TIC Plot

(1)

(2)

(3)

(4)

(5)

- I -

(6)

- II -

(7)

- III -

(8)

- IV - β

(9)

- V -

(10)

- VI - β

β

(11)

- 1 -

(12)

- 2 -

(13)

- 3 -

(14)

- 4 -

(15)

- 5 -

(16)

- 6 -

(17)

- 7 -

(18)

- 8 -

(19)

- 9 -

(20)

- 10 -

(21)

- 11 -

(22)

- 12 -

(23)

- 13 -

(24)

- 14 -

TIC Plot

Deconvoluted Plot

(25)

- 15 -

(26)

- 16 -

(27)

- 17 -

(28)

- 18 - α

α

(29)

- 19 - δ

(30)

- 20 - γ

(31)

- 21 -

(32)

- 22 -

(33)

- 23 -

(34)

- 24 -

(35)

- 25 -

(36)

- 26 -

α α

δ γ

(37)

- 27 -

(38)

- 28 -

α α

α

(39)

- 29 - α

α

δ

γ β

(40)

- 30 -

α β

(41)

- 31 -

(42)

- 32 -

(43)

- 33 - α

γ δ

β

(44)

- 34 -

(45)

- 35 - α

(46)

- 36 - β

(47)

- 37 -

(48)

- 38 -

(49)

- 39 -

(50)

- 40 - α

α

(51)

- 41 -

125

δ

(52)

- 42 -

(53)

- 43 -

(54)

- 44 - γ

(55)

- 45 -

(56)

- 46 -

(57)

- 47 -

(58)

- 48 -

(59)

- 49 - α

α

(60)

- 50 - δ

(61)

- 51 -

(62)

- 52 -

(63)

- 53 - γ

(64)

- 54 -

(65)

- 55 -

(66)

- 56 -

(67)

- 57 -

(68)

- 58 -

β

(69)

- 59 -

β β

β

(70)

- 60 -

β β

β

(71)

- 61 - β

β

(72)

- 62 - β

β

(73)

- 63 -

(74)

- 64 - β

β

(75)

- 65 -

(76)

- 66 -

(77)

- 67 -

(78)

- 68 - β

(79)

- 69 -

(80)

- 70 -

(81)

- 71 -

(82)

- 72 -

(83)

- 73 -

(84)

- 74 -

(85)

- 75 -

(86)

- 76 -

(87)

- 77 -

(88)

- 78 -

(89)

- 79 -

(90)

- 80 -

β

(91)

- 81 -

(92)

- 82 -

(93)

- 83 -

(94)

- 84 -

(95)

- 85 -

(96)

- 86 -

(97)

- 87 -

Appendix 1. Comparision of pesticide MRLs in tea among Korea, Japan, China, EU and Codex

No. Pesticide names MRLs(ppm)

Korea Japan China EU Codex 1 1,1-Dichloro-2,2-bis(4-ethylphenyl)ethane(F) 0.1 0.1

2 1,2-Dibromoethane(ethylenedibromide)(F) 0.02 3 1,2-Dichloroethane(ethylenedichloride)(F) 0.02

4 1,3-Dichloropropene 0.05

5 1-Naphthylacetamide 0.05

6 1-Naphthylacetic acid 0.05

7 1-Methylcyclopropene 0.02

8 2,4-DB 0.1

9 2,4,5-T(F) 0.05

10 2,4-D(sum of 2,4-D and its esters

expressed as 2,4-D) 0.1

11 3,5-Xylyl methylcarbamate(XMC) 10 12 4-Chlorophenoxyacetic acid 0.02 13

Abamectin(sum of avermectin B1a, Avermectin B1b and delta-8,9 isomer of avermectin B1a)(F)

0.02 002

14 Acephate 10 0.1 0.05

15 Acequinocyl 40 0.02

16 Acetamiprid(R) 3.0 50 0.1

17 Acetochlor 0.01

18

Acibenzolar-S-methyl(sum of acybenz olar-S-methyl and acibenzolar acid (CGA210007) expressed as acybenzolar -S-methyl)

0.05

19 Aclonifen 0.05

20 Acrinathrin(F) 10 0.05

21 Alanycarb 5

22 Alachlor 0.05

23 Aldicarb(sum of aldicarb, its sulfoxide

and its sulfone, expressed as aldicarb) 0.05 0.05 24 Aldrin and Dieldrin(Aldrin and dieldrin

combined expressed as dieldrin)(F) N.D. 0.02

25 Amidosulfuron 0.05

26 Aminopyralid 0.02

27

Amitraz(amitraz including the metabolites containing the 2,4-dimethyl aniline moity expressed as amitraz)

10.0 0.1

28 Amitrole 0.02

(98)

- 88 - Appendix 1. Continued.

Korea Japan China EU Codex

29 Anilazine 0.05

30 Aramite(F) 0.1 0.1

31 Asulam 0.02 0.05

32 Atrazine (F) 0.1 0.1

33 Azadirachtin 0.01

34 Azimsulfuron 0.1 0.1

35 Azinphos-ethyl (F) 0.05

36 Azinphos-methyl (F) 0.1

37

Azocyclotin and Cyhexatin (sum of azo -cyclotin and cyhexatin expressed as

cyhexatin) 0.1

38 Azoxystrobin 1.0 10 0.1

39 Barban (F) 0.1

40 Beflubutamid 0.1

41

Benalaxyl including other mixtures of constituent isomers including benalaxyl -M(sum of isomers)

0.1 0.1

42 Benfluralin (F) 0.05

43 Benfuracarb 0.1 0.1

44 Bensulfuron-methyl 0.02

45 Bensulide 0.03

46

Bentazone(sum of bentazone and the conjugates of 6-OH and 8-OH bentaz -one expressed as bentazone) (R)

0.02 0.1

47

Benthiavalicarb(Benthiavalicarb-isopropyl (KIF-230R-L) and its enantiomer(KIF-230 S-D) and diastereomers (KIF-230 R-L and KIF- 230 S-D)

0.01

48 Benzyladenine 0.02

49 Bialaphos 0.004

50 Bifenazate 2 0.02

51 Bifenox(F) 0.05

52 Bifenthrin(F) 0.3 25 5

53 Binapacryl(F) 0.1

54 Bioresmethrin 0.1

55 Bis(2-chloro-1-methyl)ether(DCIP) 0.2

56 Bitertanol(F) 10.0 0.1 0.1

57 Boscalid(F)(R) 0.5

58 Brodifacoum 0.001

59 Bromide ion 50 70

(99)

60 Bromophos-ethyl 0.1 0.1

61 Bromopropylate 0.1 0.1

62 Bromoxynil(bromoxynil including its est

-ers expressed as bromoxynil)(F) 0.1

63 Bromuconazole(sum of diasteroisomers )(F) 0.05

64 Bupirimate 0.05

65 Buprofezin(F) 1.0 20 0.05

66 Butralin 0.02

67 Butylate 0.05

68 Camphechlor(Toxaphene)(F)(R) 0.1

69 Captafol (F) 0.1

70 Carbaryl(F) 1.0 0.1

71

Carbendazim and benomyl(sum of benomyl and carbendazim expressed as carbendazim) (R)

2.0 10

0.1

72 Carbetamide 0.05

73 Carbofuran(sumofcarbofuranand3-hydroxy

-carbofuranexpressedascarbofuran) 0.2 0.05

74 Carbosulfan 0.1 0.1

75 Carboxin 0.05

76

Carfentrazone-ethyl(determined as carfentrazone and expressed as carfentrazone-ethyl)

0.1 0.02

77 Cartap 30 0.1

78 Chlorantraniliprole(DPXE-2Y45) 50 0.02

79 Chlorbenside(F) 0.1 0.1

80 Chlorbufam 0.1 0.1

81 Chlordane(sumofcis-andtrans-chlrodan

-e)(F)(R) 0.02 0.02

82 Chlordecone(F) 0.02

83 Chlorfenapyr 3.0 40 50

84 Chlorfenson (F) 0.1 0.1

85 Chlorfenvinphos (F) 0.05

86 Chlorfluazuron 10.0 10

87 Chloridazon 0.1

88 Chlormequat 0.1 0.1

89 Chlorobenzilate (F) 0.1 0.1

90 Chloropicrin 0.02

91 Chlorothalonil 10 0.1

(100)

92 Chlorotoluron 0.05

93 Chloroxuron (F) 0.1 0.1

94

Chlorpropham (chlorpropham and 3-chloroaniline, expressed as chlorpropham) (F) (R)

0.1

95 Chlorpyrifos (F) 2.0 10 0.1 2

96 Chlorpyrifos-methyl (F) 0.1 0.1 0.1

97 Chlorsulfuron 0.05

98 Chlorthal-dimethyl 0.01

99 Chlorthiamid 0.05

100 Chlozolinate 0.1

101 Chromafenozide 20 0.02

102 Cinidon-ethyl(sum of cinidon ethyl and

its E-isomer) 0.1

103

Clethodim(sum of sethoxydim and clethodium including degradation products calculated as sethoxydim)

0.1

104 Clodinafop and its S-isomers, expressed

as clodinafop (F) 0.02 0.05

105 Clofentezine (R) 20 0.05

106 Clomazone 0.02 0.02

107 Clopyralid 0.5

108 Clothianidin 50 0.05

109 Clozolinate 0.1

110 Copper compounds (Copper) 40

111 Cyanamide including salts expressed

as cyanamide 0.1

112 Cyazofamid 0.02

113 Cyclanilide (F) 0.1

114 Cycloprothrin 0.5

115

Cycloxydim including degradation and reaction products which can be determined as 3-(3-thianyl)glutaric acid S-dioxide (BH 517-TGSO2) and/or 3-hydroxy-3- (3-thianyl)glutaric acid S-dioxide(BH 517 -5-OH-TGSO2) or methyl esters thereof, calculated in total as cycloxydim

0.05 0.05

116 Cyenopyrafen 60

(101)

117 Cyflufenamid 0.05

118 Cyflumetofen 20

119

Cyfluthrin(cyfluthrin including other mixtures of constituent isomers(sum of isomers )(F)

20 0.1

120 Cyhalofop-butyl(sum of cyhalofop butyl

and its free acids) 0.05

121 Cyhalothrin 2.0 15

122 Cymoxanil 0.05 0.05

123

Cypermethrin(cypermethrin including other mixtures of constituent isomers(sum of isomers) (F)

20 20 0.5 20

124 Cyproconazole (F) 0.05

125 Cyprodinil (F) (R) 0.05

126 Cyromazine 0.05

127

DDT(sum of p,p´-DDT, o,p´-DDT, p-p´- DDE and p,p´-TDE(DDD) expressed as DDT)(F)

0.2 0.2

128 DNOC 0.1

129 Dalapon 0.05 0.1

130

Daminozide(sum of daminozide and 1,1- -dimethyl-hydrazine, expressed as daminozide)

0.1

131 Dazomet(Methylisothiocyanate resulting

from the use of dazomet and metam) 0.1 0.02 132 Deltamethrin (cis-deltamethrin) (F) 10 10 5 5

133 Demeton-S-methyl 0.05

134 Desmedipham 0.1

135 Diafenthiuron 20

136 Diallate 0.1 0.1

137 Diazinon (F) 0.1 0.02

138 Dibromethyldibromcyclohexane(DBEDC) 0.5

139 Dicamba 0.05

140 Dichlobenil 0.05

141 Dichlorfluanid 5.0

142 Dichlorprop, incl. Dichlorprop-p 0.1 0.1

143 Dichlorvos 0.1 0.02

144 Diclofop(sum diclofop-methyl and diclofop

acid expressed as diclofop-methyl) 0.05

(102)

145 Diclomezine 0.02

146 Dicloran 0.01

147 Dicofol(sum of p,p´ and o,p' isomers)(F) 3 20 50

148 Diethofencarb 0.05

149 Difenoconazole 2.0 10 0.05

150 Difenzoquat 0.05

151 Diflubenzuron (F) (R) 20 0.1

152 Diflufenican 0.002 0.05

153 Diflufenzopyr 0.05

154 Dimethachlor 0.02

155

Dimethenamid p(dimethenamid-p including– other mixtures of constituent isomers (sum of isomers))

0.02

156 Dimethipin 0.04 0.1

157 Dimethoate(sum of dimethoate and omethoate

expressed as dimethoate) 1 0.05

158 Dimethomorph 0.05

159 Dimoxystrobin 0.01

160 Diniconazole 0.05

161

Dinocap(sum of dinocap isomers and their corresponding phenols expressd a s dinocap)(F)

0.1

162 Dinoseb 0.1 0.1

163 Dinotefuran 25

164 Dinoterb 0.1 0.1

165 Dioxathion 0.1 0.1

166 Diphenylamine 0.05 0.05

167 Diquat 0.3 0.1

168

Disulfoton(sum of disulfoton, disulfoton sulfoxide and disulfotonsulfone expressed as disulfoton)(F)

0.05 0.05

169 Dithianon 0.01

170

Dithiocarbamates(dithiocarbamates expressed as CS2, including maneb, mancozeb, metiram, propineb, thiram and ziram)

5 0.1

171

Diuron(Diuron including all components containing 3,4-dichloraniline moiety expressed as 3,4-dichloraniline)

1 0.1

172 Dodine 0.2

(103)

Korea Japan China EU Codex 173 EPTC (ethyl dipropylthiocarbamate) 0.05

174 Emamectin benzoate B1a, expressed

as emamectin 0.5 0.02

175

Endosulfan(sum of alpha- and beta-isomers and endosulfan-sulphate expresses as endosulfan)(F)

30 30 30

176 Endrin (F) N.D. 0.01

177 Epoxiconazole (F) 0.05

178 Ethalfluralin 0.02

179 Ethephon 0.1 0.1

180 Ethiofencarb 0.05

181 Ethion 0.3 3

182 Ethiprole 10

183 Ethirimol 0.05

184

Ethofumesate (sum of ethofumesate and the metabolite 2,3-dihydro-3,3-dimethyl 2-2-oxo-benzofuran-5-yl methane sulphonate expressed as ethofumesate)

0.1

185 Ethoprophos 0.005 0.02

186 Ethoxyquin (F) 0.05 0.05

187 Ethoxysulfuron 0.1

188 Ethychozate 0.05

189 Ethylene dibromide 0.1

190 Ethylene dichloride 0.02

191

Ethylene oxide (sum of ethylene oxide and 2-chloro-ethanol expressed as ethylene oxide) (F)

0.2

192 Etofenprox (F) 10 0.01

193 Etoxazole 10 0.05

194 Etridiazole 0.05

195 Famoxadone 0.05

196 Fenamidone 0.05

197

Fenamiphos (sum of fenamiphos and its sulphoxide and sulphone expressed as fenamiphos)

0.05 0.05

198 Fenarimol 0.05 0.05

199 Fenazaquin 0.01

200 Fenbuconazole 10 0.05

201 Fenbutatinoxide(F) 1.0 0.1

(104)

Korea Japan China EU Codex 202 Fenchlorphos(sum of fenchlorphos and

fenchlorphos oxon expressed as fenchlorphos) 0.1 0.1

203 Fenhexamid 0.1

204 Fenitrothion 0.2 0.2 0.5 0.5

205 Fenobucarb 0.5

206 Fenoxaprop-P 0.1

207 Fenoxycarb 0.05 0.05

208 Fenpropathrin 25 2 2

209 Fenpropidin(R) 0.05

210 Fenpropimorph(R) 0.1 0.1

211 Fenpyroximate(F) 10.0 10 0.1

212

Fenthion (fenthion and its oxigen analogue, their sulfoxides and sulfone expressed as parent)(F)

0.1

213 Fentin acetate (F)(R) 0.02 0.1

214 Fentin hydroxide(F)(R) 0.02 0.1

215 Fenvalerate and Esfenvalerate(Sum of RR

& SS isomers)(F) 1.0 2 0.05

216 Fenvalerate and Esfenvalerate(Sum of RS

& SR isomers)(F) 1.0 0.05

217 Fipronil (sum fipronil + sulfone metabolite

(MB46136) expressed as fipronil)(F) 0.002 0.005

218 Flazasulfuron 0.02 0.02

219

Flonicamid (sum of flonicamid, TNFG

and TNFA)(R) 40 0.05

220 Florasulam 0.1

221 Florchlorfenuron 0.05

222 Fluazifop-P-butyl[fluazifop acid(free and

conjugate)] 0.1

223 Fluazinam (F) 7.0 5 0.05

224 Flubendiamide 40 0.02

225 Flucycloxuron 0.05

226 Flucythrinate (F) (R) 20 20 0.1

227 Fludioxonil 0.05

228

Flufenacet (sum of all compounds containing the N fluorophenyl-N-isopropyl moiety expressed as flufenacet equivalent)

0.05

229 Flufenoxuron (F) 10.0 15 15

(105)

230 Flufenzin 0.05

231 Flumioxazine 0.1

232 Fluometuron 0.02 0.02

233 Fluopicolide 0.02

234 Fluoride ion 350

235 Fluoroglycofene 0.02

236 Fluoroimide 35

237 Fluoxastrobin 0.1

238 Flupyrsulfuron-methyl 0.05

239 Fluquinconazole(F) 0.05

240 Flurochloridone 0.1

241 Fluroxypyr(fluroxypyr including its esters

expressed as fluroxypyr)(R) 0.1 0.1

242 Flurprimidole 0.02

243 Flurtamone 0.05

244 Flusilazole(F)(R) 0.05

245 Flutolanil 0.05

246 Flutriafol 0.05

247 Fluvalinate 10

248 Folpet 0.05

249 Fomesafen 0.02

250 Foramsulfuron 0.05

251 Formetanate[sum of formetanate and its

salts expressed as formetanate(hydrochloride) 0.05

252 Formothion 0.05 0.05

253 Fosetyl-Al(sum fosetyl + phosphorous

acid and their salts, expressed as fosetyl) 0.5 5

254 Fosthiazate 0.05

255 Fuberidazole 0.05

256 Furametpyr 0.1

257 Furathiocarb 0.1 0.1

258 Furfural 1

259 Gibberellic acid 5

260

Glufosinate-ammonium(sum of glufosinate, its salts, MPP and NAG expressed as glufosinate equivalents)

0.1 0.50 0.1

261 Glyphosate 1.0 2

262 Guazatine 0.1

263 Halfenprox 10

264 Halosulfuron methyl 0.02

(106)

265

Haloxyfop including haloxyfop-R(Haloxyfop -R methyl ester, haloxyfop-R and conj -ugates of haloxyfop-R expressed as haloxyfop-R)(F)(R)

0.05

266

Heptachlor(sum of heptachlor and hepta -chlor epoxide expressed as heptachlor) (F)

0.02 0.02

267 Hexachlorobenzene(F) 0.02 0.02

268 Hexachlorocyclohexane(HCH), sum of isomers,

except the gamma isomer 0.2 0.02

269 Hexaconazole 0.05 0.05

270 Hexaflumuron 5.0 15

271 Hexythiazox 20.0 35 0.05

272 Hydrogen cyanide 1

273 Hydrogen phosphide 0.01

274 Hymexazol 0.02 0.05

275 Imazalil 0.1 0.1

276 Imazamox 0.1

277 Imazaquin 0.05 0.05

278 Imazethapyr ammonium 0.05

279 Imazosulfuron 0.02

280 Imibenconazole 0.2 20

281 Imidacloprid 10 0.05

282 Iminoctadine 1.0 1

283 Indoxacarb as sum of the isomers S and

R(F) 0.05

284

Iodosulfuron-methyl(iodosulfuron-methy l including salts, expressed as iodosul -furon-methyl)

0.05

285 Ioxynil, including its esters expressed

as ioxynil(F) 0.1

286 Ipconazole 0.02

287 Iprodione(R) 20 0.1

288 Iprovalicarb 0.1

289 Isoproturon 0.1

290 Isouron 0.02

291 Isoxaben 0.02

292

Isoxaflutole(sum of isoxaflutole, RPA202248 and RPA203328, expressed as isoxaf -lutole)

0.1

(107)

293 Isoxathion 5

294 Kasugamycin 0.04

295 Kresoxim-methyl(F)(R) 20 0.1

296 Lactofen 0.02

297 Lambda-Cyhalothrin(F)(R) 1

298 Lenacil 0.1

299 Lepimectin 0.3

300 Lindane(Gamma-isomer of hexachloro

-cyclohexane(HCH))(F) 0.05

301 Linuron 0.02 0.1

302 Lufenuron(F) 10 0.02

303

MCPA and MCPB (MCPA, MCPB inclu -ding their salts, esters and conjugates

expressed as MCPA)(F)(R)

0.1

304 Malathion(sum of malathion and malaoxon

expressed as malathion) 0.5 0.5

305 Maleic hydrazide(R) 0.2 0.5

306 Mandipropamid 0.02

307 Mecarbam 0.1 0.1

308 Mecoprop(sum of mecoprop-p and

mecoprop expressed as mecoprop) 0.1

309

Mepanipyrim(Mepanipyrim and its meta -bolite(2-anilino-4-(2-hydroxypropyl)-6 -methylpyrimidine) expressed as mepa -nipyrim)

0.02

310 Mepiquat 0.1

311 Mepronil 0.1

312 Meptyldinocap(sum of 2,4 DNOPC and

2,4 DNOP expressed as meptyl dinocap) 0.1 313 Mercury compounds(sum of mercury

compounds expressed as mercury)(F) 0.02 314 Mesosulfuron-methyl expresssed as

mesosulfuron 0.02

315

Mesotrione(Sum of mesotrione and MNBA (4-methylsulfonyl-2-nitrobenzoicacid),e xpressed as mesotrione)

0.1 316 Metaflumizone(sum of E- and Z-isomers) 0.1 0.1

317

Metalaxyl and metalaxyl-M(metalaxyl including other mixtures of constituent

isomers including metalaxyl-M(sum of isomers)

0.1

(108)

318 Metaldehyde 0.1

319 Metamitron 0.1

320 Metazachlor 0.2

321 Metconazole(F) 0.02

322 Methabenzthiazuron 0.1

323 Methacrifos(F) 0.1 0.1

324 Methamidophos 5 0.02

325 Methidathion(F) 0.2 1 0.5 0.5

326

Methiocarb(sum of methiocarb and methi -ocarb sulfoxide and sulfone, expressed

as methiocarb)

0.1

327

Metholachlor and metholachlor-S(methol -achlor including other mixtures of cons -tituent isomers includingS-metholachlor S-metholachlor(sum of isomers))

0.1

328 Methomyl and Thiodicarb(sum of methomyl

and thiodicarb expressed as methomyl) 0.1

329 Methoprene 0.05

330 Methoxychlor(F) 0.1 0.1

331 Methoxyfenozide(F) 20 0.05

332 Metosulam 0.01

333 Metrafenone 0.05

334 Metribuzin 0.1 0.1

335 Metsulfuron-methyl 0.1

336 Mevinphos(sum of E-and Z-isomers) 0.02

337 Microbutanil 20

338 Milbemectin(sum of MA4+8,9Z-MA4,

expressed as milbemectin)(R) 0.5 2 0.1

339 Molinate 0.02 0.1

340 Monocrotophos 0.1 0.1

341 Monolinuron 0.05 0.1

342 Monuron 0.1

343 Myclobutanyl(R) 0.05

344 Napropamide 0.05

345 Nicosulfuron 0.05

346 Nitenpyram 10

347 Nitrofen(F) 0.02

348 Nonylphenolsulfon 0.04

349 Novaluron(F) 0.01

(109)

350 Omethoate 1

351 Orthosulfamuron 0.01

352 Oryzalin 0.02

353 Oxadiargyl 0.05

354 Oxadiazon 0.05

355 Oxadixyl 0.02

356 Oxamyl 0.02

357 Oxasulfuron 0.1

358 Oxaziclomefon -

359 Oxycarboxin 0.05

360

Oxydemeton-methyl(sum of oxydemeton -methyl and demeton-S-methyl sulfone

expressed as oxydemeton-methyl)

0.05 0.05

361 Oxyfluorfen 0.05

362 Paclobutrazol 0.02

363 Paraquat 0.3 0.05 0.2

364 Parathion(F) 0.3 0.1

365

Parathion-methyl(sum of Parathion-methyl and paraoxon-methyl expressed as

Parathion-methyl) 0.2 0.05

366 Penconazole(F) 0.1 0.1

367 Pencycuron(F) - 0.05

368 Pendimethalin(F) 0.1

369 Penoxsulam 0.02

370 Permethrin(sum of isomers) 20 20 0.1 20

371 Pethoxamid 0.02

372 Phenmedipham(R) 0.1

373 Phenothrin 0.02 0.05

374 Phenthoate 0.1

375

Phorate(sum of phorate,its oxygen analo -gue and their sulfones expressed as phorate)

0.1 0.1

376 Phosalone 2 0.1

377 Phosmet(phosmet and phosmet oxon

expressed as phosmet)(R) 0.5 0.1

378 Phosphamidon 0.1 0.02

379

Phosphines and phosphides(sum of aluminiumphosphide, aluminium phosphine, phosphine, magnesium phosphide, magne-sium phosphine, zinc phosphide and zinc phosphine)

0.05

(110)

380 Phoxim(F) 0.1 0.1

381 Picloram 0.01

382 Picolinafen 0.1

383 Picoxystrobin(F) 0.1

384 Pindone 0.001

385 Pinoxaden 0.05

386 Pirimicarb(sum of pirimicarb and desmethyl

pirimicarb expressed as pirimicarb) 0.05

387 Pirimiphos-methyl(F) 0.05

388 Probenazole 0.03

389

Prochloraz(sum of prochloraz and its metabolites containing the 2,4,6-Trichloro -phenol moiety expressed as prochloraz)

0.1 0.1

390 Procymidone(R) 0.1 0.1

391 Profenofos(F) 1 0.1

392 Profoxydim 0.1

393

Prohexadione(prohexadione(acid) and its salts expressed as prohexadione- calcium)

0.1 0.1

394 Propachlor(oxalinic derivate of propachlor,

expressed as propachlor) 0.05

395 Propamocarb(Sum of propamocarb and

its salt expressed as propamocarb) 0.2

396 Propanil 0.1

397 Propaquizafop 0.05

398 Propargite(F) 5 5 5

399 Propham 0.1

400 Propiconazole 0.1 0.1

401 Propineb(expressed as propilen diamine) 0.1

402 Propisochlor 0.01

403 Propoxur 0.1 0.1

404

Propoxycarbazone(propoxycarbazone, its salts and 2-hydroxy-propoxy-propoxy -carbazone, calculated as propoxycarba -zone)

0.05

405 Propyzamide(F)(R) 0.05 0.05

406 Proquinazid 0.05

407 Prosulfocarb 0.05

408 Prosulfuron 0.1

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Korea Japan China EU Codex 409 Prothioconazole(Prothioconazole-desthio)(R) 0.02

410 Prothiofos 5.0

411 Pymetrozine 0.1

412 Pyraclofos 5.0 5

413 Pyraclostrobin(F) 0.05

414 Pyraflufen-ethyl 0.05 0.05

415 Pyrasulfutole 0.02

416 Pyrazolinate 0.02

417 Pyrazophos(F) 0.1 0.1

418 Pyrethrins 3 0.5

419 Pyridaben(F) 10 0.05

420 Pyridalyl 0.02

421

Pyridate(sum of pyridate, its hydrolysis product CL9673(6-chloro-4-hydroxy-3- CL9673(6-chloro-4-hydroxy-3-phenyl -pyridazin) and hydrolysable conjugates

of CL9673 expressed as pyridate)

0.1

422 Pyrifenox 5.0

423 Pyrimethanil 0.1

424 Pyrimidifen 5

425 Pyrimiphos-methyl 10

426 Pyriproxyfen(F) 0.3 0.05

427 Pyroxsulam 0.02

428 Quinalphos 0.1 0.1

429 Quinclorac 0.1

430 Quinmerac 0.1

431 Quinoxyfen(F) 0.05

432 Quintozene(sum of quintozene and penta

-chloro-aniline expressed as quintozene)(F) 0.05 0.05

433 Quizalofop,incl.quizalfop-P 0.05

434

Resmethrin(resmethrin including other mixtures of consituent isomers(sum of isomers))(F)

0.2 0.2

435 Rimsulfuron 0.1

436 Rotenone 0.02

437 Sec-buthylamine 0.1

438 Silafluofen 35

439 Silthiofam 0.1

440 Simazine 0.05

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441 Simeconazole 10

442 Spinet or am(XDE-175) 0.1

443 Spinosad(sum of spinosyn A and spinosyn

D,expressed as spinosad(F) 0.1 2 0.05

444 Spirodiclofen(F) 5.0 0.05

445 Spiromesifen 30 0.02

446

Spirotetramat and its 4 metabolites BYI08330-enol, BYI08330-keto hydroxy, BYI08330-monohydroxy, and BYI08330 enol-glucoside, expressed as spirotetramat

0.1

447 Spiroxamine(R) 0.1

448 Sulcotrione 0.05

449 Sulfentrazone 0.05

450 Sulfosulfuron 0.1

451 Sulfurylfluoride 0.02

452 Sulphur 5

453 TEPP 0.02

454 Tau-Fluvalinate(F) 0.01

455 Tebuconazole 5.0 25 0.05

456 Tebufenozide(F) 25 0.1

457 Tebufenpyrad(F) 2.0 2 0.1

458 Tebuthiuron 0.02

459 Tecnazene(F) 0.1 0.1

460 Teflubenzuron 20 0.05

461 Tefluthrin(F) 0.2 0.05

462 Tembotrione 0.05

463 Tepraloxydim 0.05 0.1

464 Terbufos 0.005 0.01

465 Terbuthylazine 0.05

466 Terephthalic caid cuper 0.5

467 Tetraconazole(F) 20 0.02

468 Tetradifon 1 0.05

469 Thiabendazole(R) 0.1 0.1

470 Thiacloprid(F) 30 0.05

471 Thiamethoxam(sum of thiamethoxam

and clothianidin expressed as thiamethoxam) 2.0 20 0.1

472 Thifensulfuron-methyl 0.1

473 Thiobencarb 0.1

474 Thiodicarb & Methomyl 20

(113)

475 Thiophanate-methyl(R) 0.1

476 Thiram(expressedasthiram) 0.2

477 Tolclofos-methyl 0.1

478 Tolfenpyrad 20

479 Tolylfluanid(Sum of tolylfluanid and dimethylamino sulfotoluidide expressed

as tolylfluanid)(R) 0.1

480 Topramezone(BAS670H) 0.02

481 Tralkoxydim 0.05

482 Tri-allate 0.1

483 Triadimefon and triadimenol(sum of tri

-adimefon and triadimenol)(F) 1 0.2

484 Triasulfuron 0.1

485 Triazophos(F) 0.05 0.02

486 Tribenuron-methyl 0.02

487 Trichlamide 0.1

488 Trichlorfon 0.50 0.1

489 Triclopyr 0.03 0.1

490 Tricyclazole 0.02 0.05

491 Tridemorph(F) 20 20

492 Trifloxystrobin 5 0.05

493

Triflumizole[Triflumizole and metabolite FM-6-1(N-(4-chloro-2-trifluoromethylp h e n y l ) - n - p r o p o x y a c e t a m i d i n e ) , expressed as Triflumizole(F)

3.0 15 0.1

494 Triflumuron(F) 0.02 0.05

495 Trifluralin 0.05 0.1

496 Triflusulfuron 0.05

497 Triforine 0.1 0.1

498 Trimethyl-sulfonium cation, resulting

from the use of glyphosate(F) 0.05

499 Trinexapac 0.02 0.05

500 Triticonazole 0.02

501 Tritosulfuron 0.02

502 Valifenalate 0.02

503 Vamidothion 0.02

504 Viben 0.1

505 Vinclozolin(sum of vinclozolin and all metabolites containing the 3,5-dichloraniniline

moiety, expressed as vinclozolin)(R) 0.1

506 Warfarin 0.001

507 Ziram 0.2

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감사의 글

영국 웨스트민스터 대성당에 있는 한 주교의 묘비에 다음과 같은 글귀가 새겨져

있다 합니다. “만일 내가 내 자신을 먼저 변화시켰더라면 그것을 보고 내 가족이,

변화되었을 것을 또한 그것에 용기를 얻어 내 나라를 더 좋은 곳으로 바꿀 수 있,

었을 것을 그리고 누가 아는가 세상까지도 변했을지, , ...”

이 글귀는 스스로의 끊임없는 변화의 노력과 실천이 얼마나 중요한지를 일깨워주 는 성구로서 저 또한 일찍이 변화하지 못하고 있던 중 게으른 저를 일깨워 배움의

열의에 불을 지펴주시고 아낌없는 격려와 지도를 주신 고마우신 분들과 학위의 기,

쁨과 영광을 함께 하고자 합니다.

평소 엄격하면서도 자애로운 사랑으로 제자를 사회로 이끌어 주시고 본 과정을 완성할 수 있도록 진정한 정으로 학업은 물론 학문을 익히는 요령과 늘 따뜻한 격 려로 자신감을 갖도록 이끌어 주시고 논문 작성 시 하나하나 살펴주신 장해춘 지도교 수님께 먼저 머리 숙여 진심으로 감사를 드립니다.

그리고 논문심사 과정에서 바쁘신 중에도 논문은 본인의 얼굴이라시며 잘못된 부

분을 하나하나 짚어주시며 귀중한 조언을 해주신 조선대학교 이명렬 교수님 부경,

대학교 양지영 교수님 목포대학교 김인철 교수님께, 깊은 감사를 드립니다.

특히 전문지식이 부족하고 힘들어하는 저를 따뜻한 배려로 샘플채취에서 분석까지,

성심껏 지도해 주시고 지원을 아끼지 않았던 선배 동료이신 서울식약청 김희연 과,

장님께도 무한한 감사를 드립니다.

늦게하는 공부라 격려하고 이끌어 주신 성호정님 김희정님 바쁜 일과 중에도 자, ,

료수집에서 정리까지 많은 도움을 주었던 최재천 연구관님 학교와 멀리 떨어져 있,

다고 깊은 배려로 이것저것 챙겨주신 조선대학교 장미 박사님 김용훈, 연구사님,

최계선 한민구 후배들을 비롯한 직원 동료 여러분과 논문작성에 많은 도움을 주신,

모든 분들께 진심으로 감사를 드립니다.

돌이켜 보면 지난 4~5년은 힘들면서도 소중했던 시간이었고 좋은 기억의 시간일

것입니다.

항상 사랑으로 어려운 여건 속에서 헌신적으로 내조를 아끼지 아니한 지혜로운

아내와 주변 환경에 굴하지 않고 열심히 자신의 길을 가고 있는 아들 오현 금년에,

손주 준우를 만날 수 있는 기쁨을 안겨준 딸 주영과 사위 장인호에게 사랑한다는 말과 함께 고마움을 전합니다.

길의 끝은 언제나 또 다른 길의 시작을 의미합니다 어떤 길이 제 앞에 나타나더.

라도 저에게 힘을 주신 분들이 있기에 이제는 그 길을 헤쳐나갈 수 있는 용기가 생겼습니다.

지금까지의 배우고 느낀 것을 디딤돌 삼아 자만하지 않고 항상 자신을 돌아보며 다른 사람에게도 도움이 되는 존재가 되고 싶습니다.

모두 감사합니다.

2010.12

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