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Effects of Rice Flour Milling Types and Addition Methods on Rheological and Sensory Properties of Surimi Products

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139

서 론

연제품은대표적인수산가공식품하나로어육에소량의

소금부재료를넣고갈아서연육

(surimi)

만든다음이것

가열응고시켜만든탄력성있는

(gel)

상태의제품을

말한다

.

이러한연제품은제품의형태

,

질감을소비자의 기호에맞도록쉽게변화시킬있으며

,

조리방법이간편하고 가격이저렴하여널리이용되는대중적인수산가공식품이다

(Kim et al., 2005a).

일반적으로연제품은제조방법에따라 운어묵

,

찐어묵

,

튀김어묵

,

맛살등으로분류된다

.

국내연제품 시장에서튀김어묵이가장비중을차지하고있는데

2011

기준전체연제품생산량의

95%

차지하고있다

(Choi et al.,

2012).

동안미더덕

(Park et al., 2006a),

홍삼분말

(Shim et al., 2012),

감귤류

(Yang and Cho, 2007),

구기자분말

(Shin et al., 2008),

분말

(Kim and Byun, 2009)

각종기능성 소재들을첨가한연제품제조물리적특성에대한연구가 활발하게이루어졌다

.

현재대부분의연제품은밀가루전분을부원료로첨가하 제조되고있다

.

최근수입에의존하고있는밀가루의가격 고품질제품을원하는소비경향에따라밀가루를대체할 있는소재의탐색이요구되고있다

.

최근들어밀가루의 소재로각광을받고있는것이바로쌀가루이다

. Hur et al.

(2011)

연제품에쌀가루를적용하여물성색도개선을

고품질연제품생산이가능할것이라보고하였다

.

쌀은세계

Article history;

Received 26 February 2013; Revised 1 April 2013; Accepted 8 April 2013

*Corresponding author: Tel: +82. 51. 629. 5827 Fax: +82. 51. 629. 5824 E-mail address: [email protected]

Kor J Fish Aquat Sci 46(2) 139-146, April 2013 http://dx.doi.org/10.5657/KFAS.2013.0139 pISSN:0374-8111, eISSN:2287-8815

ⓒ The Korean Society of Fishereis and Aquatic Science. All rights reserved

Surimi products are among the most prominent seafoods in Korea. Together with fish meat, wheat flour is a major ingredient in the preparation of surimi products. Rice flour, however, can be an effective ingredient in enhancing the rheological characteristics of surimi products. In this study, we evaluated the potential of rice flour as an agent to replace wheat flour in surimi products. The effects of rice flour milling types and addition methods on the rheological and sensory properties of surimi products were investigated. Among different addition methods, the surimi product containing non-treated rice flour showed better gel strength and sensory properties than products containing paste (1:1.3 rice flour/water, w/v) and steamed paste (steamed at 100°C for 30 min). According to the gel strength results for surimi products with added roll-mill (40 mesh) and jet-mill (180 mesh) rice flours, the roll-mill rice flour shows good potential as a replacement for wheat flour. When considering gel strength and sensory properties, an effective amount of rice flour to add was 10-15% (w/w). In conclusion, the rheological and sensory properties of surimi prod- ucts containing rice flour were comparable with those of a premium commercial surimi product. Therefore, rice flour might be an effective alternative to wheat flour for premium surimi products.

Key words: Rice flour, Surimi product, Addition method, Gel strength, Sensory evaluation

쌀가루의 제분형태 및 첨가방법이 연제품의 물리적 및 관능적 특성에 미치는 영향

한국식품연구원 대사기능연구본부, 1부경대학교 식품공학과

Suengmok Cho, Minseok Yoon and Seon-Bong Kim1*

조승목ㆍ윤민석ㆍ김선봉

1

*

Effects of Rice Flour Milling Types and Addition Methods on Rheologi- cal and Sensory Properties of Surimi Products

Division of Metabolism and Functionality, Korea Food Research Institute, Sungnam 463-746, Korea

1

Department of Food Science and Technology, Pukyong National University, Busan 608-737, Korea

(2)

인구의절반이주식으로사용하는세계

3

곡물하나로

,

우리나라를비롯한아시아권에서는다른작물과대치될 없는가장중요한식량자원이다

(Lee, 2012).

최근식생활의 구화와인스턴트식품의보편화로소비량이급격히감소함

(Lee et al., 2012a)

따라쌀을밥의형태가아닌가공식품의 주요원료로서소비해야필요성이높아지고있는실정이다

(Shin, 2010). Amylose

함량은국내에서생산되는단립종쌀이

12-19%

장립종쌀의

19-23%

보다낮고상대적으로

amylo-

pectin

함량이높아동결융해에안정하고노화정도를줄여

있어가공식품소재로써활용가치가매우크다고있다

(Hur et al., 2011).

최근까지쌀을이용한국수

(Seo et al., 2012),

식혜

(Lee et al., 1997),

유과

(Shin et al., 1989),

요구르트

(Hong and Ko, 1991),

주류

(Kim et al., 2007),

(Kim et al., 2005b;

Kim et al., 2012)

쿠키

(Lee et al., 2012b)

제조에대한 양한연구가이루어져왔다

.

하지만연제품을비롯한수산가공 식품에또는쌀가루를적용시키는연구는활발하게이루어 지지못한실정이다

(Hur et al, 2011).

따라서

,

연구에서는소비촉진과고품질연제품개발을 위해쌀가루의제분형태첨가방법을달리하여가장대표적 연제품인튀김어묵을제조하였다

.

쌀가루의첨가가어묵의 물리적관능적특성에미치는영향을평가하여

,

밀가루대체 소재로써쌀가루의적용가능성을검토하였다

.

재료 및 방법

재료

연구에사용한쌀가루

(rice flour)

찹쌀가루

(glutinous rice flour)

대선제분

(

전남

,

한국

)

에서구입하였으며

,

다른 분방법에따라제조되어입자크기가다른롤밀

(roll-mill,

평균 입도

: 40 mesh)

제트밀

(jet-mill,

평균입도

: 180 mesh)

가루를 사용하였다

.

연제품의기본원료인냉동명태연육은

Premier Pacific Seafoods (Seattle, WA, USA)

사의

FA (high grade)

급을사용하였다

.

제조사에 따르면

,

명태살의 함량은

91.5%

(w/w)

이며

,

부원료로설탕

,

솔비톨

,

폴리인산나트륨

,

피로인산 나트륨이첨가되었다

.

연제품(튀김어묵)의 제조

쌀가루찹쌀가루가첨가된연제품은

Table 1

같은배합

비에따라제조되었다

.

냉동명태연육을해동시킨

silent cut- ter (OMF-500, Ohmichi Co., Ltd, Japan)

마쇄하고식염을 배합비에따라여러번에나누어골고루첨가한다음얼음을 넣어품온을

4℃

유지하면서

5

분간마쇄하였다

.

,

쌀가 찹쌀가루를첨가하여다시

5

분간얼음과함께마쇄하였

.

쌀가루찹쌀가루는

3

가지방법으로첨가되었는데첫째

,

가루를아무런처리없이있는그대로첨가하거나둘째

,

가루 물과

1:1.3 (w/v)

비율로반죽하여첨가하거나셋째

,

번째 반죽을

100℃

에서

30

분간호화시켜첨가하였다

.

혼합된 료를직경

3 cm,

길이

20 cm

틀에넣고성형한

,

150℃

대두유에서

3

분간

1

튀김하고다시

3

분간

2

튀김하여 조하였다

.

제조된튀김어묵은

4℃

에서냉장보관하면서실험 사용하였다

.

겔 강도(gel strength) 측정

어묵의 강도는 물성측정기인

Texture Analyzer (Model TAXT2, Stable Micro Systems, Godalming, England)

이용 하여측정하였다

.

연제품을일정한크기

(

직경

×

높이

, 3 cm×2 cm)

절단한

,

상온또는전자레인지에서

10

초간가온한 각각분석하였다

.

강도의분석조건은

probe: 0.25 inch spherical stainless, test speed: 1.0 mm/s

였다

.

강도는

probe

가해진하중량

(g),

연제품이파열될

probe

침입한깊이

(cm)

곱으로나타내었다

.

모든시료의강도값은

10

반복 측정하여평균값

±

편차값의형식으로나타내었다

.

물성(texture profile) 측정

경도

(hardness),

접착성

(adhesiveness),

탄력성

(springiness),

응집성

(cohesiveness),

씹힘성

(chewiness)

물성은

Texture

Analyzer

사용하여 측정하였다

.

물성 측정은어묵을 일정

크기

(

직경

×

높이

, 3 cm×2 cm)

절단한

,

직경

50 mm

probe

사용하여

test speed: 5.0 mm/s, pretest speed: 5.0 mm/s, posttest speed: 5.0 mm/s,

변형율

: 50%

조건에서이루 어졌다

.

경도는번째압축과정에서나타나는최대

peak

하며

,

접착성은번째곡선아래에생긴음의면적으로

,

탄력 성은번째그래프의

0

점에서

peak

까지의시간

(B)

번째 그래프의

0

점에서

peak

까지의시간

(A)

비율

(B/A)

표시하 였고

,

응집성은번째곡선의면적

(C)

대한번째곡선의 면적

(D)

비율

(D/C)

,

씹힘성은검성과탄력성의곱으로 타내었다

(Bourne, 1968; Breene, 1975).

관능평가

제조한연제품의관능평가는식품가공연구의전문성을가지

20

명의

panel

대상으로하였으며

,

검사방법과평가특성을 교육시킨실시하였다

.

관능특성평가항목은외관

(outward),

(color),

(flavor),

(taste),

씹힘성

(chewiness),

경도

(hard-

Table 1. The ingredient formula for preparation of surimi products

containing rice flour

Ingredients Rice flour 10% Rice flour 15% Rice flour 20%

Surimi 77% 72% 67%

Rice flour 10% 15% 20%

Salt 1.5% 1.5% 1.5%

Water 11.5% 11.5% 11.5%

(3)

ness),

종합적기호도

(overall acceptance)

였으며

, ‘

매우좋다

’ 7

점에서

매우나쁘다

’ 1

점으로하는

Likert

척도를사용하여 가하였다

.

색도 및 백색도 측정

연제품의색도는색차계

(CL-100, Minolta, Osaka, Japan)

사용하여측정하였으며

,

연제품단면의명도

(lightness, L),

색도

(redness, a),

황색도

(yellowness, b)

값을측정하였다

.

백색 도는아래식에따라계산되었다

(Park, 1994).

모든시료의측정 값은

5

반복하여평균값

±

편차값으로나타내었다

.

이때의 표준백판의

L, a, b

값은각각

97.59, -0.02, 1.83

이었다

.

통계처리

모든통계처리는통계프로그램인

SPSS 12.0 (SPSS Inc., Chi- cago, Illinois, USA)

사용하여 이루어졌으며

,

유의차 검정

ANOVA test

이용하여분산분석한

P<0.05

수준에서

Duncan

다중위검정으로실시하였다

.

결과 및 고찰

겔 강도(gel strength)

어육단백질의형성을통해만들어지는어묵의특성상 리적특성은관능적기호도와함께가장중요한어묵의품질 요인이다

.

어묵의물성을나타내는가장대표적인지표로 강도

(gel strength)

이용되고있다

(Kim et al., 2008).

연구 에서는쌀가루품종

(

찹쌀

),

제분형태

(

롤밀

: 40 mesh

트밀

: 180 mesh)

첨가방법

(

가루

,

반죽

,

호화반죽

)

달리하 튀김어묵을제조하여강도를비교하였다

.

첨가된 가루찹쌀가루의함량은

10% (w/w)

모든어묵시료에 일하게적용되었다

.

어묵의강도는익혀먹는특성을고려하 각각상온과가온

(

전자레인지에서

10

가열

)

측정되 었다

.

대조군으로는시판중인연육함량

70%

이상의고급튀김 어묵제품

(PSP, premium commercial surimi products)

사용 하였다

.

상온

(Fig. 1A)

가온

(Fig. 1B)

모든조건에서대조군

PSP

강도값이각각

487.3±5.6

325.8±14.6 g∙cm

가장높게나타났다

.

상온에서강도를측정한결과

(Fig.

1A),

쌀가루

(rice flour)

첨가한어묵

(RR

RJ)

강도가 찹쌀가루

(glutinous rice flour)

첨가한어묵

(GR

GJ)

상대적으로높게나타났다

. Amylopectin

함량이매우 백색도

(White index) =

600 500 400 300 200 100 0

Gel sterngth (g·cm)

600 500 400 300 200 100 0

1000 700 500 250

0 1000 700 500 250 0

Gel sterngth (g·cm)

PSP RR RJ RR RJ RR RJ GR GJ GR GJ GR GJ At room temperature

After microwave for 10 s

At room temperature

After microwave for 10 s Rice flour

(A)

(B)

Gel sterngth (g·cm)Gel sterngth (g·cm)

(A)

(B)

Steamed

paste Paste Flour Steamed Paste Paste paste

Glutionus rice flour a

b

a a

c bc bc

c d

b a

N.D N.D

N.D

ef f d

e a

d d b a

N.D

e e b

c

bc

c cd

a b

e

cd c

PSP 10 15 20 10 15 20

RR GR

Fig. 1. The effects of milling types and adding methods of rice flour on gel strength of surimi products. a-f: significant differences at P<0.05 by Duncan's multiple range test. N.D., not detected. Ab- breviations: PSP, premium commercial surimi products; RR, rice roll-mill flour; RJ, rice jet-mill flour; GR, glutinous rice roll-mill flour; GJ, glutinous rice jet-mill flour. Particle sizes of roll-mill and jet-mill flours are 40 and 180 mesh, respectively.

Fig. 2. Changes in gel strength of surimi products as an increase of rice flour content. a-e: significant differences at P<0.05 by Dun- can's multiple range test. Abbreviations: PSP, premium commer- cial surimi products; RR, rice roll-mill flour; GR, glutinous rice roll-mill flour.

600 500 400 300 200 100 0

Gel sterngth (g·cm)

600 500 400 300 200 100 0

1000 700 500 250

0 1000 700 500 250 0

Gel sterngth (g·cm)

PSP RR RJ RR RJ RR RJ GR GJ GR GJ GR GJ At room temperature

After microwave for 10 s

At room temperature

After microwave for 10 s Rice flour

(A)

(B)

Gel sterngth (g·cm)Gel sterngth (g·cm)

(A)

(B)

Steamed

paste Paste Flour Steamed Paste Paste paste

Glutionus rice flour a

b

a a

c bc bc

c d

b a

N.D N.D

N.D

ef f d

e a

d d b a

N.D

e e b

c

bc

c cd

a b

e

cd c

PSP 10 15 20 10 15 20

RR GR

(4)

화된쌀가루가수분을흡수하여어육단백질의형성을저해 했기때문으로판단된다

(Wu et al., 1985; Kong et al., 1999).

쌀가루의제분형태가어묵의강도에미치는영향을살펴보

,

가루의평균입자크기가롤밀

(40 mesh)

가루가제트밀

(180 mesh)

가루에비해높은강도를나타내었다

(Fig. 1A).

Park et al. (2006)

Lee et al. (2004)

쌀가루입자의크기가 작을수록전분의손상도가크고수분결합능력이증가한다고 고하였다

.

따라서입자크기가작은제트밀가루가첨가된어묵

(RJ

GJ)

어육단백질의형성에필요한수분이충분하지

못해롤밀가루첨가어묵

(RR

GR)

비해낮은강도를 것으로사료된다

.

가온한어묵의강도를측정한결과

,

전체적으로상온의

겔강도에비해낮은경향을보였다

(Fig. 1B).

이는가온으로

수분의손실로어묵겔의구조에변형이일어나고

(Gopper

찹쌀의경우응집성과접착성이높은겔을형성하는데

(Park, 2005),

찹쌀가루첨가어묵이

amylopectin

함량이상대적으 낮은쌀가루첨가어묵에비해탄력성이높은겔을형성하지 못한것으로사료된다

.

쌀가루 찹쌀가루를첨가방법을달리하여 제조한어묵의 경우

,

가루그대로첨가한

(flour)

가장높은강도를 타내었으며

,

다음으로가루를물과

1:1.3 (w/v)

비율로반죽 하여첨가한

(paste)

으로나타났다

.

특히

,

롤밀쌀가루

(RR)

그대로첨가한어묵의강도값이

463.7±16.6 g∙cm

높았으며

,

대조군인

PSP

통계적으로유사하게나타났다

(P<0.05).

반면

,

호화반죽

(steamed paste)

형태로첨가한경우 튀김과정에서겔을형성하지못해강도의측정이불가능 하였다

.

어묵의제조과정어육단백질이겔을형성하기위해 서는수분이필수적인요소인데

(Powrie and Tung, 1976),

Table 2. Textural properties of RR and GR surimi products

Samples Hardness (g) Adhesiveness (gs) Springiness Cohesiveness Chewiness

At room temperature

PSP 4275±112c -1.32±1.96a 0.94±0.02a 0.66±0.01b 2777±92c

RR 7453±261a -22.43±9.88b 0.94±0.02a 0.74±0.01a 5154±343a

GR 6844±107b -41.80±3.57c 0.95±0.03a 0.75±0.05a 4584±215b

After microwave for 10 seconds

PSP 1786±96c -2.08±1.24b 0.87±0.02a 0.76±0.02b 1203±82c

RR 3739±47a 0.44±3.09a 0.90±0.01a 0.81±0.02a 2768±107a

GR 3443±49b -21.96±3.56c 0.88±0.04a 0.76±0.01b 2243±109b

a, b, c: significant differences at P<0.05 by Duncan's multiple range test. Abbreviations: PSP, premium commercial surimi products; RR, rice roll-mill flour; GR, glutinous rice roll-mill flour.

[A cross section]

[Whole]

Surimi products added with rice roll-mill flour (RR) Premium commercial surimi products (PSP) Fig. 3. Appearance of the surimi product containing rice flour and the premium commercial surimi product.

(5)

et al., 1997),

어묵이데워짐에따라조직이부드러워졌기때문 이다

.

상온일때와마찬가지로찹쌀가루를첨가한어묵

(GR

GJ)

강도는모든조건에서쌀가루를첨가한어묵

(GR

GJ)

비해낮게나타났으며

,

또한강도의감소율이크게 타났다

.

종합적으로대조군인

PSP

비교해

,

롤밀쌀가루

(RR)

첨가한어묵은

PSP

유사한수준의겔강도를보여

가루대체원료로서가능성을확인할있었다

.

강도분석결과

,

제분형태에서는롤밀가루

(RR

GR)

첨가방법에서는무처리가루

(flour)

첨가방법이가장우수한 강도를보였다

.

따라서

,

찹쌀가루의적정첨가량을알아보 위해첨가량에따른강도의변화를알아보았다

(Fig. 3).

중인고급어묵의경우일반적으로

70%

이상의연육을첨가 하고있기때문에부원료의첨가량을감안하여찹쌀가루 함량을최대

20%

설정하였다

.

상온에서는롤밀쌀가루

(RR)

15%

첨가한어묵이

PSP

롤밀찹쌀가루

(GR)

첨가어묵

(10-20%)

보다유의적으로강도를나타내었다

(P<0.05).

롤밀쌀가루

(RR)

경우첨가량

20%

에서강도가소폭

소한것으로나타나

15%

이상의쌀가루첨가는강도측면에

의미가없을것으로사료된다

.

특히

,

대조군인

PSP

사한강도를나타내기위해서는

10%

첨가하는것이적절 것으로나타났다

.

물성(texture profile)

강도에있어서롤밀쌀가루

(RR)

찹쌀가루

(GR)

무처

가루형태로

10%

첨가한어묵들이 대조군인

PSP

유사

품질특성을나타내었다

.

이들의물성

(texture)

자세히 아보기위하여경도

(hardness),

접착성

(adhesiveness),

탄력성

(springiness),

응집성

(cohesiveness),

씹힘성

(chewiness)

석하였다

(Table 2).

어묵은원료제조방법에따라다양한

태로제조되며

,

물성또한매우다양하다

.

물성에영향을 치는요인으로는원료어육의성상

,

어묵의제조조건

,

망상구 조의형성조건

,

부원료등이있다

(Kim and Cho, 1992).

상온

에서는롤밀쌀가루

(RR)

첨가어묵이찹쌀가루

(GR)

첨가

묵에비해높은경도

(hardness),

접착성

(adhesiveness),

응집성

(cohesiveness),

씹힘성

(chewiness)

나타내었다

.

어묵

PSP

보다경도

,

응집성

,

씹힘성이높고접착성이낮게나타났

.

가온한측정한어묵의물성은상온에서측정한어묵의 성보다경도

,

탄력성

,

응집성씹힘성이낮아졌고

,

접착성이 높아졌으나조건별로제조된어묵들의물성경향은유사하 나타났다

.

일반적으로어묵의물성에서강도와경도는 관성이높은비례관계를가지는데

(Kwon et al., 1985),

연구 에서도이러한경향이확인되었다

.

Table 3. Sensory evaluation of surimi products prepared by different milling types and adding methods of rice flour

Samples Outward Color Flavor Taste Chewiness Hardness Overall acceptance

At room temperature

PSP 4.83±1.89a 4.67±2.11a 5.00±1.33a 3.50±1.17ab 2.83±1.17ab 3.50±0.67d 3.33±1.33a Rice flour

Paste RR 5.17±0.56a 5.17±0.56a 5.00±0.67a 4.33±1.22ab 4.50±0.83a 3.67±1.11cd 4.50±1.00a RJ 4.50±1.00a 4.00±1.00a 4.00±1.00a 3.83±0.56ab 4.17±0.83a 3.67±0.44cd 4.67±0.67a Flour RR 3.67±0.67a 4.17±0.28a 4.50±1.00a 3.83±0.56ab 4.00±1.33a 5.83±0.28ab 4.17±1.17a RJ 3.83±0.56a 4.33±0.56a 4.67±0.67a 4.33±0.67ab 4.17±1.11a 5.00±0.67bc 4.67±0.44a Glutinous rice flour

Paste GR 3.83±0.61a 4.83±0.89a 4.50±0.83a 3.50±1.00b 3.83±1.50ab 2.33±0.78c 3.67±1.33b GJ 4.83±0.89a 4.50±1.50a 4.83±0.83a 3.67±0.44ab 3.33±1.00b 2.50±1.00c 3.67±1.00b Flour GR 4.50±0.83a 3.67±0.78a 4.67±0.89a 5.00±0.67a 5.17±0.56a 4.83±0.28a 4.33±0.78ab GJ 4.17±0.56a 3.83±0.56a 4.67±0.67a 4.50±0.67ab 4.83±0.56ab 4.00±0.33ab 4.17±0.56ab After microwave for 10 seconds

PSP 4.83±1.89a 4.67±2.11a 3.50±2.33a 1.50±0.50c 2.00±0.33b 2.67±0.89d 1.83±0.56b Rice flour

Paste RR 5.33±0.44a 5.33±0.67a 4.50±0.89a 4.83±0.61a 4.50±1.17a 3.83±0.61cd 4.67±0.78a RJ 4.83±0.56a 4.33±0.78a 4.17±0.89a 3.83±0.89ab 3.83±0.89a 4.00±1.33cd 3.67±1.00a Flour RR 3.83±0.56a 4.17±0.28a 3.83±0.56a 4.17±0.89ab 3.33±1.11ab 6.50±0.50a 3.67±0.89a RJ 4.00±0.33a 4.50±0.67a 3.67±1.33a 3.17±1.22b 3.83±0.89a 5.00±1.00bc 3.83±0.89a Glutinous rice flour

Paste GR 4.17±0.61a 4.50±0.83a 5.00±1.00a 4.33±1.11ab 4.83±1.17ab 4.00±1.00ab 4.17±1.22ab GJ 5.00±0.67a 5.17±0.83a 5.50±0.50a 4.50±0.67ab 3.33±1.33b 3.17±0.28bc 4.17±0.89ab Flour GR 4.17±0.83a 4.50±1.00a 4.50±0.67a 5.00±0.67a 5.33±0.67a 5.17±0.28a 5.33±0.67a GJ 3.83±0.28a 4.00±0.33a 4.67±0.67a 4.67±1.11ab 4.67±1.00ab 4.17±0.56ab 5.00±1.00ab a-d: significant differences at P<0.05 by Duncan's multiple range test. Abbreviations: PSP, premium commercial surimi products; RR, rice roll-mill flour; RJ, rice jet-mill flour; GR, glutinous rice roll-mill flour; GJ, glutinous rice jet-mill flour. Particle sizes of roll-mill and jet-mill flours are 40 and 180 mesh, respectively.

수치

Fig. 1. The effects of milling types and adding methods of rice  flour on gel strength of surimi products
Table 3. Sensory evaluation of surimi products prepared by different milling types and adding methods of rice flour
Table 5. Hunter color value and white index of RR and GR surimi  products

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