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Hydroxyl Radical Species Generated by Non-thermal Direct Plasma Jet and Their Qualitative Evaluation

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198 한국진공학회 PW-P016

Low Temperature PECVD for SiOx Thin Film Encapsulation

Hyung June Ahn1, Sang Heon Yong2, Sun Jung Kim2, Changmin Lee2, Heeyeop Chae1,2

1SKKU Advanced Institute of Nanotechnology (SAINT), Sungkyunkwan University (SKKU) Suwon, 440-746,

Republic of Korea, 2School of Chemical Engineering, Sungkyunkwan University (SKKU),

Suwon, 440-746, Republic of Korea

Organic light-emitting diode (OLED) displays have promising potential to replace liquid crystal displays (LCDs) due to their advantages of low power consumption, fast response time, broad viewing angle and flexibility. Organic light emitting materials are vulnerable to moisture and oxygen, so inorganic thin films are required for barrier substrates and encapsulations.[1-2].

In this work, the silicon-based inorganic thin films are deposited on plastic substrates by plasma-enhanced chemical vapor deposition (PECVD) at low temperature. It is necessary to deposit thin film at low temperature. Because the heat gives damage to flexible plastic substrates. As one of the transparent diffusion barrier materials, silicon oxides have been investigated. SiOx have less toxic, so it is one of the more widely examined

materials as a diffusion barrier in addition to the dielectric materials in solid-state electronics [3-4]. The SiOx

thin films are deposited by a PECVD process in low temperature below 100oC. Water vapor transmission rate

(WVTR) was determined by a calcium resistance test, and the rate less than 10.-2g/m2 •day was achieved. And then, flexibility of the film was also evaluated.

Keywords: Plasma Enhanced Chemical Vapor Deposition (PECVD), Low Temperature Thin Film Encapsulation (TFE), Silicon Oxide (SiOx)

PW-P017

Hydroxyl Radical Species Generated by Non-thermal

Direct Plasma Jet and Their Qualitative Evaluation

B. Ghimire*, S. I. Hong, Y. J. Hong, E. H. Choi

Plasma Bioscience Research Center, Kwangwoon University, Seoul, Korea

Reactive oxygen and nitrogen species (RONS) can be generated by using non-thermal atmospheric pressure plasma jet which have profound biomedical applications [1, 2]. In this work, reactive oxygen species like hydroxyl radical (OH) are generated by using non-thermal direct plasma jet above water surface using Ar gas and their properties have been studied using ultraviolet absorption spectroscopy. OH radicals are found to be generated simultaneously with the discharge current with concentration of 2.7 × 1015 /cm3 at 7mm above water surface while their persistence time have been measured to be 2.8 µS. In addition, it has been shown that plasma initiated ultraviolets play a major role to generate RONS inside water. Further works are going on to measure the temporal behavior of OH and O2*-.

[1] Attri, P et al, Generation mechanism of hydroxyl radical species and its lifetime prediction during the plasma-initiated ultraviolet (UV) photolysis, Sci Rep 5, 9332 (2015)

[2] Kim, Y.H. et al, Measurement of reactive hydroxyl radical species inside the biosolutions during non-thermal atmospheric pressure plasma jet bombardment onto the solution, Plasma Chem Plasma Process 34, 457 (2014)

Keywords: non-thermal plasma, reactive oxygen and nitrogen species, plasma initiated ultraviolet photolysis, OH lifetime

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