Elements Cd Cr Pb

(1)

PLASTIC Reference materials

NMIJ CRMs

● NMIJ CRM 8102-a (pellet)

Heavy metals (Cd, Cr, Pb) in ABS resin-low concentration pellet (25g)

Elements Cd Cr Pb

Certified values 10.77 27.87 108.9 mass fraction (mg/kg)

● NMIJ CRM 8103-a (pellet)

Heavy metals (Cd, Cr, Pb) in ABS resin-high concentration pellet (25g)

Elements Cd Cr Pb

Certified values 106.9 269.5 1084 mass fraction (mg/kg)

● NMIJ CRM 8105-a (disk)

Heavy metals (Cd, Cr, Pb) in ABS resin-low concentration disk (30mm dia. x 2mm thick.)

Elements Cd Cr Pb

Certified values 10.77 27.87 108.9 mass fraction (mg/kg)

● NMIJ CRM 8106-a (disk)

Heavy metals (Cd, Cr, Pb) in ABS resin-high concentration disk (30mm dia. x 2mm thick.)

Elements Cd Cr Pb

Certified values 107.4 268.1 1076.9 mass fraction (mg/kg)

● NMIJ CRM 8112-a (pellet)

Heavy metals (Cd, Cr, Hg, Pb) in ABS resin-low concentration pellet (25g)

Elements Cd Cr Hg Pb

Certified values 9.383 94.47 94.10 94.98

mass fraction (mg/kg)

(2)

● NMIJ CRM 8113-a (pellet)

Heavy metals (Cd, Cr, Hg, Pb) in ABS resin-high concentration pellet (25g)

Elements Cd Cr Hg Pb

Certified values 93.93 943.6 941.5 945.0 mass fraction (mg/kg)

● NMIJ CRM 8115-a (disk)

Heavy metals (Cd, Cr, Hg, Pb) in ABS resin-low concentration disk (30mm dia. x 2mm thick.)

Elements Cd Cr Hg Pb

Certified values 9.341 94.27 93.81 94.21 mass fraction (mg/kg)

● NMIJ CRM 8116-a (disk)

Heavy metals (Cd, Cr, Hg, Pb) in ABS resin-high concentration disk (30mm dia. x 2mm thick.)

Elements Cd Cr Hg Pb

Certified values 93.67 943.7 938.7 940.6 mass fraction (mg/kg)

● NMIJ CRM 8108-a (disk)

Polybrominated diphenyl ethers in polystyrene (29.8mm dia. x 1.974mm thick.: 5 pcs / unit)

CAS Number

Certified value:

mass fraction (mg/kg)

Expanded uncertainty

(mg/kg) decabrominated diphenyl ether 1163-19-5 317 14

JSAC CRMs

● JSAC CRM 0601-2 (chips)

Plastics (polyester) for Chemical Analysis (50g)

Elements Cd Cr Hg Pb

Certified values 5.2 10.8 1.3 11.6

mass fraction (mg/kg)

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Page 1 of 3

EUROPEAN COMMISSION

J OINT RESEARCH CENTRE

Ins titute for Referenc e Materials and Meas urem ents

MATERIAL INFORMATION

IRMM – 310 (it not CRM, but QC)

Poly(ethyleneterephthalate) (PET) with added PBDEs and PBBs for RoHS testing

DESCRIPTION

IRMM-310 consists of poly(ethyleneterephthalate) (PET) granulate that has been fortified with commercially available PET with technical mixtures of Penta-BDE, Octa-BDE and Deca-BDE as well as Deca-BB. It is available in brown glass bottles containing approximately 10 g material.

Homogeneity: Homogeneity tests performed by X-ray fluorescence (WDXRF) showed a relative between-bottle variation of the total Br-content of less than 0.40 %.

Stability: Stability of the total Br-content was tested on samples stored for 1, 2 and 3 weeks at 60 °C, 8 weeks at 20 °C. In addition, samples were UV irradiated for 17 and 40 hours in their bottles to check for the influence of sunlight on the closed bottles. All samples were analysed by WDXRF. No significant decrease of the Br content of these samples occurred in these treatments, showing that no evaporation of PBBs and PBDEs had taken place over this period.

ASSIGNED VALUES

• Total Penta-, Octa-, Deca-BDE ande Deca-BB: Nominal contents of Penta-, Octa- and Deca-BDE as well as Deca-BB are calculated from the amount of PBBs and PBDEs added. Total bromine content was calculated from certificates of analysis obtained for technical products from the same producers, but from different production batches.

Measurements by neutron activation analysis (k

0

NAA) agree with this calculated Br content within ± 15 %, confirming absence of severe errors in the preparation.

• Congener composition: Informative congener composition was calculated from certificates of analysis obtained for technical products from the same producers, but from different production batches. Results from an interlaboratory comparison with 37 sets of results confirm these indicative congener composition.

• Total Br content: Total Br-content was measured by neutron activation analysis with

k

0

standardisation and was confirmed by results obtained independently by another

laboratory using X-ray fluorescence spectrometry.

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Page 2 of 3

Material Information

Mass Fraction Value Unit Technical pentabrominated diphenylether (Penta-BDE)

¹

700 mg/kg Technical octabrominated diphenylether (Octa-BDE)

¹

400 mg/kg Technical decabrominated diphenylether (Deca-BDE)

¹

700 mg/kg Technical decabrominated biphenyl (Deca-BB)

¹

700 mg/kg

total tri-BDEs

²

3 mg/kg

total tetra-BDEs

²

, of which 244 mg/kg

sum BDE42 + BDE66

²

6 mg/kg

BDE49

²

5 mg/kg

BDE47

²

227 mg/kg

total penta-BDEs

²

, of which 392 mg/kg

BDE85

²

17 mg/kg

BDE99

²

307 mg/kg

BDE100

²

63 mg/kg

total hexa-BDEs

²

, of which 94 mg/kg

BDE138

²

6 mg/kg

BDE139

²

5 mg/kg

BDE153

²

52 mg/kg

BDE154

²

27 mg/kg

total hepta-BDEs

²

, of which 161 mg/kg

BDE183

²

150 mg/kg

total octa-BDEs

²

, of which 143 mg/kg

BDE196

²

37 mg/kg

BDE197

²

86 mg/kg

BDE203

²

16 mg/kg

total nona-BDEs

²

77 mg/kg

BDE209

²

689 mg/kg

BB209

²

700 mg/kg

total Br

³

2.30 ± 0.12 g/kg

total Sb

³

0.98 ± 0.05 g/kg

1) Calculated from the amount of technical mixtures added. The values are confirmed by measurement of the total Br-content and the results of an intercomparison.

2) Calculated from the amount of technical mixtures added and certificates of analysis of technical products from the same suppliers but of different batches. The values are confirmed by the result of an intercomparison.

3) Determined by neutron activation analysis with k

0

standardisation (k

0

NAA) and confirmed by X-ray-

fluorescence spectromety (XRF). Values are mean values ± expanded uncertainties with a k-factor of 2,

corresponding to a level of confidence of about 95 %.

(5)

Page 3 of 3 European Commission – Joint Research Centre

Institute for Reference Materials and Measurements (IRMM) Retieseweg 111, 2440 Geel (Belgium)

Telephone: +32-(0)14-571.722 - Telefax: +32-(0)14-590.406

SAFETY INFORMATION

The usual laboratory safety precautions apply.

INSTRUCTIONS FOR USE

The material IRMM-310 has been designed to fill an urgent need for reference materials for PBBs and PBDEs in connection with Directive 2002/95/EC on the “Reduction of the use of certain hazardous substances in electrical and electronic equipment” (RoHS). It will be eventually replaced by certified reference materials. In the meantime, the material can be used by laboratories to perform a rough confirmation of the performance of their method and the accuracy of statement of RoHS compliance.

The minimum sample intake is 100 mg for the polybrominated flame retardants and 250 mg for total Br and Sb.

Draft IEC Standard IEC 62321 recommends cryogenic milling with nitrogen cooling of the material to particle sizes < 0.5 mm.

STORAGE

The test material shall be stored at +4 °C in the dark.

The European Commission cannot be held responsible for changes that can take place during storage of the material at the customer's premises, especially of opened samples.

DISCLAIMER

IRMM-310 is not a certified reference material. In addition, homogeneity and stability of the brominated flame retardant content has not been tested, but was inferred from homogeneity and stability of the total Br-content.

The values are theoretically calculated and naturally only approximations of the true value. The figures should be regarded as guide values only and not as binding values.

LEGAL NOTICE

Neither IRMM, its subsidiaries, its contractors nor any person acting on their behalf.

(a) make any warranty or representation, express or implied that the use of any information, material, apparatus, method or process disclosed in this document does not infringe any privately owned intellectual property rights; or

(b) assume any liability with respect to, or for damages resulting from, the use of any information, material, apparatus, method or process disclosed in this document save for loss or damage arising solely and directly from the negligence of IRMM or any of its subsidiaries.

Geel, Belgium, May 2007

Signed:

Prof. Dr. Hendrik Emons Unit for Reference Materials EC-DG JRC-IRMM

Retieseweg 111

2440 Geel, Belgium

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● JSAC CRM 0602-2 (chips)

Plastics (polyester) for Chemical Analysis (50g)

Elements Cd Cr Hg Pb

Certified values 51.7 108.8 12.4 109.3 mass fraction (mg/kg)

● JSAC CRM 0611 – 0615 (disk)

Plastics (polyester) for Fluorescent X-ray Analysis (40mm dia. x 4.0mm thick.: 5 pcs / set)

CRM Elements Certified value Pb Reference value Less than 1 Cd Reference value Less than 1 JSAC 0611

(for blank test) Cr Reference value Less than 1

Pb 26.1

Cd 4.5

JSAC 0612

Cr 25.5

Pb 54.6

Cd 10.0

JSAC 0613

Cr 52.0

Pb 106.8

Cd 23.8

JSAC 0614

Cr 98.6

Pb 202.2

Cd 43.4

JSAC 0615

Cr 212.8 mass fraction (mg/kg)

● JSAC CRM 0621 – 0625 (disk)

Plastics (polyester) for Fluorescent X-ray Analysis of Trace Mercury (40mm dia. x 4.0mm thick.: 5 pcs / set)

CRM Elements Certified value JSAC 0621

(for blank test)

Reference value Less than 1

JSAC 0622 Hg 10.0

JSAC 0623 Hg 49.0

JSAC 0624 Hg 121.1

JSAC 0625 Hg 244.4

mass fraction (mg/kg)

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● JSAC CRM 0631 and JSAC CRM 0632 (disk)

Plastics (polyester) for Fluorescent X-ray Analysis (40mm dia. x 4.0mm thick.: 2 pcs / set)

CRM Elements Certified value

Pb 24.5 Cd 22.5 Cr 25.8 JSAC 0631

Hg 19.7 Pb 92.9 Cd 46.1 Cr 93.3 JSAC 0632

Hg 59.4 mass fraction (mg/kg)

● JSAC CRM 0651 - JSAC CRM 0655 (disk)

Plastics (polyester) for Fluorescent X-ray Analysis of Bromine (40mm dia. x 4.0mm thick.: 5 pcs / set)

CRM Elements Certified value JSAC 0651

(for blank test)

Br Reference value Less than 1

JSAC 0652 Br 105.8

JSAC 0653 Br 292.6

JSAC 0654 Br 595

JSAC 0655 Br 993

mass fraction (mg/kg)

JFE RMs

● JSM P 700-1

● JSM P 701-1

Plastic (polyethylene) reference material for chemical analysis (grain: 50g)

Item No. Cd Pb Hg Cr As Br Cl S

Unit (μg/g) （mass %）

JSM P 700-1 5.0 5.0 5.3 4.9 9.1 0.002* 0.004* 0.006*

JSM P 701-1 113.5 111.3 111.6 114.8 187.3 0.05* 0.06* 0.04*

*) non-certified value

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● JSM P 710-1

Plastic (polyethylene) reference material for X-ray fluorescence analysis (plate) (30mm x 30mm x 3mm thick.: 7 pcs / set)

Item No. Cd Pb Hg Cr As Br

Unit (μg/g) （%）

a <1 <1 <1 <1 <1 <0.001*

b 5 5 5 5 9 0.002*

c 50 50 51 52 86 0.035*

d 114 111 112 115 187 0.05*

e 264 270 254 265 478 0.15*

f 522 532 546 515 907 0.27*

JSM P 710-1

g 1.11x10

³

1.12x10

³

1.09x10

³

1.10x10

³

1.95x10

³

0.62*

*) non-certified value

Note) Not every analyzer gets accurate result by the effect of coexistent materials.

Result accuracy (check your analyzer by the chart and the linearity of the calibration curve.)

Analysis Cd Pb Hg Cr As Br

Wavelength dispersive X-ray fluorescence analysis (WDX) ○ ○ ○ ○ ○ △ Energy dispersive X-ray fluorescence analysis (EDX) ○ ○ ○ ― ― △

SCAS RMs

Drift correction sample (Cr, Cd, Hg, Pb, Br-containing sample)

● PVC-5E6 (C-H-C-E): Vinyl chloride resin (6 level)

● PE-5E6 (C-H-B-F): Polyethylene resin (LDPE) (6 level) Cd 0, 25, 50, 75, 100, 300 (ppm) Pb

Hg Cr Br

0, 50, 100, 300, 600, 1200 (ppm)

Size: 48mm dia. × 5mm thick.

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● PVC-5E2 (C-H-C-E): Vinyl chloride resin (2 level)

● PE-5E2 (C-H-B-F): Polyethylene resin (LDPE) (2 level) Cd 0, 300 (ppm)

Pb Hg Cr Br

0, 600 (ppm)

Size: 48mm dia. × 5mm thick.

IJE RMs

Drift correction samples

● IJE PVC-CD-PB: PVC resin (Cd and Pb),

● IJE PE-CD-PB: Polyethylene resin (Cd and Pb)

IJE PVC-CD-PB IJE PE-CD-PB Cd 5, 10, 25, 45, 100 ppm 0, 5, 11, 30, 60, 120 ppm Pb 5, 10, 25, 50, 100 ppm 0, 5, 11, 30, 60, 120 ppm Size

(Quantity)

25 ×40 × 6 (t) mm (each level × 1 pc,

10 pcs / set)

24.5 ×39.0 × 6.2 (t) mm (0 ppm × 1 pc + each level × 1 pc,

11 pcs / set)

Note: Cd and Pb are contained in separate plate

● IJE PVC-30: PVC resin (Cd, Pb, Cr, Br),

● IJE PVC-40: PVC resin (Hg)

IJE PVC-30 IJE PVC-40 Plate No. Cd Pb Cr Br Plate No. Hg

PVC00 <1 <2 <5 <20 PVC00 <1

PVC31 24 26 24 28 PVC41 26

PVC32 50 53 44 46 PVC42 51

PVC33 99 110 84 93 PVC43 130

PVC34 240 290 210 240 PVC44 290 PVC35 490 530 370 470 PVC45 630 PVC36 1000 1120 1020 970 PVC46 1250

Size (Quantity)

25 x 39.5 x 2mm (each 3 pc, 21 pcs / set)

mass fraction (ppm)

(10)

● IJE ABS-30: ABS resin (Cd, Pb, Cr, Br),

● IJE ABS-40: ABS resin (Hg)

IJE ABS-30 IJE ABS-40 Plate No. Cd Pb Cr Br Plate No. Hg

ABSC00 <1 <2 <5 <20 ABS00 <1

ABS31 23 27 31 32 ABS41 29

ABS32 45 41 50 54 ABS42 56

ABS33 92 77 110 110 ABS43 110

ABS34 240 230 290 280 ABS44 300 ABS35 490 480 560 550 ABS45 590 ABS36 980 1010 1010 960 ABS46 1160

Size (Quantity)

25 x 39.5 x 2mm (each 3 pc, 21 pcs / set)

mass fraction (ppm)

● IJE PBDE-ABS-PE: ABS and PE resin (PBDE)

ABS base PE base PBDE 1000, 9600, 98000 ppm 950 ppm

Size (Quantity)

25 x 39.5 x 2mm

(each 3 pc, 12 pcs / set)

(11)

Hg Pb

74XCA2 - % wt 3.50 0.0002 0.0100 0.0014 0.0329 0.0010 0.782 0.00 21 0.0007 0.0062 0.0308 0.005 5 0.0331 (0.0048 ) 0.0737 0.0015 0.0003 74X CA4· % wt 2.95 0.0002 0.017 1 0.0021 0.0641 (0.0001) 0.473 0.007 0.0015 0.0040 0.065 (0.00 13) 0.0621 (0.0056) 0.041 0.0065 0.0008 74XCAS· % wt 4.01 (0.0003 ) 0.0353 0.0049 0.0207 0.0025 1.098 0.0019 0.0006 0.0111 0.0147 0.0108 0.0116 0.0005 0.133 0.003 0.0009 74XCA6 -% wt 0.282 0.0006 0.0086 0.0106 0.008 7 0.00033 0.629 0.0061 0.0064 0.0218 0.0 194 0.0046 0.0174 (0.0008) 0.0078 0.000 7 0.0006 74X CA7 - % wt 4.21 ... ^0.0095 ^... ^0.0081 ^0.0045 ^0.333 ^0.0047 ^0.053 ^0.0026 ^0.0007 ^0.003 ^0.0965 ... 0.0 103 ... . ..

74XCA8 - %wt 2,44 ... 0.0100 ... 0.0032 0.0103 0.947 0.0037 0.101 0.0041 0.0007 0.00 77 0.0403 . .. ^0.0045 .. .

."

Copper Alloys Ag AI As Au B Be Bi Cd Co Cr Fe Mg Mn NI Pb 5b

58

51 5n Te Zn 39 X 17866· ppm 61 <10 400 ... ... ⁽¹⁾ ⁶³ 327 229 15 101 2 1.6 548 240 58 30

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2100 53 340 39 X 17868 " ppm 250 1390 294 220 30 13 430 330 480 2000 470 470 580 330 380 330 40 1000 350 320 390 39 X 17869 - ppm 440 6 137 90 ... ...

440

85 133 2.3 230 4 13 144 478 389 63 en ¹⁵⁰ ³²³ ¹¹⁰

39 X 17871 - ppm 270 (2) 290 45 (2) 4 700 32 8 2 20 (2) 10 275 90 180 280 (3) (20) 110 8

5U5 RC11 • ppm ... 4 1 ...

^.

.. ... 1 1 3

.. .

5 ... 1 5 2 1 1 1 4 1 2

5U5-RC12· %wt ... 0.3 0.15 .. . ... 0 0.015 0.03 0.1 ... 0.2 .

..

0.2 0.5 0.08 0.04 0.02 0.2 0.5 0.02 0.6

Aluminum Alloys As Cd Cr Cu Fe Hg Mg Mn Nl Pb 51 n V Zn Zr

350/02·

%

wt <0.00003 <0.00002 0.0009 0.149 0.46 1 <0.00005 1.08 1.16 0.003 0.00066 0.255 0.0246 0.0114 0.0522 0.005 351/02· % wt 0.00 135 0.0013 (0.001) (0.15) (0.46) 0.00094 (1.08) (1.16) (0 .003) 0.0025 (0.26) (0. 02 5) (0.0 11) (0.052 ) (0.005) 352102·

%

wt 0.00142 0.0021 (0.0007) (0.15) (0.48) 0.0022 (1.06) (1.13) (0.003) 0.0039 (0.26) (0.019) (0.0 1) (0. 049) (0 .005) 353/02 ·

%

wt 0.0061 0.005 (0.00 1) (0.15) (0 ,46) 0.0059 ( 1.08) (1.16) (0.003) 0.0053 (0.26) (0.02 5) (0.011 ) (0.052) (0 .005) 354102 -

%

wt 0.0121 0.01 (0.001) (0.15) (0.46) 0.0099 (1.08) (1.16) (0. 003) 0.0101 (0.26) (0.025) (0.0 11) (0.052) (0.005)

Iron Alloys

AI

As B C Co Cr Cu Mn Mo N Nb Ni 0 P Pb 5 51 5n n V Zr 182A·

%

wt 0.020 0 .008 0.0003 0.20 0.011 0.56 0.23 0.90 0.18 0.0067 0.003 0.50 0.00 14 0.028 0.14 0.023 0.25 0.01 2 0.005 0.005 <0.003 183B - % wt

[0.0031

[O.DOll [0.002] (0.073] [0.005] [0.046] (0.021] (1.08) (0.006] [0.003] (0.001 [0.024] (0.0 14] (0.060] [0.28) (0.33] (0.004] (0.002] (0.001] (0.003] (0.002)

PVC Materials

Sr

Hg

Cr Pb

Cd

PVC-H-03A • oom 1101 1101 1001 1201 300

PVC-L-04A - ppm 500 200 400 400 100

PVC-01A - ppm 0 0 0 0

0

PE Materials

Sr

Hg

Cr

Pb Cd

PE-H-04A • ppm 1100 1100 1001 1200 300

PE-L-04A - ppm 502 201 400 400 100

PE-02A· ppm 0 0 0 0 0

SAC30S & SAC405 Check Set

5n Pb Cu BI Ag Hg P

5AC30S

-%

wt

Bal.

0.076 0.49 0.004 3.00 0.0016 0.004 5AC405 - % wt

Bal.

<0 .001 0.46 - 4.01 0.0002 0.006

XRF Glasses·

Sr

Hg Cr Pb Cd

BR-ROH5 1/3 - ppm 0

0 0 0

0 BR-ROH5 213 - ppm 1000 0 1000 1000 100

BR ROHS 3/3 • ppm 5000 0 5000 5000 1000

"Matrix : Sicj=53%,Na²⁰=17%,CaO=10%. AI~J=7% , Mg0=6G;I,. 8^203=4%, Sb^Z0 ³=1%

(12)

4 LGC Standards - Excellence throught measurement December 2007 Quality Control Material - Batch Number 001

Expiry date: November 2008 Indicative values

Complex cyanide... 72 mg/kg Free cyanide... < 2.5 mg/kg Total cyanide ... 72 mg/kg LOI... 6.7 mg/kg pH... 8.1 mg/kg Sulfide ... 29 mg/kg Thiocyanate... < 5 mg/kg Total sulfate... 7000 mg/kg Water-soluble boron... 2.1 mg/kg Water-soluble chloride ... 150 mg/kg Water-soluble fluoride ... 2.6 mg/kg Water-soluble sulfate 2:1 ... 3400 mg/kg Water-soluble sulfate 5:1 ... 5000 mg/kg

LGCQC3009-5 Silt clay soil - Inorganics

Quality Control Material - Batch Number 001 Expiry date: November 2008

5 x 150 g 1282,00

LGCQC3009-10 Silt clay soil - Inorganics

Quality Control Material - Batch Number 001 Expiry date: November 2008

10 x 150 g 1282,00

Standards from Cambridge Isotope Laboratories (CIL)

RoHS standards from CIL

Code Product Unit Price €

CIL-EO-5402 ROHS PBDE Calibration Solution CS1-CS5 (Unlabelled/

¹³

C

12

,99%)

Solvent: Nonane

All concentrations are in ng/mL

Unlabelled Congener BDE# CS1 CS2 CS3 CS4 CS5

4-MonoBDE ...3 ...1... 5... 20... 100 ... 500

2,4-DiBDE ...7 ...1... 5... 20... 100 ... 500

4,4'-DiBDE ...15 ...1... 5... 20... 100 ... 500

2,2',4-TriBDE ...17 ...1... 5... 20... 100 ... 500

2,4,4'-TriBDE ...28 ...1... 5... 20... 100 ... 500

2,2',4,4'-TetraBDE ...47 ...1... 5... 20... 100 ... 500

2,2',4,5'-TetraBDE ...49 ...1... 5... 20... 100 ... 500

2,3',4,4'-TetraBDE ...66 ...1... 5... 20... 100 ... 500

2,3',4',6-TetraBDE ...71 ...1... 5... 20... 100 ... 500

3,3',4,4'-TetraBDE ...77 ...1... 5... 20... 100 ... 500

2,2',3,4,4'-PentaBDE ...85 ...1... 5... 20... 100 ... 500

2,2',4,4',5-PentaBDE ...99 ...1... 5... 20... 100 ... 500

2,2',4,4',6-PentaBDE ...100 ...1... 5... 20... 100 ... 500

2,3',4,4',6-PentaBDE ...119 ...1... 5... 20... 100 ... 500

3,3',4,4',5-PentaBDE ...126 ...1... 5... 20... 100 ... 500

2,2',3,4,4',5'-HexaBDE ...138 ...2... 10... 40... 200 ... 1000

2,2',4,4',5,5'-HexaBDE ...153 ...2... 10... 40... 200 ... 1000

2,2',4,4',5,6'-HexaBDE ...154 ...2... 10... 40... 200 ... 1000

2,2',4,4',6,6'-HexaBDE ...155 ...2... 10... 40... 200 ... 1000

2,3,4,4',5,6-HexaBDE ...166 ...2... 10... 40... 200 ... 1000

2,2',3,4,4',5,6-HeptaBDE ...181 ...2... 10... 40... 200 ... 1000

2,2',3,4,4',5',6-HeptaBDE ...183 ...2... 10... 40... 200 ... 1000

2,3,3',4,4',5,6-HeptaBDE ...190 ...2... 10... 40... 200 ... 1000

2,2',3,4,4',5,5',6-OctaBDE ...203 ...2... 10... 40... 200 ... 1000

2,3,3',4,4',5,5',6-OctaBDE ...205 ...2... 10... 40... 200 ... 1000

2,2',3,3',4,4',5,5',6-NonaBDE ...206 ...5... 25... 100... 500 ... 2500

2,2',3,3',4,4',5,6,6'-NonaBDE ...207 ...5... 25... 100... 500 ... 2500

DecaBDE...209 ...5... 25... 100... 500 ... 2500

13C12-Labelled Congener BDE# CS1 CS2 CS3 CS4 CS5 4-MonoBDE (¹³C12,99%)...3 ...100... 100... 100... 100 ... 100

4,4'-DiBDE (¹³C12,99%) ...15 ...100... 100... 100... 100 ... 100

2,4,4'-TriBDE (¹³C12,99%)...28 ...100... 100... 100... 100 ... 100

2,2',4,4'-TetraBDE (¹³C12,99%)...47 ...100... 100... 100... 100 ... 100

2,2',4,4',5-PentaBDE (¹³C12,99%)...99 ...100... 100... 100... 100 ... 100

2,2',3,4,4',5-HexaBDE (¹³C12,99%) ...138 ...200... 200... 200... 200 ... 200

2,2',4,4',5,5'-HexaBDE (¹³C12,99%) ...153 ...200... 200... 200... 200 ... 200

2,2',4,4',5,6'-HexaBDE (¹³C12,99%) ...154 ...200... 200... 200... 200 ... 200

2,2',3,4,4',5',6-HeptaBDE (¹³C12,99%) ...183 ...200... 200... 200... 200 ... 200

2,2',3,4,4',5,6,6'-OctaBDE (¹³C12,99%) ...204 ...200... 200... 200... 200 ... 200

2,2',3,3',4,4',5,6,6'-NonaBDE (¹³C12,99%) ....207 ...500... 500... 500... 500 ... 500

DecaBDE (¹³C12,99%) ...209 ...500... 500... 500... 500 ... 500

5 x 0.2 mL 2430,00

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December 2007 LGC Standards - Excellence through measurement 5

CIL-EO-5403 ROHS PBDE Clean-up Spike (

¹³

C

12

,99%)

Solvent: Nonane

Component BDE# Concentration

(ng/mL)

4-MonoBDE (¹³C12,99%) ... 3... 100

4,4'-DiBDE (¹³C12,99%)... 15... 100

2,4,4'-TriBDE (¹³C12,99%) ... 28... 100

2,2',4,4'-TetraBDE (¹³C12,99%) ... 47... 100

2,2',4,4',5-PentaBDE (¹³C12,99%) ... 99... 100

2,2',4,4',5,5'-HexaBDE (¹³C12,99%)... 153... 200

2,2',4,4',5,6'-HexaBDE (¹³C12,99%)... 154... 200

2,2',3,4,4',5',6-HeptaBDE (¹³C12,99%) ... 183... 200

2,2',3,4,4',5,6,6'-OctaBDE (¹³C12,99%) ... 204... 200

2,2',3,3',4,4',5,6,6'-NonaBDE (¹³C12,99%)... 207... 500

DecaBDE (¹³C12,99%)... 209... 500

1.2 mL 751,00 CIL-EO-5404 ROHS PBDE Syringe Spike (

¹³

C

12

,99%)

Solvent: Nonane 2,2',3,4,4',5-HexaBDE (¹³C12,99%) (BDE 138) ... 200 ng/mL

1.2 mL 243,00 CIL-EO-5405 ROHS PBDE Native PAR Spike

Solvent: Nonane Component BDE# Concentration (ng/mL) 4-MonoBDE... 3... 1000

2,4-DiBDE ... 7... 1000

4,4'-DiBDE ... 15... 1000

2,2',4-TriBDE... 17... 1000

2,4,4'-TriBDE... 28... 1000

2,2',4,4'-TetraBDE ... 47... 1000

2,2',4,5'-TetraBDE ... 49... 1000

2,3',4,4'-TetraBDE ... 66... 1000

2,3',4',6-TetraBDE... 71... 1000

3,3',4,4'-TetraBDE ... 77... 1000

2,2',3,4,4'-PentaBDE... 85... 1000

2,2',4,4',5-PentaBDE... 99... 1000

2,2',4,4',6-PentaBDE... 100... 1000

2,3',4,4',6-PentaBDE... 119... 1000

3,3',4,4',5-PentaBDE... 126... 1000

2,2',3,4,4',5'-HexaBDE ... 138... 2000

2,2',4,4',5,5'-HexaBDE ... 153... 2000

2,2',4,4',5,6'-HexaBDE ... 154... 2000

2,2',4,4',6,6'-HexaBDE ... 155... 2000

2,3,4,4',5,6-HexaBDE ... 166... 2000

2,2',3,4,4',5,6-HeptaBDE ... 181... 2000

2,2',3,4,4',5',6-HeptaBDE... 183... 2000

2,3,3',4,4',5,6-HeptaBDE ... 190... 2000

2,2',3,4,4',5,5',6-OctaBDE... 203... 2000

2,3,3',4,4',5,5',6-OctaBDE... 205... 2000

2,2',3,3',4,4',5,5',6-NonaBDE ... 206... 5000

2,2',3,3',4,4',5,6,6'-NonaBDE ... 207... 5000

DecaBDE ... 209... 5000

1.2 mL 783,00

POPs standards from CIL

CIL-ES-5400 POPS Clean-up Spike (

¹³

C,99%)

Solvent: Nonane

Hexachlorobenzene (¹³C6,99%) ... 200 ng/mL Aldrin (¹³C12,99%) ... 200 ng/mL Dieldrin (¹³C12,99%) ... 200 ng/mL Endrin (¹³C12,99%) ... 200 ng/mL 4,4'-DDT (¹³C12,99%) ... 200 ng/mL 4,4'-DDE (¹³C12,99%) ... 200 ng/mL 4,4'-DDD (¹³C12,99%) ... 200 ng/mL 2,4'-DDT (¹³C12,99%) ... 200 ng/mL 2,4'-DDE (¹³C12,99%) ... 200 ng/mL 2,4'-DDD (¹³C12,99%) ... 200 ng/mL trans-Chlordane (gamma) (¹³C10,99%) .... 200 ng/mL trans-Nonachlor (¹³C10,99%) ... 200 ng/mL cis-Nonachlor (¹³C10,99%)... 200 ng/mL Oxychlordane (¹³C10,99%)... 200 ng/mL Heptachlor (¹³C10,99%) ... 200 ng/mL cis-Heptachlor Epoxide (¹³C10,99%)... 200 ng/mL Mirex (¹³C10,99%) ... 200 ng/mL alpha-BHC (¹³C10,99%) ... 200 ng/mL beta-BHC (¹³C10,99%)... 200 ng/mL Lindane (gamma-BHC) (¹³C6,99%)... 200 ng/mL delta-BHC (¹³C6,99%) ... 200 ng/mL

1.2 mL 500,00

(14)

6 LGC Standards - Excellence throught measurement December 2007 Solvent: Nonane

Hexachlorobenzene ... 200 ng/mL Aldrin ... 200 ng/mL Dieldrin ... 200 ng/mL Endrin... 200 ng/mL 4,4'-DDT ... 200 ng/mL 4,4'-DDE... 200 ng/mL 4,4'-DDD... 200 ng/mL 2,4'-DDT ... 200 ng/mL 2,4'-DDE... 200 ng/mL 2,4'-DDD... 200 ng/mL trans-Chlordane (gamma) ... 200 ng/mL cis-Chlordane (alpha)... 200 ng/mL trans-Nonachlor... 200 ng/mL cis-Nonachlor ... 200 ng/mL Oxychlordane ... 200 ng/mL Heptachlor... 200 ng/mL trans-Heptachlor Epoxide... 200 ng/mL cis-Heptachlor Epoxide ... 200 ng/mL Mirex... 200 ng/mL alpha-BHC... 200 ng/mL beta-BHC ... 200 ng/mL Lindane (gamma-BHC) ... 200 ng/mL Delta-BHC ... 200 ng/mL

Mixed bromo/chlorobiphenyl standards

CIL-EBC-5390 PXB Calibration solutions CS1-CS5 (unlabelled/

¹³

C

12

,99%)

Solvent: Nonane

All concentrations are in ng/mL

Unlabelled Compounds CS1 CS2 CS3 CS4 CS5

4'-Bromo-2,3',4,5-TetraCB ... 2... 10 ... 50 ...200 ... 200

4'-Bromo-2,3,3',4-TetraCB ... 2... 10 ... 50 ...200 ... 200

4'-Bromo-2,3,3',4,5-PentaCB ... 2... 10 ... 50 ...200 ... 200

4'-Bromo-3,3',4,5,5'-PentaCB ... 2... 10 ... 50 ...200 .... 1000

3,4-Dichloro-3',4',5'-TriBB ... 4... 20 ... 100 ...400 ... 2000

13C-Labelled Compounds CS1 CS2 CS3 CS4 CS5 4'-Bromo-3,3',4,5-TetraCB (¹³C12,99%)... 100... 100 ... 100 ...100 ... 100

4'-Bromo-2,3',4,5-TetraCB (¹³C12,99%)... 100... 100 ... 100 ...100 ... 100

4'-Bromo-2,3,3',4-TetraCB (¹³C12,99%)... 100... 100 ... 100 ...100 ... 100

4'-Bromo-2,3,3',4,5-PentaCB (¹³C12,99%)... 100... 100 ... 100 ...100 ... 100

4'-Bromo-3,3',4,5,5'-PentaCB (¹³C12,99%) ... 100... 100 ... 100 ...100 ... 100

3,4-Dichloro-3',4',5'-TriBB (¹³C12,99%)... 100... 100 ... 100 ...100 ... 100

2,2',3,4,5,5'-HexaCDE (¹³C12,99%) ... 100... 100 ... 100 ...100 ... 100

5 x 0.2 mL 2430,00

CIL-EBC-5389 PXB Clean-up Spike (

¹³

C

12

,99%)

Solvent: Nonane

4'-Bromo-3,3',4,5-TetraCB (¹³C12,99%)... 1000 ng/mL 4'-Bromo-2,3',4,5-TetraCB (¹³C12,99%)... 1000 ng/mL 4'-Bromo-2,3,3',4-TetraCB (¹³C12,99%)... 1000 ng/mL 4'-Bromo-2,3,3',4,5-PentaCB (¹³C12,99%)... 1000 ng/mL 4'-Bromo-3,3',4,5,5'-PentaCB (¹³C12,99%) ... 1000 ng/mL 3,4-Dichloro-3',4',5'-TriBB (¹³C12,99%)... 2000 ng/mL

1.2 mL 1944,00

CIL-EO-5388 PXB Syringe Standard (

¹³

C

12

,99%)

Solvent: Nonane

2,2',3,4,5,5'-HexaCDE (¹³C12,99%) ... 1000 ng/mL

1.2 mL 371,00

CIL-EBC-5387 PXB Native PAR Solution

Solvent: Nonane

4'-Bromo-3,3',4,5-TetraCB ... 1000 ng/mL 4'-Bromo-2,3',4,5-TetraCB ... 1000 ng/mL 4'-Bromo-2,3,3',4-TetraCB ... 1000 ng/mL 4'-Bromo-2,3,3',4,5-PentaCB ... 1000 ng/mL 4'-Bromo-3,3',4,5,5'-PentaCB ... 1000 ng/mL 3,4-Dichloro-3',4',5'-TriBB ... 2000 ng/mL

0.5 mL 535,00

Perfluorinated compounds

We are very pleased to announce that

¹³

C

9

-Perfluorononanoic acid (PFNA) is now available from stock!

The new

¹³

C

9

-PFNA standard provides several advantages to the PFC researcher:

- Uniformly-labeled (¹³C9) standard offering a superior M+9 mass differential from native.

- Isomeric composition >99% linear chain.

CIL-CLM-8060-1.2 Perfluorononanoic acid (PFNA) (

¹³

C

9

,99%) 50 µg/mL in Methanol 1.2 mL 492,00

CIL-ULM-8066-1.2 Perfluorononanoic acid (PFNA) (unlabelled) 50 µg/mL in Methanol 1.2 mL 94,00

(15)

(16)

10 LGC Standards - Excellence throught measurement December 2007

IPO F 022 Sodium benzoate (E 211) 250 mg 27,00

Food contaminated standards

ERM-AC057 Aflatoxin B1 in acetonitrile

Compound Certified value Uncertainty

Aflatoxin B1 ... 3.79 µg/g ... 0.30 µg/g

ampoule 230,00

ERM-AC058 Aflatoxin B2 in acetonitrile

Aflatoxin B2 ... 3.80 µg/g ... 0.08 µg/g

ampoule 230,00

ERM-AC059 Aflatoxin G1 in acetonitrile

Aflatoxin G1... 3.78 µg/g ... 0.13 µg/g

ampoule 230,00

ERM-AC060 Aflatoxin G2 in acetonitrile

Aflatoxin G2... 3.80 µg/g ... 0.07 µg/g

ampoule 230,00

ERM-AC699 Zearalenone in acetonitrile

Zearalenone ... 9.95 µg/mL ...0.30 µg/mL

amp. 110,00

B-MYC0430-1.2 Fumonisin B3 (U-

¹³

C

34

) 10 µg/mL in acetonitrile/water (1:1) CERTAN

^®

1.2 mL 454,00 B-MYC0423-1.2 Fumonisin B2 (U-

¹³

C

34

) 10 µg/mL in acetonitrile/water (1:1) CERTAN

^®

1.2 mL 454,00

B-MYC0457-1 Mycophenolic acid 100 µg/mL in acetonitrile 1 mL 50,00

B-MYC0457 Mycophenolic acid 100 µg/mL in acetonitrile 5 mL 142,00

B-MYC0520-1 Sterigmatocystin 50 µg/mL in acetonitrile 1 mL 50,00

B-MYC0520 Sterigmatocystin 50 µg/mL in acetonitrile 5 mL 142,00

Shellfish toxins

NRCCRM-CYN Cylindrospermopsin solution

Each ampoule contains approximately 0.5 mL of solution with 30 ± 2 mmoles/L (12.6 ± 0.8 µg/L at 20 °C) of cylindrospermopsin in filtered, deionized water.

0.5 mL 176,00

NRCCRM-DCNEO Decarbamoylneosaxitoxin solution

Each ampoule contains approximately 0.5 mL of solution with 30 ± 1µmoles/L of decarbamoylneosaxitoxin in filtered and aqueous 0.003 M hydrochloric acid.

0.5 mL 176,00

NRCCRM-AZA1 Azaspiracid-1 solution

Each ampoule contains approximately 0.5 mL of solution with 1.47 ± 0.08 µmol/L AZA1 in methanol.

0.5 mL 176,00

Industrial matrix reference materials

ERM-EC680K Polyethylene - Trace elements (low level)

Certified values

As ... 4.1 mg/kg Hg ... 4.64 mg/kg Br... 96 mg/kg Pb ... 13.6 mg/kg Cd... 19.6 mg/kg S ... 76 mg/kg Cl... 102.2 mg/kg Sb ... 10.1 mg/kg Cr ... 20.2 mg/kg

100 g 120,00

ERM-EC681K Polyethylene - Trace elements (high level)

Certified values

As ... 29.1 mg/kg Hg ... 23.7 mg/kg Br... 0.77 g/kg Pb ... 98 mg/kg Cd... 137 mg/kg S ... 0.63 g/kg Cl... 0.8 g/kg Sb ... 99 mg/kg Cr ... 100 mg/kg

100 g 120,00

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65 Cd in polyethylene (VDA 001-004)

A set of four certified reference materials for Cd in polyethylene (40.9 mg/kg, 75.9 mg/kg, 197.9 mg/kg and 407 mg/kg) has been certified by IRMM on behalf of VDA (Verband der Automobilindustrie e.V., Frankfurt). Information can be obtained from IRMM, Geel (B).

5.3 OTHERS

Antimony implanted in silicon ERM-EG001 (BAM-L001)

Certified quantity Certified value

(10¹⁶·cm^-2)

Areal density of Sb atoms 4.81 ± 0.06

Isotope amount ratio n(¹²¹Sb) / n(¹²³Sb) 1.435 ± 0.006 Availability: The sample is a 10 mm x 10 mm silicon chip with a thermally grown surface oxide layer and Sb ions implanted with an energy of

400 keV. The certified value for the areal density of Sb atoms is valid for fractions of the chip surface down to 0.15 mm² in size.

6 MATERIALS RELATED TO ISOTOPIC MEASUREMENTS

6.1 CERTIFIED FOR ISOTOPE ABUNDANCE RATIO

BCR-123 Ethanol

Parameter Ethanol H Ethanol M Ethanol L

(D/H)I 109.65 × 10⁻⁶ ± 0.20 × 10⁻⁶ 101.69 × 10⁻⁶ ± 0.17 × 10⁻⁶ 90.30 × 10⁻⁶ ± 0.18 × 10⁻⁶ (D/H)II 119.76 × 10⁻⁶ ± 0.25 × 10⁻⁶ 130.94 × 10⁻⁶ ± 0.21 × 10⁻⁶ 122.20 × 10⁻⁶ ± 0.4 × 10⁻⁶

R 2.184 ± 0.005 2.575 ± 0.006 2.708 ± 0.009

Availability: Units of 3 sealed NMR tubes containing respectively H-, M-, and L-ethanols, to which the tetramethylurea internal standard and the C6F6 lock substance are added. 10 mm (BCR-123A) or 15 mm (BCR-123B) O.D. NRM tubes can be supplied.

Parameter Unit BCR-656 (96% ethanol)

BCR-657 (Sugar)

BCR-658 (Synthetic wine)

BCR-659 (Synthetic wine)

BCR-660 (Ethanol in water)

(D/H)I by ²H-NMR ppm 102.84 ± 0.20 102.90 ± 0.16

(D/H)II by ²H-NMR ppm 132.07 ± 0.30 131.95 ± 0.23

R by ²H-NMR 2.570 ± 0.005 2.567 ± 0.005

δ¹³CVPDB by IRMS ‰ -26.91 ± 0.07 -10.76 ± 0.04 -26.72 ± 0.09 δ¹⁸OVSMOW of water from

wine by IRMS

‰ -7.19 ± 0.04 -7.18 ± 0.02

(D/H)w of water (IRMS) ppm 148.68 ± 0.14

Alcoholic grade tD w/w % 94.61 ± 0.05 11.96 ± 0.06 ¹⁾

1) in v/v %

Availability: BCR-656: Units of 25 mL of 96 % vol. neutral ethanol from wine in glass bottle;

BCR-657: Units of approx. 1 g of dry glucose in a sealed amber vial;

BCR-658: Units of 25 mL of synthetic wine solution in glass bottle;

BCR-659: Units of 25 mL of synthetic wine solution in glass bottle;

BCR-660: Units of 450 mL of aqueous ethanol solution in glass bottle.