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A study on the synthesis of Polyhydroxybenzoate ester Dendrimers

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42 2006년 한국생명과학회 추계학술대회

P19

A study on the synthesis of Polyhydroxybenzoate ester Dendrimers

임우진, 조혜진, 최순규, 정대일, 한정태1

동아대학교 화학과, 1영동대학교 뷰티케어학과

Dendrimers was synthesized as various purpose-luminescence device, nano materials and life science, etc-since 1980's. Polyphenol have recently been used as antioxidant, antiphlogistics and antimicro bialactivity.

Polyphenol produces singlet oxygen in the presence of hydrogen peroxide in an alkaline medium and emits light. The CL intensities of polyphenol are very weak. Thus trans-4-(3-Propionic acid) phenyl- boronic acid, 4-Biphenyl-boronic acid in the presence of peroxidase or 1-ethyl-3-(3-dimethylami- no-propyl)carbodiimide have been used as enhancer for highly sensitive polyphenol CL determination.

This point, we designed new types of polyphenol dendrimers having an increased number of chem- iluminophores for high luminescence intensity and hydroxyl groups in periphery to form hydrogen bonds.

Now we report the synthesis of various polyphenol dendrimers. And we report a study about the physical properties(PL, CL, etc) as a result of modification of core and structure change of polyphenol dendrimers.

P20

Characteristics of seed to calcium-enhanced rice plants expressing the Arabidopsis Ca

2+

/H

+

antiporter gene

Kyung-Min Kim*, Dai-Hee Kim, Ji-Hee Nam1, Hyun-Suk Lee1, Jae-Keun Sohn1

Department of Environmental Horticulture, College of Life Science and Natural Resources, Sangju National University, Sangju, Kyungbuk, 742-711, Korea.

1Division of Plant Biosciences, Department of Agriculture and life Sciences, Kyungpook National University, Daegu, 702-701, Korea

This study was carried out to analyze the mineral contents including calcium in brown rice for the rice plants transformed with CAX1 gene (accession no. U57411). In the previous study the transgenic rice plants over-expressing the Arabidopsis Ca2+/H+ antiporter CAX1 gene were developed using Agrobacterium-mediated transformation method. The calcium contents in brown rice of the transgenic rice plants were ranged from 1.2 to 5.2 times, however, that of donor cultivar. SEM (scanning electronic microscope) analysis showed that the starch structure of transgenic rice comprised round and tightly packed granules compared with wild type.

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관련 문서

Thus, condensation of 4-(3,4-di- methoxy-phenyl)-5-phenylsulfanyl-thiazol-2-ylamine (3) and its sulfone (4) with phenacyl bromides yielded the hydrobromide salts

The presence of 2,4-dichloro, 2-chloro, 4-nitro and 2-bromo groups attached to the phenyl group at position 2 of the thiazolidin-4-ones ring showed good activity against all

It was treated with methyl (triphenylphosphoranylidene) acetate (2) in refluxing THF with catalytic amounts of benzoic acid. 11) Trans enonate 3 with D-arabino configuration

4치환 Phenyl Ethyl Benzylphosphonate 의 알칼리 가수분해 반응에 대한 속도론적 연구 301 는 단순 정제를 통해 회수하였다.. 또한 합성 과정에서 얻은 ethyl benzylphos-

Aldol condensation of 2[2,-(4-phenyl-3-butenyl)]-l,3-oxazole-4-carboxaldehyde(4a) with lithium enolate of methyl propionate provided the discokiic acid methyl ester.. The

thiazin-3-yl)acetamido]-3-heterocyclothiomethyl-3-cephem-4-carboxylic acid derivatives(2a^-2d) were synthesized. Antibacterial activities of these new cephalosporin derivatives

Not only cyclization of 3 in the presence of performic acid gave desired product 4 but also thermal reaction in boiling n- butanol also gave desired product1. The

Methods: ETS-4 (2-(2-mercaptoethylthio)-3-{2-[3-mercapto-2-(2-mercaptoethylthio)propyl thio]ethylthio}propane -1-thiol), which is optical lens monomer resin having super