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Interface and Crystallinity of 1,4,5,8,9,11-Hexaazatriphenylene-hexanitrile thin films between an Organic and Transparent Conductive Oxide layers

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Academic year: 2021

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248 한국진공학회

TF-017

Interface and Crystallinity of

1,4,5,8,9,11-Hexaazatriphenylene-hexanitrile thin films

between an Organic and Transparent Conductive Oxide layers

이현휘1, 이정환2, 김장주3, 김효정4

1포항가속기연구소, 2Large Area Electronics Group, IMEC, Kapeldreef, Belgium, 3서울대학교, 4

부산대학교 We have investigated the crystallinity, preferential ordering, and interfacial stability of 1,4,5,8,9,11-hexaa-zatriphenylene-hexanitrile (HATCN) thin film interconnected with organic/inorganic multilayer. At the region close to the organic-organic interface, HATCN formed low crystalline order with substantial amorphous phase. As film growth continued, HATCN stacked with high crystalline phase. After a sputtering deposition of the indium zinc oxide (IZO) layer on top of HATCN/organic layer, the volume fraction of preferentially ordered HATCN crystals increased without any structural deterioration. In addition, the HATCN surface was kept quite stable by preserving the sharp interface between HATCN and sputtering deposited IZO layers.

Keywords: 1,4,5,8,9,11-hexaazatriphenylene-hexanitrile (HATCN); crystal; interface; IZO; GIWAXS; x-ray

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