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9. Statistical Physics

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http://optics.hanyang.ac.kr/~shsong

Modern Physics for Scientists and Engineers International Edition, 4th Edition

1. THE BIRTH OF MODERN PHYSICS 2. SPECIAL THEORY OF RELATIVITY

3. THE EXPERIMENTAL BASIS OF QUANTUM PHYSICS 4. STRUCTURE OF THE ATOM

5. WAVE PROPERTIES OF MATTER AND QUANTUM MECHANICS I 6. QUANTUM MECHANICS II

7. THE HYDROGEN ATOM 8. ATOMIC PHYSICS

9. STATISTICAL PHYSICS

10. MOLECULES, LASERS, AND SOLIDS

11. SEMICONDUCTOR THEORY AND DEVICES 12. THE ATOMIC NUCLEUS

13. NUCLEAR INTERACTIONS AND APPLICATIONS 14. PARTICLE PHYSICS

15. GENERAL RELATIVITY

16. COSMOLOGY AND MODERN ASTROPHYSICS

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8. ATOMIC PHYSICS

8.1 Atomic Structure and the Periodic Table 8.2 Total Angular Momentum

8.3 Anomalous Zeeman Effect

What would happen if there are more than one electron?

Pauli exclusion principle:

No two electrons in an atom may have the same set of quantum numbers (n, ℓ, m, ms).

Periodic table can be understood by two rules:

1) The electrons in an atom tend to occupy the lowest energy levels available to them.

2) Only one electron can be in a state with a given (complete) set of quantum numbers (Pauli exclusion principle).

Total angular momentum = Orbital angular momentum + Spin angular momentum LS coupling: (for most atoms)

jj coupling: (for heavier atoms) 1 1 1

2 2 2

J L S

J L S

1 2

J J J

1 2

1 2

L L L S S S

J  L S

Anomalous Zeeman effect: More than 3 closely spaced optical lines  mJ    ( J, , 0, J) Notation for a single-electron atom: 2S 1

n

L

J 31P0,33P2, 33D1 53P0,1,2, 3P0,1,2, 3P

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9. Statistical Physics

9.1 Historical Overview

9.2 Maxwell Velocity Distribution 9.3 Equipartition Theorem

9.4 Maxwell Speed Distribution

9.5 Classical and Quantum Statistics 9.6 Fermi-Dirac Statistics

9.7 Bose-Einstein Statistics

 Statistics and Probability

 What are the relative probabilities of finding an atom in any particular state?

Maxwell Velocity Distribution: What is the distribution of velocities for an ideal gas at a given T?

 

3 1 2 3

( ) exp 2 /

f d C mkT d

Equipartition Theorem: Mean energy of is associated with each degree of freedom12kT

For rigid connector: DOF = 5 (3-translational; 2-rotational) For spring connector: DOF = 7 (3-tran; 2-rot; 2-vibrational)

For a single atom: DOF = 3  K12 kT 3 32kT

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9. Statistical Physics

9.4 Maxwell Speed Distribution

9.5 Classical and Quantum Statistics 9.6 Fermi-Dirac Statistics

9.7 Bose-Einstein Statistics

Maxwell Speed Distribution: the probability of finding a particle with speed between v ~ v+dv

12 2

2

( ) 4 exp /

f  d C mkT  d

Classical and Quantum Statistics:

Most probable speed:

Mean speed:

Root-mean-square (rms) speed:

* 2kT m/

 

( 4 / ) *

    ( 3 / 2) *

rms   *   rms

Classical Distributions  Each particle is distinguishable

 There is no restriction on particle energies.

Maxwell-Boltzman

Quantum Distributions  Each particle is indistinguishable due to overlap of wave functions

 There are only certain energy values allowed.

Fermi-Dirac: identical/indistinguishable particles with integer spin (Fermions)

Bose-Einstein: identical/indistinguishable particles with half-integer spin (Bosons)

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10. Molecules and Solids

10.1 Molecular Bonding and Spectra 10.2 Stimulated Emission and Lasers 10.3 Structural Properties of Solids

10.4 Thermal and Magnetic Properties of Solids 10.5 Superconductivity

10.6 Applications of Superconductivity Molecular Bonding: binding energy (potential)

Ionic bond

Covalent bond

Van der Waals bond

Hydrogen bond

Metallic bond

 What happens when atoms join together?

Molecular Spectra: Band spectrum due to rotational and vibrational energy states

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10. Molecules and Solids

10.2 Stimulated Emission and Lasers 10.3 Structural Properties of Solids

10.4 Thermal and Magnetic Properties of Solids 10.5 Superconductivity

10.6 Applications of Superconductivity

Emission of Photons by molecules: Spontaneous and Stimulated

Spontaneous Emission: emit a photon without any stimulus from the outside

Stimulated Emission: emit a photon stimulated by incoming photons

Laser: Light amplification by the Stimulated Emission of Radiation (T. Maiman, 1960)

Maser: Microwave Amplification by the Stimulated Emission of Radiation (C. Townes, 1954)

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10. Molecules and Solids

10.3 Structural Properties of Solids

10.4 Thermal and Magnetic Properties of Solids 10.5 Superconductivity

10.6 Applications of Superconductivity

Condensed Matter Physics: Study of electronic properties of Solids and Liquids

Magnetic properties: Characterized by intrinsic magnetic moments (Magnetic susceptivility: ) and their responses to applied magnetic fields (Magnetization: M)

Thermal expansion: Tendency of a solid to expand as its temperature increases

 Nearly linear with temperature in classical limit.

Crystal structure: The atoms are arranged in extremely regular, periodic patterns.

Lattice = Set of points in space occupied by atomic centers

Thermal Conductivity: A measure of how well they transmit thermal energy

 The ratio of thermal con. And electrical con. is proportional to T

Diamagnetism, Paramagnetism, Ferromagnetism

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10. Molecules and Solids

10.5 Superconductivity

10.6 Applications of Superconductivity

Superconductivity: Absence of electrical resistance (Zero resistivity under critical Tc ) Complete expulsion of magnetic flux (Meissner effect)

Applications:

BCS (J. Bardeen, L. Cooper, R. Schrieffer) Theory: Electron-Phonon interaction

Cooper Pair (two-electron pair) + Lattice Phonon (lattice vibration)

Josephson junctions: Superconductor-Insulator-Superconductor  SQUIDs Maglev: Magnetic levitation of trains

MRI: (Nuclear) Magnetic Resonance Imaging

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11. Semiconductors

11.1 Band Theory of Solids 11.2 Semiconductor Theory 11.3 Semiconductor Devices 11.4 Nanotechnology

Solids: Insulator, Metal, Semimetal, Semiconductor

 How energy bands and forbidden energy gaps formed?

Band Theory: Conduction, Valence, Forbidden gap

 Kronig-Penney Model

Semiconductor Theory: Distribution of electrons (fermions) at the various energy levels is governed by the Fermi-Dirac distribution

Holes: vacancy in valence band (work as positive charge)

n-type and p-type: adding only a small amount of dopants to silicon greatly increases the electrical conductivity.

Semiconductor Devices:

 pn-Junction Diodes: p-type and n-type semiconductors are joined together.

 Light-emitting diodes (LED), Photovotaic Cells (Solar cells)

 Transistors: npn-junction, pnp junction

 Field effect transistors (FET)

 Schottky barriers: Metal-semiconductor junction

Nanotechnology: Scientific study and manufacture of materials on a submicron scale.

Carbon Nanotubes, Graphene, Quantum Dots

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