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Disassembly of the Mounted Electric/Electronic Components on Wasted Printed Circuit Board and their Characterizations

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(1)

http://dx.doi.org/10.12972/ksmer.2012.49.6.728

ඍ1$#઩ୋచܤୢ׆ୢୀऀඨଭंࠤࢫ൉ন

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 ଲ୨ผ



 ଲ୍వ



 ଲ୍ߡ



Disassembly of the Mounted Electric/Electronic Components on Wasted Printed Circuit Board and their Characterizations

Youngjin Kim, Junghoon Lee, Jae-chun Lee and Jaeryeong Lee

Abstract : Disassembly of the mounted electric/electronic components (EECs) on WPCBs and their characterizations were surveyed for enhancing the reusing/recycling feasibility of WPCBs. Disassembling treatment was carried out by using the self-designed apparatus installed grinding attachment. The weight ratio of the detached EECs was used as the efficiency of disassembly, which was the average value of the result treated with 3 WPCBs in each condition. 95.2 wt% of the disassembling efficiency could be accomplished ultimately by 3 repetitive treatments at a grinder height of 1.5 mm, a grinder speed of 5500 rpm and the WPCB moving speed of 1 cm/s.

After this treatment, WPCB could be categorized to three divisions such as disassembled EECs, dismantled board and abrasion powders. Total content of metal in WPCB was surveyed to 17.9 wt%, and 48.4 % of them (8.7 wt%) was contained in the division of EECs. 20 metal elements could be detected in WPCBs. Moreover, 4 major elements (Cu, Al, Fe, Pb Cu) in total metal content were comprised at 90.7 % and Pb/Ag existed mainly in abrasion powders.

Key words : Wasted printed circuit board, Grinding treatment, Disassembling, Metal content, Metal distribution څ أ दۍթধͿşࣺقۤ޳ʼرەəۻş/ۻۙҙुۆۦԐڌ/ۦটڌÀɠՁںॳԜ֨ࢅşڦ३ҙुқν

֬ॹфқνʽҙुۆ࣢ՁथÀε֬֨ॠٕɰ. ҙुқν֬ॹڹٍԑѓѪں޽ڌॢҙुқνşεۙߕÒьॠي

սॱॠٕڷ϶, ٍυԵۆȭۋ(0.5, 1.5 mm), ধۻ՚ʪ(2500, 5500 rpm), WPCB ۋʴ՚ʪ(1~5 cm/sec), ٍԑবս

ˣںѺজ֨ࢅϸԴҙुқνমڱںथÀॠČ߯ۺߌνܓæںʪ߻ॠٕɰ. ҙुқνমڱڹۤ޳ʽҙुۆ

ۻߕИóقʂॢқνʽҙुۆИóҼͿथÀॠٕڷ϶, ÁߌνܓæقԴ3ÒۆWPCBقʂ३थŒÉڷͿćԓ ॠٕɰ. ٍυԵȭۋ1.5 mm, ধۻ՚ʪ5500 rpm, ۋʴ՚ʪ1 cm/s ߌνܓæڷͿ3 ধߌν֨, 95.2 %ۆҙुқ νÀÀɠॠٕɰ. ߌν঳WPCBə, ҙु, ҙुۋ࢐äʽWPCB, ٍԑқϊͿқνʼؽڷ϶, WPCBۆŚ՚Ձқ

॥͟ڹ17.9 wt%ٕڷ϶, ۋܼ48.4 % Ś՚Ձқ(8.7 wt%)ڹҙुق॥ڮʼرەڼںঝۍॠٕɰ. WPCBقԴ

ߪ20ÒŚ՚ڙՙÀê߻ʼؽڷ϶, ۋܼCu, Al, Fe, PbÀۻߕŚ՚ۆ90.7 %ε޲ݓॠٕČ, Pb, Agəٍԑқϊ قȬ߹ʼرқपॠٕɰ.

ܳڅر  दۍթধͿşࣺ, ٍԑ, ҙुқν, Ś՚॥͟, Ձққप

2012ț8ښ29ێۿս, 2012ț11ښ4ێ֮ԐٰΒ 2012ț12ښ13ێóۦঝ܁

1) Ìڙʂॡİقȃݓ·ۙڙėॡę 2) ॢĶݓݗۙڙٍĵڙġНۙڙٍĵ҆ҙ

*Corresponding Author(ۋۦͺ) E-mail; [email protected]

Address; Department of Energy & Resources Engineering, Kangwon National University Chuncheon, Kangwon-do, 200-701

eISSN 2287-4321(Online)

Դ΁

ۻۙ, ܁҃ࣀ֪ф࠻ौࢢˣߐɳԓغۋьۻ॥ق˰

͆ɰتॢۻş/ۻۙ܃ुۆԦԓфՙҼÀƴܵ০ݒÀ ॠČەڷ϶, ՙҼۙۆşɠф˥ۙۍقʂॢşʂսܵ

ۋȭ؉ݙق˰͆ԞͿڏ܃ुۆÒьşÂۋ۾޲ɳ߹

ʼČ, ۋͿۍॠيदۻş/ۻۙ܃ुۆьԦ͟ۋśü০

ݒÀॠČ ەə ֬܁ۋɰ(Lee et al., 2000; Cui and Forssberg, 2003; Lee et al., 2007, Cui and Forssberg, 2007; Khetriwaal et al., 2009). ॢठ, ʂशۺۍۻş/ۻ

ۙҙुܼۆ ॠǣۍ ۍթধͿşࣺ(PCB, printed circuit board)ڹ ۹२ş(resistor), ͔࣡ݓ֟ࢢ(transistor), ࡓʜ Դ(capacitor) ˣę Ïڹ ɰتॢ ۻş/ۻۙҙु(EECs, electric/electronic components)ۋ ۤ޳ʼر Á ҙुں

ٍĵȦЛ

(2)

Fig. 1. The pictures of the experimental apparatus for this experiment.

܃رॠəًॣںॠəۤ࠘ͿԴʂҙқۆۻۙ܃ुقۋ ڌʼČ ەر, दۻş/ۻۙ܃ुۆ ьԦ͟ ݒÀə द PCB(WPCB, wasted printed circuit board)ۆьԦ͟ݒ ÀͿٍĀʼرɰتॢ܃ुۆWPCB ьԦۋݒÀॣì ڷͿ ٚԜʼČ ەɰ.

ێъۺڷͿWPCBق॥ڮʽŚ՚ՁқڷͿə؎Θй ɔ(Al), ĵν(Cu), ߏ(Fe) ˣۆܳՁқęŚ(Au), ڹ(Ag),

ࣻ͆˘(Pd)ęÏڹŊŚ՚ʪй͟॥ڮʼرەəìڷͿ

؎Ͳ܋ەɰ. Ӽχ؉ɦ͆Ǭ(Pb), սڹ(Hg), ࠢ˚в(Cd) ˣęÏڹڮ३ڙՙۆ॥ڮÀɠՁʪȭ؉ߌνʼݓ؍

ڹԜࢗͿѓ࠘ॣąڍঞą١ّںьԦॠČɰتॢԦ НۆԦϼটʴقʪǣԄٖॳںܶսەɰČ҃ČʼČ

ەɰ(Li et al., 2007; Huang et al., 2009).

ইۦێъۺۍWPCBߌνė܁قԴəCu, AlęÏڹ

ܳŚ՚ՁқęČÀۆŊŚ՚χںধսॣЀۺڷͿۻş /ۻۙҙुۋۤ޳ʽԜࢗۆWPCBεцͿshredder ф

stamp mill ˣęÏڹࣷ/қթۤ࠘εۋڌ३қթॠČ, ۋͿҙࢢধսʂԜŚ՚Ձқں֥֩ওڹæ֩܃ʹѓ֩

ڷͿߌνॠČەɰ(Lee et al., 2002; Eswaraiah et al., 2008; Wu et al., 2008; Das et al., 2009; Duan et al., 2009; Yoo et al., 2009; Guo et al., 2011). ॠݓχۋ͠

ॢߌνė܁ڹWPCBق॥ڮʽй͟ۆŚ՚Ձқęڮ ३ܼŚ՚ۆߌνقəҙۺۼॠ϶, ̚ॢŚ՚ধսė܁

঳ɰ͟ۆė܁ҙԓНۋьԦʼəɳ۾ںÀݓČەɰ (Kinoshita et al., 2003, Cui and Zhang, 2008; Zuou and Qiu, 2010; Long et al., 2010; Kim et al., 2011; Jha et al., 2012; Yang et al., 2011).

ۋ͠ॢ ۋڮقԴ ߯Ŗ WPCBͿҙࢢ ҙुں َߌν

ওڹজॡۺߌνقۆ३ڍԸۺڷͿқνॠəٍĵÀ

ݕॱʼČەɰ. ॠݓχ, َۺߌνѓ֩ڹҙुۤ޳ѓ֩

фWPCBڮşНܛΪق˰͆܃ॢۺۋ϶, জॡۺߌν ѓ֩ڹWPCBۆĵܓфࠗսق˰͆Ԑڌۋ܃ॢۺۋ

͆ॣ ս ەɰ(Li et al., 2006; Wu and Zhang, 2010;

Duan et al., 2011).

˰͆Դٍ҆ĵقԴəɰتॢ঍ࢗфĵܓۆWPCB قۺڌÀɠॢٍԑѓ֩ۆҙुқνۤ࠘ε܃ۚॠي, ɰࠗĵܓٮҼİۺψڹҙुۋۤ޳ʼرەəदҼ˥١ (WVCR, wasted video cassette recorder) WPCBεʂԜ ڷͿҙुқνমڱфқν঳ԓНقʂॢŚ՚Ձқ,

॥͟ ˣۆ ࣢ՁथÀε ֬֨ॠٕɰ.

֬ॹѓѪ

֬ॹۤ࠘

ٍ҆ĵقԐڌʽşşəWPCBقۤ޳ʽEECsεқ

νॠşڦ३ٍ҆ĵ֬قԴ܃ۚॢٍԑߌνۤ࠘ͿԴ

Fig. 1ęÏۋşćۺٍԑߌνε֬֨ॠيWPCB ڬϸ قۤ޳ʽEECsۆқνÀÀɠॠʪ΀ॠٕɰ. şşۆĵ ՁڹWPCB ঳ϸںٍԑߌνॠşڦ३ٍυԵ4Ò(Ø : 75 mm, ŚՁٍυėغ(ܳ))εԺ࠘ॠٕڷ϶, ٍυԵۆধۻ՚

ʪ(grinder speed : 05500 rpm), ٍυԵȭۋ(height of grinder : 01.5 mm)ۆܓۼۋÀɠॠʪ΀܃ۚॠٕɰ.

̚ॢڮؓ֩֬οʌ(TCDMB20-100, air cylinder) 9Òε

ॠǣۆϿ˗((ÀͿ) 300 mm × (ՃͿ) 350 mm × (ȭۋ) 65 mm)ͿĵՁॠيٍԑߌν֨WPCBεԜҙقԴɄ͠

Č܁ॣ ս ەʪ΀ ॠٕڷ϶, ٍԑߌν ۤ࠘ūݓ ۋʴ (moving speed : 05 cm/s) Àɠॠʪ΀΂͠εԺ࠘ॠٕ

ɰ. ۋٽقWPCBͿҙࢢқνʽEECsεধսॠşڦॢ

ҙुধսۤ࠘фٍԑߌν֨, WPCB ঳ϸقԴьԦʼə

ٍԑқϊںߌνॠşڦॢݚݕۤ࠘(vacuum air cleaner, CR-401T, cleon)εԺ࠘ॠٕɰ.

֬ॹڙΒфė܁

ߌνʂԜWPCBəɰࠗĵܓ, ɳࠗŚ՚֨࣡, Ҽİۺ

(3)

Fig. 2. Flow sheet of disassembly process for this experiments.

ψڹEECsۋۤ޳ʼرەəܓæںχܔॠəWVCR قۤ޳ʽWPCBͿԸ܁ॠٕɰ. WPCBəÀۻ܃ुں

սݚ/३ߕॠəĶǴغߕͿҙࢢĵۓॢìڷͿ1996țق Դ2005țԐۋقԦԓʽWVCRقप॥ʽWPCBεԐ ڌॠٕڷ϶, ܃ܓغߕق˰͆WPCBۆࡾşфۤ޳ʽ

EECsۆ࣢Ձ(ܛΪ, Òս, ۤ޳ڦ࠘)ۋأÂۆ޲ۋəە ڷǣ, ێъۺۍ঍ࢗٮĵܓəFig. 2ۆԜɳڍࠑقǣࢍ

Ƕ ìęʴێॠɰ.

Fig. 2ə ҆ ٍĵۆ ֬ॹ ė܁ʪͿ ٍԑߌν ۻ, WPCBقۤ޳ʽʫςۺ঍ࢗۆҙुںսԸқνॠٕ

ɰ. ʫςۺҙुڹWPCBͿҙࢢқνÀڌۋॠş˺Л ق҆֬ॹقԴəҙुқνεČͲॠݓ؍ؕɰ. ˰͆Դ

҆֬ॹقԴəʫςۺ঍ࢗۆҙुںڍԸқνॢˏ, WPCBقʂॢٍԑߌν֬ॹںݕॱॠٕɰ.

ҙुқν֬ॹڹWPCBۆɰتՁقŖäॢߌνĀę ۆ ١޲ε ߯ՙজॠş ڦ३, ʴێॢ ܓæقԴ 3Òۆ

WPCBق ʂ३ ֬ॹॢ Āęε थŒڷͿ ćԓॠٕɰ.

EECs қνমڱф߯ۺܓæںʪ߻ॠşڦ३ٍυԵۆ

ধۻ՚ʪ(2500, 5500 rpm), ٍυԵۆȭۋ(0.5, 1.5 mm), WPCB ۋʴ՚ʪ(1, 3, 5 cm/s), ߌνবս(1, 2, 3 ধ)ε

Ѻজ֨ࢅϸԴ֬ॹॠٕɰ. EECs қνমڱ(Eweight)ڹ֩

(1)قۆ३ćԓॠٕڷ϶WPCBقۤ޳ʽۻߕEECsۆ

Иó(Wtotal weight of EECs in WPCB)ε100%ͿԺ܁ॠČ, қ

νʼəEECsεϔٍԑߌν֨ধսॠيИó(Wtotal weight of EECs detached by treatment)εࠑ܁ॠيćԓॠٕɰ.

žƕ ƃƇƅƆ ƒá ć

°ƒƍƒſƊ ƕ ƃƇƅƆ ƒ ƍƄžžœ Ƒ Ƈ ƌ ©œ ›

°ƒƍƒſƊ ƕ ƃƇƅƆ ƒ ƍƄžžœ Ƒ ‹Œ›ſƁƆ ƃƂ ƀƗ ƒƐƃſƒƋƃƌƒ × 100

(1)

WPCBͿҙࢢ EECsÀ қνʽ ԓНق ʂॢ ࣢Ձں

ܓԐॠşڦ३EECs қν߯ۺܓæڷͿWPCB 10Ò εߌνॢ঳, ÁԓНقʂॢՁқф॥͟ںܓԐॠٕ

ɰ. EECs қνߌν ঳ ԓНͿə, ٍԑߌν ʽ WPCB (dismantled board), ٍԑқϊ(Abrasion powder), EECs Ϳĵқॣսەؽڷ϶, ÁԓНقʂॢŚ՚ڙՙۆܛΪ

ф॥͟ںঝۍॠşڦ३Chemical Digestionںۋڌॠ ي ٰۻ ڌ३֨ࢇ ˏ, ڮʪĀ०॔͆݋υ(ICP, Optima 7300 DV, PerkinElmer, USA)εۋڌॠيқԵॠٕɰ.

ĀęфČ޶

Fig. 3(a and b)ڹٍυԵۆধۻ՚ʪε2500 rpmͿ

Č܁ॠČ, ٍυԵۆȭۋ(0.5, 1.5 mm), WPCBۆۋʴ

՚ʪ(1, 3, 5 cm/s)εܓۼॠϸԴEECsқνε֬ॱॢĀ ęۋɰ. ۻъۺڷͿWPCBۆۋʴ՚ʪÀӇεս΀, 1޲

ߌν҃ɰə2޲ߌνę܁قԴқνমڱۋȭóǣࢍǫ ں؎սەؽɰ. ۋəٍԑߌνʼəWPCB ঳ϸقҙ

޳ʽێҙEECs ܳѺقԴəäۆߌνʼݓ؍ڹԜࢗͿ

WPCBÀۋʴʽĀęͿࣺɳʽɰ. ˰͆Դ1޲ߌνমڱ ۋȭںս΀3ধߌν঳ۆۻߕEECsқνমڱۋȭó

ǣࢍǫں؎սەؽɰ. WPCB ۋʴ՚ʪÇՙ(5 G 1 cm/s)ق˰δEECsۆқνমڱݒÀڱ(10% ۋԜ)ۋۻ ߕۺڷͿ ȭڹ ąॳں ǣࢍǻؽɰ. ۋ͠ॢ Āęə

WPCBۆۋʴ՚ʪÇՙق˰͆ɳڦϸۺɾߌν֨Â ۋݒÀʼرEECsۆқνমڱۋȭ؉ݕìڷͿࣺɳʽ ɰ. ॢठٍυԵۆȭۋѺজə2500 rpmۆٍԑ՚ʪܓ æقԴəࢀٖॳۋǣࢍǣݓ؍ؕɰ. ۋə2500 rpmۆ

ٍυԵধۻ՚ʪÀWPCB ঳ϸۆEECs ф՝ʌτҙқ ۆٍυقə߿қॠݓ؍؉ԴьԦʽĀęͿࣺɳʽɰ.

ۋقধۻ՚ʪε5500 rpmڷͿݒÀ֨ࡈٍԑ֬ॹںݕ ॱॠٕɰ(Fig. 3(c) and (d)). ۋܓæقԴʪυ޴ÀݓͿ

1޲ߌνমڱۋȭںս΀ۻߕEECsқνমڱۋȭ ó ǣࢍǣə ąॳں ǣࢍǴؽɰ. ॢठ, ۹՚ ٍԑܓæ (2500 rpm)قԴٮə ɵν WPCBۋʴ՚ʪۆ Çՙقʪ

ࢀٖॳۋػؽڷ϶, ъʂͿٍυԵۆȭۋѺজق˰͆

ߌνমڱۋ ࡾó ɵ͆ݓə ąॳں ǣࢍǴؽɰ. WPCB ۋʴ՚ʪق ʂॢ ٖॳՁڹ, ٍυ՚ʪÀ ݒÀ॥ق ˰͆

WPCB ɳڦϸۺɾڅĵʼəߌν֨Âۋɳ߹ʽĀęͿ

ࣺɳʽɰ. ̚ॢٍυԵধۻ՚ʪ5500 rpm, ٍυԵۆȭۋ

1.5 mm ܓæقԴ1޲ߌνমڱۋÀۤȭóܓԐʼؽ

(4)

Fig. 3. Disassembly efficiencies of EECs with a change of treatment conditions.

əʚ, ۋəٍԑߌνʂԜϸقҙ޳ʽEECsقʂॢٍ

ԑĀę͆Čࣺɳʽɰ. Fig. 3(d)قԴ҃əцٮÏۋٍԑ՚ʪ

5500 rpm, ٍυԵȭۋ1.5 mm, WPCB ۋʴ՚ʪ1 cm/s ܓ æڷͿ 3 ধ ٍԑߌνقԴ Àۤ ȭڹ EECs қνমڱ (95.2%)ںǣࢍǸںঝۍॣսەؽɰ.

WPCBͿҙࢢқνʽEECs ࣢Ձقʂॢ֬ॹڹ߯ʂ

EECs қνܓæڷͿ10ÒۆWPCBsεߌνॢ঳, ÁÁ ۆԓНقʂ३қԵॠٕɰ. ߌνę܁ܼWPCBۆѺজ ə Fig. 4ق ǣࢍǴؽɰ.

ےۆͿ Ը࢘ॢ WPCBs 10Òۆ ߪИóə 3742.2 g (100 wt%)ۋؽڷ϶, EECsқνমڱۋÀۤȭڹ߯ۺ ܓæ(ٍυԵۆ ধۻ՚ʪ : 5500 rpm, ٍυԵۆ ȭۋ : 1.5 mm, WPCB ۋʴ՚ʪ : 1 cm/s)ڷͿ ߌνॢĀę, Fig. 5ٮÏۋٍԑߌνʽWPCB(2164.1 g), ٍԑқϊ (439.2 g), EECs(560.5 g)ۆ3ÀݓԓНۋьԦॠٕڷ϶, ʫςۺ঍ࢗۆҙुڹأ545.2 g(14.6 wt%), ٍԑߌν

֨ ьԦॢ ՜֬تڹ 33.2 g(0.9 wt%)ڷͿঝۍʼؽɰ.

WPCB ٍԑߌνͿҙࢢьԦॢԓНۆʂॢ࣢ՁथÀ

(5)

Fig. 4. The images of WPCB treated in the optimum conditions (5500 rpm, 1.5 mm, 1 cm/s) by using the apparatus shown in Fig. 1.

Fig. 5. The weights and proportions of the three products after disassembling by using the apparatus shown in Fig. 1.

ə ʫςۺ঍ࢗۆҙुę՜֬ʽИóε܃ٽॠČ, ٍԑ ߌνʽWPCB, ٍԑқϊ, EECsۆߪИó(3163.8 g)ε

100 wt%Ϳঞԓॠي֬֨ॠٕɰ(Fig. 5).

Fig. 6قԴ, WPCB, ٍԑߌν঳ьԦॢÁԓНقप

॥ʽŚ՚фҼŚ՚ՁқۆИó(g)ٮ॥͟(wt%)ںǣ

ࢍǴؽɰ. 10ÒۆWPCBsق॥ڮʽŚ՚ۆ॥͟ڹ17.9 wt%Ϳঝۍʼؽɰ. ٍԑߌν঳ÁԓНقʂॢИóə,

ٍԑߌν ʽ WPCB 68.4 wt%(2164.1 g), EECs 17.7 wt%(560.5 g), ٍԑқϊۋ13.9 wt%(439.2 g)տڷͿܓ Ԑʼؽɰ. ߌν঳, EECsÀ࢐äʽWPCBÀʂҙқۆ

Иóε ޲ݓॠČ ەؽڷǣ, ۻߕ Ś՚Ձқ(567.5 g)ۆ

48.4%(274.5 g)əқνʽEECsق॥ڮʼرەڼںঝ ۍॣսەؽɰ. ۋ͠ॢĀęͿҙࢢWPCBقҙ޳ʼر

ەəEECsںқνॠəìۋWPCBۆۦটڌڱॳԜڹ

Н΁মęۺۍŚ՚Ձқধսقज़սۺۍė܁ۋ͆Čࣺ

ɳʽɰ.

WPCBق॥ڮʽŚ՚ՁқںқԵॢĀę, ߪ20Òۆ

Ś՚ڙՙÀê߻ʼؽڷ϶Áڙՙقʂ३ٍԑߌνԓН ѻ॥͟ںTable 1ق܁νॠٕɰ. WPCB ॥ڮŚ՚ܼ

4Òڙՙ(Cu, Al, Fe, Pb)ÀۻߕŚ՚Ձқۆ90.7%ε޲

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Fig. 6. The weights and their ratios for metal and non- metal ingredient in each product.

Table 1. The content of metal elements in each disassembling product (ppm)

Elements Dismantled board Abrasion powder EECs Total

Ag 37.5 64.2 47.7 149.4

Al 1,932.2 4,062.7 23,871.5 29,866.4

Au N.D N.D 5.5 5.5

Ba 291.0 96.6 81.5 469.1

Bi N.D N.D 65.2 65.2

Ca 69.7 49.0 1,318.3 1,437

Co 4.7 N.D 30.6 35.3

Cr 39.2 17.8 48.1 105.1

Cu 34,651.0 27,803.4 35,572.1 98,026.5

Fe 8,677.4 2,224.0 12,546.4 23,447.8

Mg 11.7 N.D 40.4 52.1

Mn N.D N.D 414.6 414.6

Ni 649.3 223.2 1,297.7 2,170.2

Pb 2,811.1 6,523.3 2,045.0 11,379.4

Sb 35.7 N.D 230.7 266.4

Si 82.0 7.6 3,573.3 3,662.9

Sn N.D N.D 1,100.4 1,100.4

Sr N.D 18.4 179.9 198.3

Ti 449.1 N.D 423.4 872.5

Zn 1,507.1 268.3 3,856.7 5,632.1

Total 51,248.7 41,358.5 86,749.0 179,356.2

ݓॠČەؽڷ϶, Au, Bi, Mn Sn Ձқڹқνʽҙुق Դχê߻ʼؽɰ. ٍԑߌνʽWPCBقܕۦॠəŚ՚

ՁқۆʂҙқڹCu(67.6%)ۋؽڷ϶, ٍԑқϊقəۻ ߕ Pbۆ 57.3%À қपॠČ ەؽɰ.

Ā΁

WPCBقʂॢۦটڌڱڹН΁ҙ޳ʽEECsقʂॢ

ۦԐڌ/ۦটڌڱںॳԜ֨ࢅşڦ३Դə1޲ۺڷͿWPCB ͿҙࢢEECs қνė܁ۋज़սۺۋɰ. ۋقٍ҆ĵقԴ ə ɰتॢ ঍ࢗۆ WPCBق ۺڌ Àɠॢ ٍԑѓ֩ۆ

EECsқνşε܃ۚॠي, WVCRقۤ޳ʽWPCBεʂ ԜڷͿEECsқν֬ॹں֬֨ॠٕČ, EECsқν঳ԓ Нقʂॢ࣢ՁںŚ՚ڙՙεşܵڷͿथÀॠٕڷ϶ɰ ڼę Ïڹ Ā΁ں صؽɰ.

1) ٍԑѓ֩قۆॢEECs қνəäۆϿ˜ܓæقԴ

1޲ߌνমڱۋ2޲ߌνমڱ҃ɰǰóǣࢍǮڷ϶, ۋəٍԑߌνʂԜۆWPCB ঳ϸقҙ޳ʼرەəێ ҙEECsقۆ३1޲ߌνę܁قԴٍԑϸۺۋ܃ॢʽ

Āę͆Čࣺɳʽɰ. ̚ॢϿ˜ܓæقԴ1޲ߌνমڱ

(7)

ۋȭںս΀3 ধъ҄ߌν঳, EECs қνমڱۋȭó

ǣࢍǫں ؎ ս ەؽɰ.

2) ٍυԵধۻ՚ʪ2500 rpm ܓæقԴəWPCB ۋ ʴ՚ʪεÇՙॣս΀ߌνমڱۋȭóǣࢍǮڷ϶, ъ ϸق5500 rpm ܓæقԴəۋʴ՚ʪقäۆٖॳںы ݓ ؍ؕɰ. ٍυԵۆ ȭۋ ̚ॢ 2500 rpm ܓæ҃ɰə

5500 rpm ܓæقԴࡾóٖॳںܳəìڷͿܓԐʼؽ ڷ϶, ٍυԵۆধۻ՚ʪ5500 rpm, ٍυԵۆȭۋ1.5 mm, WPCBۆ ۋʴ՚ʪ 1 cm/s ܓæقԴ 95.2%ۆ

EECsқνÀÀɠ॥ں؎սەؽɰ.

3) WPCBق॥ڮʽߪŚ՚Ձқڹ17.9 wt%ͿܓԐ ʼؽڷ϶, ٍԑߌνقۆ३ьԦʽԓНڹٍԑߌνʽ

WPCB, ٍԑқϊ, EECsͿĵқॣսەؽɰ. ۋٍܼ

ԑߌνʽWPCBÀۻߕИóۆ68.4 wt%ε޲ݓॠČ

ەؽڷǣ, Ś՚Ձқۆ48.4%əEECsقқपॠČەؽ ɰ. WPCB ॥ڮŚ՚ܼ4Òڙՙ(Cu, Al, Fe, Pb)Àۻ ߕŚ՚Ձқۆ90.7%ε޲ݓॠČەؽڷ϶, Au, Bi, Mn Sn ՁқڹқνʽEECsقԴχê߻ʼؽČ, ٍԑߌνʽ

WPCBقܕۦॠəŚ՚ՁқۆʂҙқڹCu(67.6%)ۋ ؽڷ϶, ٍԑқϊقəۻߕPbۆ57.3%Àқप॥ں؎

ս ەؽɰ.

ÇԐۆŘ

ٍ҆ĵə2010țʪݓ֩ą܃ҙۆۦڙڷͿॢĶقȃ ݓşցथÀڙ(KETEP)ۆݓڙںы؉սॱॢٍĵę܃

ۓɦɰ. (No. 20105010006B)

޷ČЛॶ

Cui, J.R. and Forssberg, E., 2003, “Mechanical recycling of waste electric and electronic equipment: a review,”

Journal of Hazardous Materials, Vol. B99, pp. 243-263.

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Cui, J.R. and Zhang, L., 2008, “Metallurgical recovery of metals from electronic waste : A review,” Journal of Hazardous Materials, Vol. 158, pp. 228-256.

Das, A., Vidyadhar, A. and Mehrotra, S.P., 2009, “A noble flowsheet for the recovery of metal value from waste printed circuit boards,” Resources, Conservation and recycling, Vol. 53, pp. 464-469.

Duan et al., 2009, “Recovery of metals from waste printed circuit boards by mechanical method using a water medium,” Journal of Hazardous Materials, Vol. 166, pp.

478-482.

Duan, H.b., Hou, K., Li, J.H. and Zhu, X.D., 2011,

“Examining the technology acceptance for dismantling of waste printed circuit boards in light of recycling and environmental concerns,” Journal of Environmental Management, Vol. 92, pp. 392-399.

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Journal of Environmental Management, Vol. 90, pp.

153-165.

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Hydrometallurgy, Vol. 69, pp. 73-79.

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Journal of Hazardous Materials, Vol. A73, pp. 209-220.

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Environmental Science and Technology, Vol. 41, No. 1,

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׌ઽ஼

2009ț Ìڙʂॡİ ݓĵ֨֟ࢰėॡę

ėॡԐ

2011ț Ìڙʂॡİ ݓĵ֨֟ࢰėॡę

ėॡԵԐ

ইۦ Ìڙʂॡİ قȃݓۙڙėॡę чԐę܁

(E-mail; [email protected])

ଲ୍వ

ইۦ ॢĶݓݗۙڙٍĵڙ ġНۙڙٍĵ҆ҙ ޾ےٍĵڙ (欧G 彳櫾躇G 缧49嘳G 缧1埲G 垾畢)

ଲ୨ผ

2013țÌڙʂॡİقȃݓۙڙėॡę

ėॡԐ (ܖغٚ܁)

ইۦ Ìڙʂॡİ قȃݓۙڙėॡę ॡԐę܁

(E-mail; [email protected])

ଲ୍ߡ

1996ț ॢتʂॡİۙڙėॡęėॡԐ 1998ț ॢتʂॡİۙڙėॡęėॡԵԐ 2002ț Tohoku University ۦΒėॡę

ėॡчԐ

ইۦ Ìڙʂॡİ قȃݓۙڙėॡę ܓİս (E-mail; [email protected])

pp. 1995-2000.

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Journal of Hazardous Materials, Vol. 177, pp. 626-632.

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393-400.

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Journal of Hazardous Materials, Vol. 175, pp. 823-828.

수치

Fig. 1. The pictures of the experimental apparatus for this  experiment.
Fig. 2. Flow sheet of disassembly process for this  experiments. ψڹEECsۋۤ޳ʼرەəܓæںχܔॠəWVCR قۤ޳ʽWPCBͿԸ܁ॠٕɰ
Fig. 3. Disassembly efficiencies of EECs with a change of treatment conditions. əʚ, ۋəٍԑߌνʂԜϸقҙ޳ʽEECsقʂॢٍ ԑĀę͆Čࣺɳʽɰ
Fig. 4. The images of WPCB treated in the optimum conditions (5500 rpm, 1.5 mm, 1 cm/s) by using the apparatus  shown in Fig
+2

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