Surface treatment of vulcanized rubber by ArF excimer laser

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(5) 334. 7²æ B 13² B 4^,. j 8ú. 2002. æ &ê Ã&¢ Ã& B 227 mJ/cm öBº â 4(c)¾" «¶ ÚÒ& jêjê oöB æ N ê R ôjr æò 7OKf 6²® . ©f .& 7 Ò *f Þ® 'Ú ¢~² >ÚB 7OKf 280 N/mb ·~æò ö.æ & ê~ Ã&º Þ® ~ Ã& '~ Ã&öò jî¢ æ N ~ Bb 7OB& Ê Ú& 7OK Ã&>î . ¾ z× Ã&º jêjê z ô o~, æ N ê ôjræò, .& ö.æö ~ ~ ² b Z& æW>Ú 7OK 6²>î ' B . 2. IV.. Ö . &~Zº 2® ÷7 ÷^ ªÊ .& 7~ ¾ Òö ~ 7OK Ëç>î . .& 7 Ò >~ Ã&ö V¢, 7OKf Ã&~ Ò > 100²öB 1500 N/m~ &Ë 8j áî . ¾ ç~ Ò >öBº 1420 N/m b 6²~& . ©f .& 7~ Òö ~ ¦ö B î B~ V~ æzö ~ R>Î"& B®V r^î . 6 ö.æ &ê Ã&ö V 7OK f Ã&~ ö.æ &ê 176 mJ/cm öB &Ë 7OK 1500 N/m¢ á² >î . ¾ ö.æ &ê¢ z Ã& Ê 6²¢ &^z . ö.æ &ê~ Ã&º Þ® ~ Ã& '~ Ã&öò jî¢ æ N ~ B b 7OB& Ê Ú& 7OK~ Ã&¢ &^z º ©j r~ . 2. ^^ò. â 4. .& 7 Ò * " ê~ SEM ç (a) .& 7 Ò ìr, (b) .& 7 176 mJ/cm Ò, (c) .& 7 227 mJ/cm Ò. 2. 2. & Z~ SEM Òêj ¾æÚî . .& 7 Ò * f â 4(a)ö ¾æÞ ©¾" ~ æz& ~ ì ¢ ~² >Ú®æò, ö.æ &ê Ã&ö V .& 7 Òº â 4(b)¾" 176 mJ/cm öB «¶~ ÚÒ& æ² >Ú ®j öò jî¢ Þ® ê &V>Ú '~ Ã&ö ò jî¢ æ N b 7OB& Ê Ú& ÎÚæV& Ú[² >Ú &Ë 7OK B~& . ¾ z× ö. 2. [1] J. V. Pascale, T. D. Benedicts and P. M. Rentzepis, “The effect of oxidation inhibitors on mechanochemical processes in rubber,” Polym. Sci., vol. 7, no. 4, pp. 2206-2211, 1965. [2] M. M. Kadasd and C. G. Seefried, “Closer characterization of corona-treated PE surfaces,” Plastic Eng. vol. 41, no. 12, pp. 45-48, 1985. [3] M. Strobel, C. Dunatov, J. M. Strobel, C. S. Lyons, S. J. Perron and M. C. Morgen, “Low-molecular-weight materials on corona-treated polypropylene,” J. Adh. Sci. Tech, vol. 3, no. 5, pp. 321-335, 1989. [4] J. A. Lanauze. and D. L. “Myers, Ink adhesion on coronatreated polypropylene studied by chemical derivatization of surface functional groups,” J. Appl. Pol. Sci. vol. 40, no. 34, pp. 595-611, 1990. [5] J. Y. Lai, Y. Y. Lin, Y. L. Denq, S. S. Shyuand and J. K. Chen, “Surface modification of silicone rubber by gas plasma treatment,” J. Adh. Sci. Tech., vol. 10, no. 3, pp. 231-242, 1996..

(6) Ó¢^ÔArF ÷^ .&ö ~ &~ Z~ ¾Ò /" Surface treatment of vulcanized rubber by ArF excimer laser Bong Ju Lee† Division of Physics and Chemistry, College of Nature Science, Chosun University, Kwangju 501-759, KOREA † E-mail: [email protected]. (Received January 28, 2002 ; revised manuscript received June 17, 2002). Surface treatment was carried out by an Excimer Pulse laser beam in order to increase the adhesive strength of vulcanized rubber. With increasing number of laser beam irradiations, the adhesive strength was greatly increased; the adhesive strength was 1,500 N/m after irradiation 100 times. The energy density increase was in direct proportion to the adhesive strength increase; the maximum value of the adhesive strength was 1,500 N/m at the energy density of 176 mJ/cm2. It was concluded that the increase of surface area was relevant to that of both energy density and adhesive strength Classification code : LO.050.. 335.

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