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Ultra-Clean Patterned Transfer of Single-Layer Graphene by Recyclable Pressure Sensitive Adhesive Films

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제 50 회 동계학술대회 301

TT-P006

Ultra-Clean Patterned Transfer of Single-Layer Graphene

by Recyclable Pressure Sensitive Adhesive Films

Sang Jin Kim1, Bora Lee2, Yong Seok Choi2, Philip Kim3, James Hone4,

Byung Hee Hong2 and Sukang Bae1

1Institute of Advanced Composite Materials, Korea Institute of Science and Technology 2Department of Chemistry, Seoul National University 3Department of Physics, Harvard University

4Department of Mechanical Engineering, Columbia University

We report an ultraclean, cost-effective, and easily scalable method of transferring and patterning large-area graphene using pressure sensitive adhesive films (PSAFs) at room temperature. This simple transfer is enabled by the difference in wettability and adhesion energy of graphene with respect to PSAF and a target substrate. The PSAF transferred graphene is found to be free from residues, and shows excellent charge carrier mobility as high as ~17,700 cm2/V·s with less doping compared to the graphene transferred by thermal release tape (TRT) or poly(methyl methacrylate) (PMMA) as well as good uniformity over large areas. In addition, the sheet resistance of graphene transferred by recycled PSAF does not change considerably up to 4 times, which would be advantageous for more cost-effective and environmentally friendly production of large-area graphene films for practical applications.

Keywords: clean transfer, supporting polymer recycle, graphene patterning, surface wetting, adhesion energy

TT-P007

Sr-doped AlOx gate dielectrics enabling high-performance flexible

transparent thin film transistors by sol-gel process

Jaeyoung Kim1, Seungbeom Choi1, and Yong-Hoon Kim1,2*

1SKKU Advanced Institute of Nanotechnology (SAINT), Sungkyunkwan University, Suwon 440-746, Korea 2School of Advanced Materials Science and Engineering, Sungkyunkwan University, Suwon 440-746, Korea

Metal-oxide thin-film transistors (TFTs) have gained a considerable interest in transparent electronics owing to their high optical transparency and outstanding electrical performance even in an amorphous state. Also, these metal-oxide materials can be solution-processed at a low temperature by using deep ultraviolet (DUV) induced photochemical activation allowing facile integration on flexible substrates [1]. In addition, high-dielectric constant (k) inorganic gate dielectrics are also of a great interest as a key element to lower the operating voltage and as well as the formation of coherent interface with the oxide semiconductors, which may lead to a considerable improvement in the TFT performance.

In this study, we investigated the electrical properties of solution-processed high-k strontium-doped AlOx (Sr-AlOx) gate dielectrics. Using the Sr-AlOx as a gate dielectric, indium-gallium-zinc oxide (IGZO) TFTs were fabricated and their electrical properties are analyzed. We demonstrate IGZO TFTs with a 10-nm-thick Sr-AlOx gate dielectric which can be operated at a low voltage (~5 V).

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