = 0/100 MO-01/PVC = 10/90 MO-01/PVC = 30/70 MO-01/PVC = 50/50 MO-01/PVC = 70/30 MO-01/PVC = 90/10 MO-01/PVC = 100/0
)LJXUH # Orvv# wdqjhqw# fxuyh# iru# wkh# PR0342SYF#
eohqg#ilopv1#
7[Ú# 2Z2Z# äò~1# Fz# wdqδ# {ºj¶# ®
¦v# Ëj# Ê# ö# Ö# Â^.# PR035# ®¦v Ú#ÞQö#sÞ#z#"~1##
[# ³# # ®¦vò# s# ª^Ë# sÞ# zÊ ö# J# [CË# »j¶# PR034 # ®¦v# ?# J
²òz#~æ#PR035/#PR036#¶Öö#ø¶#prusk0 rorj|#©#ª^#zÊò#JÚ#òò~1#
²ï*# ²Öö# z*# ®¦vò# Ê^#
ÖËÚ# # [CË# «ö# ËÞ# Z.# Öö#
æ¾Ò# "Ö/# # ·j# ö# ^# h# z¶#
[v~1# z*# ®¦v# Þ# J²ö# [CËÞ# b# æ# # Ë.j# j# ®¦v# Ëòz# ".#
# ¶²# z*~ò# Ê^# ÖË~ò# Jº# cz¬#
~#,ZF~.#z#"~1"'#2#[CË#®
¦v# Þ[CË# ®¦v~# Ê^# ÖË# ²vv#
J²ö#Ú#Þb/#®¦vò#Ê^#ËbÚ#prusk0 rorj|j#&#òö~1#Iljxuh#46Ú##®¦v#Þ
ò# # lqlwldo# prgxoxv# ®¦v# Ëò# ²ö# 2Z R# ~1# PR034ò# SYF# ®¦vò# WJ# SYF
# hÚ# j¶.# qhjdwlyh# ghyldwlrqÞ/# PR034 )LJXUH # Vwrudjh# prgxoxv# fxuyh# iru# wkh# PR0
352SYF#eohqg#ilopv1#
Temperature(oC)
50 100 150 200
107 108 109 1010 1011
MO-02/PVC = 0/100 MO-02/PVC = 10/90 MO-02/PVC = 30/70 MO-02/PVC = 50/50 MO-02/PVC = 70/30 MO-02/PVC = 90/10 MO-02/PVC = 100/0
Temperature(oC)
50 100 150 200
tan δ
0.0 0.2 0.4 0.6 0.8 1.0
MO-02/PVC = 0/100 MO-02/PVC = 10/90 MO-02/PVC = 30/70 MO-02/PVC = 50/50 MO-02/PVC = 70/30 MO-02/PVC = 90/10 MO-02/PVC = 100/0
)LJXUH #Orvv#wdqjhqw#fxuyh#iru#wkh#PR0352SYF#
eohqg#ilopv1#
6WRUDJHPRGXOXVG\QFP 6WRUDJHPRGXOXVG\QFP
Temperature (oC)
50 100 150 200
107 108 109 1010 1011
MO-03/PVC = 0/100 MO-03/PVC = 10/90 MO-03/PVC = 30/70 MO-03/PVC = 50/50 MO-03/PVC = 70/30 MO-03/PVC = 90/10 MO-03/PVC = 100/0
)LJXUH # Vwrudjh# prgxoxv# fxuyh# iru# wkh# PR0 362SYF#eohqg#ilopv1#
Temperature (oC)
50 100 150 200
tanδ
0.0 0.2 0.4 0.6 0.8 1.0
MO-03/PVC = 0/100 MO-03/PVC = 10/90 MO-03/PVC = 30/70 MO-03/PVC = 50/50 MO-03/PVC = 70/30 MO-03/PVC = 90/10 MO-03/PVC = 100/0
)LJXUH #Orvv#wdqjhqw#fxuyh#iru#wkh#PR0362SYF#
eohqg#ilopv1#
# hÚ# j¶.# srvlwlyh# ghyldwlrqÞ# z# "
~1#PR035Úò#WJ#Ëj#j¶#dgglwlyh#uxoh j# ¶# srvlwlyh# ghyldwlrqÞ# z# "./# .#
J[ò# grpdlq# uhlqiruflqj# Bj# Êö# Ö ö# B^~1# PR036ò# SYF# ®¦vò# WJ# ²
Öö# ö# qhjdwlyh# ghyldwlrqÞ# .# .# J[# ~RG>ò# ö# [Fj# Êö# Öö#
ª¶~1#Iljxuh#47.# # ®¦v# Þò# ¢#Z¯
úÞ# ®¦v# Ëò# ²ö# 2ZR# ~1# Ò# ò#
®¦v# Þ# Bê# dgglwlyh# uxohj# ¶# qhjdwlyh#
ghyldwlrqÞ# z# "Ö/# # ö# ¯^.# PR0 36/# PR035/# PR034ò# ®¦v# ¶Öö# 2ZF~1#
Iljxuh# 48.# # ®¦v# Þò# ¢# ë¿Þ# ®¦v#
Ëò# ²ö# 2ZR# ~1# PR034# ®¦vò# W J# PR034 # c# hÚ# j¶# dgglwlyh# uxohj#
# srvlwlyh# ghyldwlrq# # ²/# PR034# c#
Ú# j¶.# qhjdwlyh# ghyldwlrqÞ# z# "~1#
öR/#PR035Ú#PR036#®¦v.#Bê#ö#qhjd0 wlyh# ghyldwlrqÞ# z# ".# .# pruskrorj|j
¶# Êö# ®Ú# ³# ö# [Fj# òö# Öö# ª
¶~1#
#
N
#
SYFÚ# YF2DQ# cÞj# Ê# sro|+YF0fr0DQ, Úò# ®¦v# Cû# ÞÞ# ¶ò# pruskrorj|/#
ª^/# s# ª^Ë# ©# Ê^ÖËÞ# # zÊö# J# ~æ
#³Ú#JúÞ#Ub~1#
41# SYFÚ# sro|+YF0fr0DQ,ò# ®¦v.# ²
Öö# pdwul{0grpdlq# ¯vò# Þ[C^ö# «Nj
¶# YF# c# 7ú²÷# pruskrorj|.# ~&# z
ò~1#S/#DQ#c#551:<(#PR034ò#®
¦vò#WJ##SYF#hÚ#j¶#[CËÚ#J
²ò~1#
51# ®¦v# Cûò# ª^.# ²Öö# Þ[CËÖö#
ò# qhjdwlyh# ghyldwlrqÞ# 2/# PR034ò#
®¦vj¶# # SYF# c# <3(# æ# £Cö# ª
Copolymer content (wt%)
0 20 40 60 80 100
Initial Modulus( kg/mm2
X
109 )
0 5 10 15 20 25 30 35
MO-01/PVC MO-02/PVC MO-03/PVC
)LJXUH # Lqlwldo# prgxoxv# fxuyh# iru# wkh# frsro|0 phu2SYF#eohqg#ilopv#dw#73# ~1#
7HUVLOHVWUHQJWKNJPP
Copolymer content (wt%)
0 20 40 60 80 100
0 5 10 15 20
MO-01/PVC MO-02/PVC MO-03/PVC
)LJXUH # Whqvloh# vwuhqjwk# fxuyh# iru# wkh# frsro|0 phu2SYF#eohqg#ilopv1#
Copolymer content (wt%)
0 20 40 60 80 100
Elongation (%)
0 50 100 150 200 250 300
MO-01/PVC MO-02/PVC MO-03/PVC
)LJXUH #Horqjdwlrq#fxuyh#iru#wkh#frsro|phu2SYF#
eohqg#ilopv1#
^ò#7#~1#
61# s# ª^Ë# »¯Öö# H′# ©# Wj# sÞ# zÊö#
J# PR034# SYF# ®¦vò# WJ# [CË# ®¦v ò# Wj# ZîÚ# W?# ºFòÖ2# PR035# ©#
PR036ò# WJ# Þ[CË# ®¦vò# W?Þ# 2ZNb
~1#
71# ®¦v# Þò# Ê^# ÖË# »¯j¶# ¢Ê^Ë Â1# ?¯^/# horqjdwlrq# # ²Öö# ª&ò
Ö/# s# ª^Ë# ©# ª^# »¯# Jö# [CË# J
²ö# j¶ò# PR034ò# SYF#®¦v# WJj^#
Ê^#ÖË#?[Ú#Êú#²#`b~1#
#
& Î & º
# #
# 4 1# Z1# –V1# Nlp/# L1# K1# Nlp/# V1# F1# Ndqj/# W1# Prul/# \1#
Wvxgd/# dqg# N1# U1# Kd/# Polymer(Korea)/# /# 854#
+5334,1#
# 51# H1#S1#Olhehupdq/#Off. Dig., Fed. Soc. Paint Technol1/#/#
63#+4<95,1#
# 61# D1# Jduwrq/# P1# Dxelq/# dqg# U1# H1# Suxg*krpph/# J.
Polym. Sci1/#/#66<+4<;6,1#
# 71# J1# Y1# Ylqrjudgry/# Y1# G1# Ilnkpdq/# dqg# Y1# P1#
Dohnvh|hyd/#Polym. Eng. Sci./#/#64:+4<:5,1#
# 81# F1# Ohgrxv# dqg# D1# Gh# Yulhv/# X1# V1# Sdwhqw#
6/9:6/49:+4<:5,1#
# 91# O1# Jrug/# “Pdq0pdgh# ileuhv/#Vflhqfh# dqg# Whf0 kqrorj|”/# hg1# K1# I1# Pdun/# et al.,# yro1# 6/# s1# 65:/#
Lqwhuvflhqfh/#Qhz#\run/#4<9;1## #
# :1# \1# V1# Rk/# V1# U1# Nlp/# V1# Ohh/# dqg# E1# N1# Nlp/# J1#
Macromol. Sci. Phys1/##+6,/#538#+4<<8,1#
# ;1# \1#V1#Rk/#V1#Ohh/#dqg#E1#N1#Nlp/#J. Appl. Polym. Sci1/#
/#4<6:#+4<<:,1#
# <1# Y1# Kxhofn/# G1# D1# Wkrpdv/# dqg# K1# Vshuolqj/#
Macromolecules/#/67;#+4<:5,1#
431# V1#F1#Nlp/#G1#Nohpsqhu/#N1#F1#Iulvfk/#K1#O1#Iulvk/#
dqg#K1#Jkludghood/#Polym. Eng. Sci1/#/#66<#+4<:8,1#
441# W1# N1# Nzhl/# J1# G1# Sdwwhuvrq/# dqg# W1# W1# Zdqj/#
Macromolecules/#/#:;3#+4<:9,1#
451# W1#Pxud|dpd/#J. Appl. Polym. Sci1/#/#58<6+4<:9,1#
461# F1#V1#S1#Vxqj#dqg#Q1#V1#Vfkqhlghu/#Macromolecules/#
/#9;#+4<:8,1###
471# P1#P1#Frohpdq/#M1#]duldq/#G1#I1#Yduqho/#dqg#S1#F1#
Sdlqwhu/#J. Polym. Sci., Polym. Lett. Ed1/#/#:78#+4<::,1###
481# D1#Uxglq/#K1#O1#Z/#Krhj|/#dqg#K1#N1#Mrkqvwrq/#J.
Appl. Polym. Sci1/#/#45;4#+4<:5,1#
491# \1#Qrmlpd/#dqg#K1#Wdfkledqd/#Plastic Age/#/#444#
+4<;8,1#