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Epitaxial growth of GaN thin films on atomically stepped lithium niobate (LiNbO

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168 한국진공학회

TF-P015

Epitaxial growth of GaN thin films on atomically stepped lithium niobate

(LiNbO

3

) substrates

Man Hoai Nam, Minsun Kim, Minho Lee, Younsik Park, Jiwon Sung, and WoochulYang*

Department of Physics, Dongguk University, Seoul 100-715, KOREA

*corresponding Author: [email protected]

This study presents the growth of epitaxial thin film of GaN on atomically flat lithium niobate (LiNbO3)substrates by molecular beam epitaxy(MBE). High temperature treatment of as-received LiNbO3 wafers has been carried out to obtain atomically flat surface and to remove the surface damage due to mechanical polishing. Annealing at 1000oC for 2hrs. produces the optima lsurface smoothness. The microsteps are nearly parallel and periodical most all over the sample. AFM measurements displayed that the step height on Z-cut substrates was 0.27 nm, which was well accordance with the distance between oxygen layers along the c-axis of the hexagonal unit cell of LiNbO3 crystals. Also, the step terrace width is about 200 nm and the surface roughness is 0.111 nm for a scan area of a 3µm x 3µm. We obtained GaN films with relatively high quality on the atomically-flat LiNbO3 substrates with AlN buffer layers. The structural and optical properties were performed by XRD, PL, and AFM measurements. The full-width-at-half maximum (FWHM) values of the XRD (0002) GaN rocking curves were 122.14 arcsec and 168.80 arcsec for GaN film grown on the positive side (+z-LiNbO3) and negative side (-z-LiNbO3), respectively. AFM measurements showed that the RMS value of GaN films are 0.䴀 9 nm for the z -LiNbO– 3 substrate and 1.0 nm for the+z -LiNbO3, respectively. The optical properties of these samples were characterized by photoluminescence (PL) measurement using a He-Cd laser ( 325nm) as the excitation source at room temperature. The typical PL spectrum of GaN film grown on the both side of LiNbO3 substrate reveals a strong band-edge emission peak at 360nm(3.45eV). We will discuss that the effects of the polarity of the LiNbO3 subtrates on the crysta lstructure and polarity of GaN films.

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